Plasmon-induced catalytic CO2 hydrogenation by a nano-sheet Pt/HxMoO3−y hybrid with abundant surface oxygen vacancies

Author(s):  
Hao Ge ◽  
Yasutaka Kuwahara ◽  
Kazuki Kusu ◽  
Hiromi Yamashita

The hybrid of nanosheet-structured HxMoO3−y coupled with Pt exhibits efficient photothermal catalytic hydrogenation of CO2.

2021 ◽  
Vol 865 ◽  
pp. 158746
Author(s):  
Yongchao Niu ◽  
Xiaoju Yin ◽  
Chengzhi Sun ◽  
Xueqin Song ◽  
Naiqing Zhang

2020 ◽  
Vol 11 (29) ◽  
pp. 7593-7598 ◽  
Author(s):  
Erwin Lam ◽  
Gina Noh ◽  
Ka Wing Chan ◽  
Kim Larmier ◽  
Dmitry Lebedev ◽  
...  

CuGax alloy nanoparticles supported on SiO2 can be obtained by surface organometallic chemistry. This catalyst is active and selective for the hydrogenation of CO2 to CH3OH, related to the formation of an optimal interface between Cu and GaIIIOx.


2018 ◽  
Vol 11 (03) ◽  
pp. 1850057 ◽  
Author(s):  
Reza Meshkini Far ◽  
Olena V. Ischenko ◽  
Alla G. Dyachenko ◽  
Oleksandr Bieda ◽  
Snezhana V. Gaidai ◽  
...  

Here, we report, for the first time, on the catalytic hydrogenation of CO2 to methane at atmospheric pressure. For the preparation of hydrogenation catalysts based on Ni and Fe metals, a convenient method is developed. According to this method, low-temperature reduction of the co-precipitated Ni and Fe oxides with hydrogen gives the effective and selective bimetallic Ni[Formula: see text]Fe[Formula: see text], Ni[Formula: see text]Fe[Formula: see text] and Ni[Formula: see text]Fe[Formula: see text] catalysts. At the temperature range of 300–400[Formula: see text]C, they exhibit a high efficiency of CH4 production with respect to monometallic Ni and Fe catalysts. The results imply a synergistic effect between Ni and Fe which caused the superior activity of the Ni[Formula: see text]Fe[Formula: see text] catalyst conversing [Formula: see text]% of CO2 into CH4 at 350[Formula: see text]C. To adapt the Ni–Fe catalysts in the industry, the effect of two different carriers on the efficiency of the alumina-supported Ni[Formula: see text]Fe[Formula: see text] catalyst was investigated. It is found that the Ni[Formula: see text]Fe[Formula: see text]/[Formula: see text]-Al2O3 catalyst effectively conversed CO2 giving 100% methane yield already at 275[Formula: see text]C.


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