ITIC Derivative Acceptors for Ternary Organic Solar Cells: Fine-Tuning of Absorption Bands, LUMO Energy Levels, and Cascade Charge Transfer

Author(s):  
Seungyun Baik ◽  
Dong Won Kim ◽  
Hyun−Sik Kang ◽  
Seung Hwa Hong ◽  
Sungjin Park ◽  
...  

For effective supplementary acceptor molecules (A2) in ternary organic solar cell (TOSC) devices, a series of ITIC derivatives was designed and synthesized by incorporating symmetrically or asymmetrically functional termini of...

2018 ◽  
Vol 5 (5) ◽  
pp. 837-848 ◽  
Author(s):  
Frank-Julian Kahle ◽  
Alexander Rudnick ◽  
Heinz Bässler ◽  
Anna Köhler

Energetic disorder is crucial to consistently model both absorption and photoluminescence spectra of charge transfer states in organic solar cells.


2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.


Author(s):  
Jie Lv ◽  
Hua Tang ◽  
Jiaming Huang ◽  
Cenqi Yan ◽  
Kuan Liu ◽  
...  

Due to the barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves excellent power conversion efficiency (PCE) of 15.7%. However, the...


2015 ◽  
Vol 12 (5) ◽  
pp. 413-420
Author(s):  
Muhammad Ahsan Naveed ◽  
A. Hussain ◽  
K. Islam ◽  
P. Akhter

Organic solar cells have potential as an alternative to conventional inorganic solar cell due to low processing cost, flexibility and easy fabrication technique. The goal of this paper is to study the characteristics of the CuPc and PCBM based organic solar cell by introducing a thin layer of Ag at the interface of donor (CuPc) and Acceptor (PCBM), their photovoltaic and optical properties were investigated. The heterojunction solar cells with and without silver inter layer were fabricated through thermal deposition in HR vacuum. The OPV solar cells were characterized using current-voltage graphs, absorbance spectrum and Impedance spectroscopy. Impedance spectroscopy was taken to identify the traps using series resistance, parallel resistance, and Impedance spectrums under different frequencies. Optical behaviors of these devices have been investigated with absorbance spectrum. Introducing Ag to interfacing point produced traps and these traps causes to decreased Voc, Isc, FF, and efficiency. The effect of silver layer at donor acceptor interface was studied.


2015 ◽  
Vol 8 (2) ◽  
pp. 592-601 ◽  
Author(s):  
Bradley A. MacLeod ◽  
Bertrand J. Tremolet de Villers ◽  
Philip Schulz ◽  
Paul F. Ndione ◽  
Hyungchul Kim ◽  
...  

Interstitial zinc defects in solution-processed ZnO can be mitigated by using a diethylzinc precursor instead of zinc acetate, or by modifying the ZnO surface with a phosphonic acid, resulting in improved organic solar cell stability.


2019 ◽  
Vol 7 (3) ◽  
pp. 543-552 ◽  
Author(s):  
Suman Suman ◽  
Afzal Siddiqui ◽  
M. L. Keshtov ◽  
Ganesh D. Sharma ◽  
Surya Prakash Singh

In this work, two new indolo-[3,2-b]-carbazole (ICz) core-based non-fullerene acceptors (ICz-Rd2 and ICz-RdCN2) with an A–π–D–π–A backbone were designed, synthesized, and characterized and the influence of molecular engineering on the terminal end groups on their performance in organic solar cells (OSCs) was systematically examined.


RSC Advances ◽  
2015 ◽  
Vol 5 (30) ◽  
pp. 23892-23899 ◽  
Author(s):  
Seung Joo Lee ◽  
Jae-Yeon Kim ◽  
Abd. Rashid bin Mohd Yusoff ◽  
Jin Jang

We report a comprehensive study of the influence of NPs on organic solar cells by introducing Au NPs into OSCs fabricated using PEDOT:PSS:rGO. The PEDOT:PSS:rGO embedded with Au NPs had better Jsc and PCE values than the control devices.


RSC Advances ◽  
2020 ◽  
Vol 10 (42) ◽  
pp. 24882-24892 ◽  
Author(s):  
Anjusree S. ◽  
Arya K. R. ◽  
Bikas C. Das

Current imaging by C-AFM is demonstrated as a very effective tool to probe the defects in the organic solar cell active layer.


2016 ◽  
Vol 7 (9) ◽  
pp. 5798-5804 ◽  
Author(s):  
Wenhan He ◽  
Maksim Y. Livshits ◽  
Diane A. Dickie ◽  
Jianzhong Yang ◽  
Rachel Quinnett ◽  
...  

“Roller-wheel” shaped Pt-containing molecules display enhanced crystallinity and are better performing organic solar cell materials than conventional small molecules and polymers featuring “dumbbell” shaped structures.


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