Trimethylsulfonium Lead Triiodide (TMSPbI3) For Moisture-Stable Perovskite Solar Cells

2021 ◽  
Author(s):  
Md. Mahbubur Rahman ◽  
Ahmed Arif ◽  
Chuang-ye Ge ◽  
Ranbir Singh ◽  
Kicheon Yoo ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Organic Cations ◽  
Hydrogen Bonding Interaction ◽  
Lead Iodide ◽  
Bonding Interaction ◽  
Moisture Stability ◽  
Methylammonium Lead Iodide ◽  
Effective Hydrogen

Conventional, high-efficiency, hybrid organic—inorganic perovskites (e.g., methylammonium lead iodide (MAPbI3), formamidinium lead iodide (FAPbI3)) having ammonium-based organic cations exhibits poor moisture stability mainly due to the effective hydrogen bonding interaction...

Enhanced Grain Size and Crystallinity in CH3NH3PbI3 Perovskite Films by Metal Additives to the Single-Step Solution Fabrication Process

MRS Advances ◽  
2018 ◽  
Vol 3 (55) ◽  
pp. 3237-3242 ◽  
Author(s):  
Zahrah S. Almutawah ◽  
Suneth C. Watthage ◽  
Zhaoning Song ◽  
Ramez H. Ahangharnejhad ◽  
Kamala K. Subedi ◽  
...  
Keyword(s):  
Grain Size ◽  
Solar Cells ◽  
High Performance ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Precursor Solution ◽  
Single Step ◽  
Fabrication Process ◽  
Lead Iodide ◽  
Methylammonium Lead Iodide

ABSTRACTMethods of obtaining large grain size and high crystallinity in absorber materials play an important role in fabrication of high-performance methylammonium lead iodide (MAPbI3) perovskite solar cells. Here we study the effect of adding small concentrations of Cd2+, Zn2+, and Fe2+salts to the perovskite precursor solution used in the single-step solution fabrication process. Enhanced grain size and crystallinity in MAPbI3 films were obtained by using 0.1% of Cd2+ or Zn2+in the precursor solution. Consequently, solar cells constructed with Cd- and Zn-doped perovskite films show a significant improvement in device performance. These results suggest that the process may be an effective and facile method to fabricate high-efficiency perovskite photovoltaic devices.

scholarly journals Intermediate Phase‐Free Process for Methylammonium Lead Iodide Thin Film for High‐Efficiency Perovskite Solar Cells

2021 ◽  
pp. 2102492
Author(s):  
Yeonghun Yun ◽  
Devthade Vidyasagar ◽  
Minho Lee ◽  
Oh Yeong Gong ◽  
Jina Jung ◽  
...  
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
High Efficiency ◽  
Intermediate Phase ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Free Process ◽  
Methylammonium Lead Iodide

scholarly journals The dynamics of methylammonium ions in hybrid organic–inorganic perovskite solar cells

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Aurelien M. A. Leguy ◽  
Jarvist Moore Frost ◽  
Andrew P. McMahon ◽  
Victoria Garcia Sakai ◽  
W. Kockelmann ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Time Window ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
High Efficiency Solar Cells ◽  
Scattering Measurements ◽  
Quasielastic Neutron ◽  
Methylammonium Lead Iodide

Abstract Methylammonium lead iodide perovskite can make high-efficiency solar cells, which also show an unexplained photocurrent hysteresis dependent on the device-poling history. Here we report quasielastic neutron scattering measurements showing that dipolar CH3NH3 + ions reorientate between the faces, corners or edges of the pseudo-cubic lattice cages in CH3NH3PbI3 crystals with a room temperature residence time of ∼14 ps. Free rotation, π-flips and ionic diffusion are ruled out within a 1–200-ps time window. Monte Carlo simulations of interacting CH3NH3 + dipoles realigning within a 3D lattice suggest that the scattering measurements may be explained by the stabilization of CH3NH3 + in either antiferroelectric or ferroelectric domains. Collective realignment of CH3NH3 + to screen a device’s built-in potential could reduce photovoltaic performance. However, we estimate the timescale for a domain wall to traverse a typical device to be ∼0.1–1 ms, faster than most observed hysteresis.

scholarly journals Mixed Formamidinium-Methylammonium Lead Iodide perovskite from first-principles: Hydrogen-bonding impact on the electronic properties

2021 ◽  
Author(s):  
Maximiliano Alejandro Senno ◽  
Silvia Tinte
Keyword(s):  
Hydrogen Bonding ◽  
Electronic Properties ◽  
First Principles ◽  
Organic Cations ◽  
Lead Iodide ◽  
Improved Stability ◽  
Methylammonium Lead Iodide

Hybrid perovskites with mixed organic cations such as methylammonium (CH3NH3, MA) and formamidinium (CH(NH2)2, FA) have attracted interest due to their improved stability and capability to tune their properties varying...

scholarly journals High efficiency single-junction semitransparent perovskite solar cells

2014 ◽  
Vol 7 (9) ◽  
pp. 2968-2973 ◽  
Author(s):  
Cristina Roldán-Carmona ◽  
Olga Malinkiewicz ◽  
Rafael Betancur ◽  
Giulia Longo ◽  
Cristina Momblona ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Single Junction ◽  
Methylammonium Lead Iodide

Semitransparent efficient methylammonium lead iodide perovskite based solar cells.

Enhanced thermal and moisture stability via dual additives approach in methylammonium lead iodide based planar perovskite solar cells

Solar Energy ◽  
2021 ◽  
Vol 225 ◽  
pp. 200-210
Author(s):  
Rahul Ranjan ◽  
Sudhir Ranjan ◽  
Monali Monalisa ◽  
Kanwar Singh Nalwa ◽  
Anand Singh ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Moisture Stability ◽  
Methylammonium Lead Iodide
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