Polyoxometalate-Induced ‘Cage-within-Cage’ Metal Organic Frameworks with High Efficiency of CO2 Photoreduction

Author(s):  
Zeyu Du ◽  
Yanzhao Yu ◽  
Ningfang Li ◽  
Yuanshan Xue ◽  
Lingxi Xu ◽  
...  

Photocatalytic CO2 reduction (CO2RR) into high-value products is of great significance not only in addressing global warming but developing sustainable energy. Herein, two novel metal organic frameworks (MOFs) induced by...

Molecules ◽  
2018 ◽  
Vol 23 (11) ◽  
pp. 2947 ◽  
Author(s):  
Shu-Na Zhao ◽  
Guangbo Wang ◽  
Dirk Poelman ◽  
Pascal Van Der Voort

The increase in environmental pollution due to the excessive use of fossil fuels has prompted the development of alternative and sustainable energy sources. As an abundant and sustainable energy, solar energy represents the most attractive and promising clean energy source for replacing fossil fuels. Metal organic frameworks (MOFs) are easily constructed and can be tailored towards favorable photocatalytic properties in pollution degradation, organic transformations, CO2 reduction and water splitting. In this review, we first summarize the different roles of MOF materials in the photoredox chemical systems. Then, the typical applications of MOF materials in heterogeneous photocatalysis are discussed in detail. Finally, the challenges and opportunities in this promising field are evaluated.


2021 ◽  
Author(s):  
Cornelia Elizabeth Pompe ◽  
Petra Agota Szilagyi

Metal-organic frameworks are promising host supporting matrices for catalytically active guest. In particular, their crystallinity renders them desirable as their pores may act as atom-precise templates for the growth of...


Author(s):  
Xuewei Li ◽  
Wei She ◽  
Jing Wang ◽  
Weizuo Li ◽  
Guangming Li

Bi-metal organic frameworks (Bi-MOFs) derived carbon-based catalysts have exhibited the considerable potential for hydrogenation reactions. However, designing a suitable bi-MOF to fabricate the highly efficient catalyst is still great challenge....


2017 ◽  
Vol 7 (21) ◽  
pp. 4893-4904 ◽  
Author(s):  
Yi Chen ◽  
Dengke Wang ◽  
Xiaoyu Deng ◽  
Zhaohui Li

This review summarized the recent progress, limitations and challenges in using MOFs for photocatalytic CO2 reduction, a green and sustainable strategy for CO2 utilization.


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