A high performance all-vanadate-based Li-ion full cell

2021 ◽  
Vol 9 (16) ◽  
pp. 10345-10353
Author(s):  
Jie Xu ◽  
Dongmei Zhang ◽  
Zongping Zhang ◽  
Shibing Ni
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
High Performance ◽  
High Energy ◽  
High Energy Density ◽  
Porous Microspheres ◽  
Full Cell ◽  
Excellent Electrochemical Performance ◽  
Li Ion ◽  
First Time

An all-vanadate-based Li-ion full cell with high energy density and long lifespan is constructed for the first time based on the design of Li3VO4/N doped C porous microspheres with excellent electrochemical performance.

Significantly improved conductivity of spinel Co3O4 porous nanowires partially substituted by Sn in tetrahedral sites for high-performance quasi-solid-state supercapacitors

2021 ◽  
Vol 9 (11) ◽  
pp. 7005-7017
Author(s):  
Yunjian Chen ◽  
Jia Zhu ◽  
Ni Wang ◽  
Huanyu Cheng ◽  
Xianzhong Tang ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Solid State ◽  
Energy Density ◽  
Electrochemical Performance ◽  
High Performance ◽  
High Energy ◽  
High Energy Density ◽  
Partial Substitution ◽  
Tetrahedral Sites ◽  
Excellent Electrochemical Performance

The partial substitution of Sn in spinel-structured Co3O4 exhibits excellent electrochemical performance, including good electrical conductivity, high energy density, power density and cycling retention, as a positive electrode for supercapacitors.

scholarly journals Fabrication of Hierarchical NiMoO4/NiMoO4 Nanoflowers on Highly Conductive Flexible Nickel Foam Substrate as a Capacitive Electrode Material for Supercapacitors with Enhanced Electrochemical Performance

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Charge Discharge

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.

Bifunctional iron disulfide nanoellipsoids for high energy density supercapacitor and electrocatalytic oxygen evolution applications

2019 ◽  
Vol 6 (3) ◽  
pp. 659-670 ◽  
Author(s):  
Zhiqin Sun ◽  
Xue Yang ◽  
Huiming Lin ◽  
Feng Zhang ◽  
Qian Wang ◽  
...  
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Oxygen Evolution ◽  
High Energy ◽  
High Energy Density ◽  
Microwave Assisted ◽  
Iron Disulfide ◽  
Excellent Electrochemical Performance ◽  
Microwave Assisted Method

FeS2, prepared using a rapid microwave assisted method, exhibits excellent electrochemical performance for supercapacitor and OER applications.

scholarly journals Enhanced Roles of Carbon Architectures in High-Performance Lithium-Ion Batteries

2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Lu Wang ◽  
Junwei Han ◽  
Debin Kong ◽  
Ying Tao ◽  
Quan-Hong Yang
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
High Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
High Mass

Abstract Lithium-ion batteries (LIBs), which are high-energy-density and low-safety-risk secondary batteries, are underpinned to the rise in electrochemical energy storage devices that satisfy the urgent demands of the global energy storage market. With the aim of achieving high energy density and fast-charging performance, the exploitation of simple and low-cost approaches for the production of high capacity, high density, high mass loading, and kinetically ion-accessible electrodes that maximize charge storage and transport in LIBs, is a critical need. Toward the construction of high-performance electrodes, carbons are promisingly used in the enhanced roles of active materials, electrochemical reaction frameworks for high-capacity noncarbons, and lightweight current collectors. Here, we review recent advances in the carbon engineering of electrodes for excellent electrochemical performance and structural stability, which is enabled by assembled carbon architectures that guarantee sufficient charge delivery and volume fluctuation buffering inside the electrode during cycling. Some specific feasible assembly methods, synergism between structural design components of carbon assemblies, and electrochemical performance enhancement are highlighted. The precise design of carbon cages by the assembly of graphene units is potentially useful for the controlled preparation of high-capacity carbon-caged noncarbon anodes with volumetric capacities over 2100 mAh cm−3. Finally, insights are given on the prospects and challenges for designing carbon architectures for practical LIBs that simultaneously provide high energy densities (both gravimetric and volumetric) and high rate performance.

