A study on electroactive PVDF/mica nanosheet composites with enhanced γ-phase for capacitive and piezoelectric force sensing

Soft Matter ◽  
2021 ◽  
Author(s):  
Mohammed Khalifa ◽  
Elisabeth Schoeffmann ◽  
Herfried Lammer ◽  
Arunjunairaj Mahendran ◽  
Günter Wuzella ◽  
...  

Herein, a multifunctional poly(vinylidene fluoride) (PVDF)/mica nanosheets composite (PMNC) thin film was developed for the capacitive and piezoelectric force sensor. High electroactive γ-phase content (89%) of PVDF was achieved through...

1991 ◽  
Vol 202 (2) ◽  
pp. 213-220 ◽  
Author(s):  
Akiyoshi Takeno ◽  
Norimasa Okui ◽  
Tetsuji Kitoh ◽  
Michiharu Muraoka ◽  
Susumu Umemoto ◽  
...  

ChemPhysChem ◽  
2013 ◽  
Vol 14 (9) ◽  
pp. 1926-1933 ◽  
Author(s):  
Ana Catarina Lopes ◽  
Sonia A. C. Carabineiro ◽  
Manuel Fernando R. Pereira ◽  
Gabriela Botelho ◽  
Senentxu Lanceros-Mendez

Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3292
Author(s):  
Wu Guo ◽  
Zhaogang Liu ◽  
Yan Zhu ◽  
Li Li

Based on poly(vinylidene fluoride)/graphene (PVDF/GP) nano-composite powder, with high β-phase content (>90%), prepared on our self-designed pan-mill mechanochemical reactor, the micro-injection molding of PVDF/GP composite was successfully realized and micro-parts with good replication and dimensional stability were achieved. The filling behaviors and the structure evolution of the composite during the extremely narrow channel of the micro-injection molding were systematically studied. In contrast to conventional injection molding, the extremely high injection speed and small cavity of micro-injection molding produced a high shear force and cooling rate, leading to the obvious “skin-core” structure of the micro-parts and the orientation of both PVDF and GP in the shear layer, thus, endowing the micro-parts with a higher melting point and crystallinity and also inducing the transformation of more α-phase PVDF to β-phase. At the injection speed of 500 mm/s, the β-phase PVDF in the micro-part was 78%, almost two times of that in the macro-part, which was beneficial to improve the dielectric properties. The micro-part had the higher tensile strength (57.6 MPa) and elongation at break (53.6%) than those of the macro-part, due to its increased crystallinity and β-phase content.


RSC Advances ◽  
2017 ◽  
Vol 7 (77) ◽  
pp. 48712-48722 ◽  
Author(s):  
Ji Eun Lee ◽  
Yanting Guo ◽  
Richard Eungkee Lee ◽  
Siu Ning Leung

A new strategy using non-isothermal crystallization and supercritical CO2 processing is found to promote the electroactive phase content in PVDF.


2006 ◽  
Vol 298 (2) ◽  
pp. 639-651 ◽  
Author(s):  
Ivo B. Rietveld ◽  
K. Kobayashi ◽  
H. Yamada ◽  
K. Matsushige

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