Ultrafast reproducible synthesis of an Agnanocluster@MOF composite and its superior visible-photocatalytic activity in batch and in continuous flow

2021 ◽  
Author(s):  
Ana Arenas-Vivo ◽  
Sara Rojas ◽  
Ivan Ocaña ◽  
Ana Torres ◽  
Marta Liras ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Surface Area ◽  
Continuous Flow ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Metal Organic ◽  
Visible Photocatalytic Activity ◽  
Metallic Species

The (photo)catalytical properties of Metal-Organic Frameworks (MOFs) can be enhanced by postsynthetic inclusion of metallic species in their porosity. Due to their extraordinarily high surface area and well defined porous...

Exploring frontiers of high surface area metal–organic frameworks

2013 ◽  
Vol 4 (4) ◽  
pp. 1781 ◽  
Author(s):  
Richard Luis Martin ◽  
Maciej Haranczyk
Keyword(s):  
Surface Area ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Metal Organic

scholarly journals Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal–Organic Frameworks with High Surface Area

2014 ◽  
Vol 137 (1) ◽  
pp. 413-419 ◽  
Author(s):  
Tian-Fu Liu ◽  
Dawei Feng ◽  
Ying-Pin Chen ◽  
Lanfang Zou ◽  
Mathieu Bosch ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Metal Organic ◽  
Zirconium Metal

Recent strategies to improve the photoactivity of metal-organic frameworks

2021 ◽  
Author(s):  
Yu Yan ◽  
Reza Abazari ◽  
Juming Yao ◽  
Junkuo Gao
Keyword(s):  
Surface Area ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Crystalline Materials ◽  
Rigid Framework ◽  
Metal Organic ◽  
Compositional Diversity

Metal-organic frameworks (MOFs) are micro/mesoporous crystalline materials with high surface area, tunability, and compositional diversity which have been widely applied in diverse applications, including catalysis. The rigid framework built from...

scholarly journals Enhanced Fungicidal Efficacy by Co-Delivery of Azoxystrobin and Diniconazole with Cauliflower-Like Metal–Organic Frameworks NH2-Al-MIL-101

2021 ◽  
Vol 22 (19) ◽  
pp. 10412
Author(s):  
Huiping Chen ◽  
Yongpan Shan ◽  
Lidong Cao ◽  
Pengyue Zhao ◽  
Chong Cao ◽  
...  
Keyword(s):  
Surface Area ◽  
Plant Protection ◽  
Metal Organic Framework ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Release Time ◽  
Natural Ecosystems ◽  
Resistance Risk ◽  
Metal Organic

Long-term use of a single fungicide increases the resistance risk and causes adverse effects on natural ecosystems. Controlled release formulations of dual fungicides with different modes of action can afford a new dimension for addressing the current issues. Based on adjustable aperture and superhigh surface area, metal–organic frameworks (MOFs) are ideal candidates as pesticide release carriers. This study used Al3+ as the metal node and 2-aminoterephthalic acid as the organic chain to prepare aluminum-based metal–organic framework material (NH2-Al-MIL-101) with “cauliflower-like” structure and high surface area of 2359.0 m2/g. Fungicides of azoxystrobin (AZOX) and diniconazole (Dini) were simultaneously encapsulated into NH2-Al-MIL-101 with the loading content of 6.71% and 29.72%, respectively. Dual fungicide delivery system of AZOX@Dini@NH2-Al-MIL-101 demonstrated sustained and pH responsive release profiles. When the maximum cumulative release rate of AZOX and Dini both reached about 90%, the release time was 46 and 136 h, respectively. Furthermore, EC50 values as well as the percentage of inhibition revealed that AZOX@Dini@NH2-Al-MIL-101 had enhanced germicidal efficacy against rice sheath blight (Rhizoctonia solani), evidenced by the synergistic ratio of 1.83. The present study demonstrates a potential application prospect in sustainable plant protection through co-delivery fungicides with MOFs as a platform.

Rendering High Surface Area, Mesoporous Metal–Organic Frameworks Electronically Conductive

2017 ◽  
Vol 9 (14) ◽  
pp. 12584-12591 ◽  
Author(s):  
Timothy C. Wang ◽  
Idan Hod ◽  
Cornelius O. Audu ◽  
Nicolaas A. Vermeulen ◽  
SonBinh T. Nguyen ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Metal Organic ◽  
Mesoporous Metal

Metal–organic frameworks grown on a porous planar template with an exceptionally high surface area: promising nanofiller platforms for CO2 separation

2017 ◽  
Vol 5 (43) ◽  
pp. 22500-22505 ◽  
Author(s):  
Hyunhee Lee ◽  
Seul Chan Park ◽  
Ji Soo Roh ◽  
Gi Hyeon Moon ◽  
Jae Eun Shin ◽  
...  
Keyword(s):  
Surface Area ◽  
Gas Separation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Co2 Separation ◽  
Two Dimensional ◽  
Real Gas ◽  
Metal Organic

A new concept of nanocomposites, MOFs on porous two-dimensional nanosheets (MP2), was demonstrated and showed great potential in real gas separation.

scholarly journals Enhanced Desalination Performance of Capacitive Deionization Using Nanoporous Carbon Derived from ZIF-67 Metal Organic Frameworks and CNTs

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2091
Author(s):  
Ngo Minh Phuoc ◽  
Euiyeon Jung ◽  
Nguyen Anh Thu Tran ◽  
Young-Woo Lee ◽  
Chung-Yul Yoo ◽  
...  
Keyword(s):  
Surface Area ◽  
Electrochemical Impedance ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Metal Center ◽  
Carbon Cloth ◽  
Capacitive Deionization ◽  
Metal Organic ◽  
Carbon Based

Capacitive deionization (CDI) based on ion electrosorption has recently emerged as a promising desalination technology due to its low energy consumption and environmental friendliness compared to conventional purification technologies. Carbon-based materials, including activated carbon (AC), carbon aerogel, carbon cloth, and carbon fiber, have been mostly used in CDI electrodes due their high surface area, electrochemical stability, and abundance. However, the low electrical conductivity and non-regular pore shape and size distribution of carbon-based electrodes limits the maximization of the salt removal performance of a CDI desalination system using such electrodes. Metal-organic frameworks (MOFs) are novel porous materials with periodic three-dimensional structures consisting of metal center and organic ligands. MOFs have received substantial attention due to their high surface area, adjustable pore size, periodical unsaturated pores of metal center, and high thermal and chemical stabilities. In this study, we have synthesized ZIF-67 using CNTs as a substrate to fully utilize the unique advantages of both MOF and nanocarbon materials. Such synthesis of ZIF-67 carbon nanostructures was confirmed by TEM, SEM, and XRD. The results showed that the 3D-connected ZIF-67 nanostructures bridging by CNTs were successfully prepared. We applied this nanostructured ZIF-67@CNT to CDI electrodes for desalination. We found that the salt removal performance was significantly enhanced by 88% for 30% ZIF-67@CNTs-included electrodes as compared with pristine AC electrodes. This increase in salt removal behavior was analyzed by electrochemical analysis such as cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements, and the results indicate reduced electrical impedance and enhanced electrode capacitance in the presence of ZIF-67@CNTs.

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