MOF-derived α-NiS nanorods on graphene as an electrode for high-energy-density supercapacitors

2018 ◽  
Vol 6 (9) ◽  
pp. 4003-4012 ◽  
Author(s):  
Chong Qu ◽  
Lei Zhang ◽  
Wei Meng ◽  
Zibin Liang ◽  
Bingjun Zhu ◽  
...  
Keyword(s):  
Energy Density ◽  
High Performance ◽  
High Energy ◽  
Positive Electrode ◽  
High Energy Density ◽  
Hybrid Supercapacitor ◽  
First Time

α-NiS/rGO nanohybrids synthesized from water-refluxed Ni-MOF-74/rGO were applied as a high-performance hybrid supercapacitor positive electrode for the first time.

scholarly journals Facile Synthesis of FeS@C Particles Toward High-Performance Anodes for Lithium-Ion Batteries

Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1467
Author(s):  
Xuanni Lin ◽  
Zhuoyi Yang ◽  
Anru Guo ◽  
Dong Liu
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
High Current Density ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Hierarchical Porous

High energy density batteries with high performance are significantly important for intelligent electrical vehicular systems. Iron sulfurs are recognized as one of the most promising anodes for high energy density lithium-ion batteries because of their high theoretical specific capacity and relatively stable electrochemical performance. However, their large-scale commercialized application for lithium-ion batteries are plagued by high-cost and complicated preparation methods. Here, we report a simple and cost-effective method for the scalable synthesis of nanoconfined FeS in porous carbon (defined as FeS@C) as anodes by direct pyrolysis of an iron(III) p-toluenesulfonate precursor. The carbon architecture embedded with FeS nanoparticles provides a rapid electron transport property, and its hierarchical porous structure effectively enhances the ion transport rate, thereby leading to a good electrochemical performance. The resultant FeS@C anodes exhibit high reversible capacity and long cycle life up to 500 cycles at high current density. This work provides a simple strategy for the mass production of FeS@C particles, which represents a critical step forward toward practical applications of iron sulfurs anodes.

Probing heat generation and release in 57.5 Ah high-energy-density Li-ion pouch cell with nickel-rich cathode and SiOx/graphite anode

2021 ◽  
Author(s):  
Xiaopeng Qi ◽  
Bingxue Liu ◽  
Fengling Yun ◽  
Changhong Wang ◽  
Rennian Wang ◽  
...  
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Thermal Management ◽  
Heat Generation ◽  
High Energy ◽  
Graphite Anode ◽  
High Energy Density ◽  
Large Format ◽  
Li Ion ◽  
Generation Mechanisms

The electrochemical performance, reliability, and safety of Li-ion cells depend on thermal management. However, the heat generation mechanisms and release characteristics of large-format high-energy-density (HED) Li-ion cells, a prerequisite for...

A novel caterpillar-with-eggs mesostructured iron sulfide as Li-ion battery anode displaying stable electrochemical performance

2022 ◽  
Author(s):  
Ting Zhou ◽  
Yan Wang ◽  
Yajun Zhu ◽  
Tianli Han ◽  
Huigang Zhang ◽  
...  
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Iron Sulfide ◽  
High Energy ◽  
High Energy Density ◽  
Li Ion Batteries ◽  
Li Ion Battery ◽  
Li Ion ◽  
Battery Anode

Emerging anodes are significant for high energy-density Li-ion batteries. Here, we present a mesostructured FeS2 composing of nanoparticles embedded in a nanoneedle-assembled nanotube, forming a novel caterpillar-with-eggs (CWE) structure. The...

Nb2O5 nanoparticles encapsulated in ordered mesoporous carbon matrix as advanced anode materials for Li ion capacitors

RSC Advances ◽  
2016 ◽  
Vol 6 (75) ◽  
pp. 71338-71344 ◽  
Author(s):  
Jingjie Wang ◽  
Hongsen Li ◽  
Laifa Shen ◽  
Shengyang Dong ◽  
Xiaogang Zhang
Keyword(s):  
Activated Carbon ◽  
Energy Density ◽  
Mesoporous Carbon ◽  
Anode Materials ◽  
High Performance ◽  
Carbon Matrix ◽  
High Energy ◽  
High Energy Density ◽  
Ordered Mesoporous ◽  
Li Ion

A high performance Li ion capacitor was constructed with Nb2O5/CMK-3 as anode and activated carbon as cathode, which demonstrated high energy density and power density benefit from the combination of the merits of batteries and supercapacitors.

scholarly journals Preparation of a NbN/graphene nanocomposite by solution impregnation and its application in high-performance Li-ion hybrid capacitors

RSC Advances ◽  
2017 ◽  
Vol 7 (32) ◽  
pp. 19967-19975 ◽  
Author(s):  
Zhen-Kun Chen ◽  
Jun-Wei Lang ◽  
Ling-Yang Liu ◽  
Ling-Bin Kong
Keyword(s):  
Energy Density ◽  
Power Density ◽  
High Performance ◽  
High Energy ◽  
High Energy Density ◽  
Graphene Nanocomposite ◽  
Li Ion ◽  
Hybrid Capacitors

Freestanding NbN/graphene papers were used in Li-ion hybrid capacitors and exhibit high energy density and power density.

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