Interfacial atomic Ni tetragon intercalation in a NiO2-to-Pd hetero-structure triggers superior HER activity to the Pt catalyst

Author(s):  
Haolin Li ◽  
Sheng Dai ◽  
Dinesh Bhalothia ◽  
Alice Hu ◽  
Jyh-Pin Chou ◽  
...  

Electron relocation pumps charge from Ni via tensile strain of doped Ni tetragons, compression strain of surrounding Pd atoms and the inherent electronegative difference, thus promising prominent hydrogen evolution efficiency for the Pd surface.

2015 ◽  
Vol 5 (1) ◽  
pp. 428-437 ◽  
Author(s):  
Yusuke Yamada ◽  
Akifumi Nomura ◽  
Hideyuki Tadokoro ◽  
Shunichi Fukuzumi

A Pt catalyst was closely located to an organic photosensitiser on a negatively charged semiconductor for efficient photocatalytic H2 evolution.


2017 ◽  
Vol 5 (13) ◽  
pp. 6233-6244 ◽  
Author(s):  
Baohe Chong ◽  
Wen Zhu ◽  
Xianghui Hou

The photocatalytic decomposition of water is believed to be able to help mitigate the crisis of fossil fuel depletion.


Small ◽  
2021 ◽  
pp. 2104288
Author(s):  
Xiaowen Yu ◽  
Egon Campos dos Santos ◽  
Jai White ◽  
Germán Salazar‐Alvarez ◽  
Lars G. M. Pettersson ◽  
...  

2019 ◽  
Vol 92 (8) ◽  
pp. 411-418
Author(s):  
Abdurrahman Yilmaz ◽  
Ugur Pasaogullari

2020 ◽  
Vol 30 (47) ◽  
pp. 1910028 ◽  
Author(s):  
Luyang Xiu ◽  
Wei Pei ◽  
Si Zhou ◽  
Zhiyu Wang ◽  
Pengju Yang ◽  
...  

1999 ◽  
Vol 1 (2) ◽  
pp. 75-78
Author(s):  
Tatiana Oncescu ◽  
M. Contineanu ◽  
Lucia Meahcov

Colloidal chemical approaches are increasingly utilised for the preparation and stabilization of semiconductor nanoparticles.We prepared a colloidal CdS in excess ofNa2Susing a method described in the literature and determined the particle size from its absorption spectrum by Brus equation. A diameter of about 50Å was calculated. For the stabilization of colloid we choosed from various tested polymers a 1% in weight copolymer (1/1), styrene/maleic anhydride. As redox catalyst we used colloidal Pt obtained “in situ” by irradiaton ofPtCl6K2. We established the role of each of the system partners as: CdS concentration,Na2Sexcess, Pt catalyst concentration, the irradiation time, and the system temperature. We studied the influence of each participant to the hydrogen evolution in order to optimize this system.The formation of nanosize composite particlesCd1−xZnxSshowed an increasing ofH2amount generated under irradiation, in comparison with CdS particles.The results obtained permitted us to calculate the turnover number (TO) of the system.


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