An advanced electrocatalyst for efficient synthesis of ammonia based on chemically coupled NiS@MoS2 heterostructured nanospheres

Author(s):  
Shoushuang Huang ◽  
Chunyan Gao ◽  
Peijun Xin ◽  
Haitao Wang ◽  
Xiao Liu ◽  
...  

Here, uniform NiS@MoS2 core–shell microspheres were controllably prepared by the in situ growth of MoS2 nanosheets on the nanoplates of NiS2–NiS hierarchical microspheres, and they exhibited efficient catalytic activity for ambient NRR reaction.

2017 ◽  
Vol 7 (3) ◽  
pp. 658-667 ◽  
Author(s):  
Xin Geng ◽  
Wentao Li ◽  
Feng Xiao ◽  
Dongsheng Wang ◽  
Lian Yang

Scheme of the visible light-Fenton-like catalytic reaction mechanism.


2019 ◽  
Vol 21 (16) ◽  
pp. 4334-4340 ◽  
Author(s):  
Kang-kang Sun ◽  
Jia-lin Sun ◽  
Guo-Ping Lu ◽  
Chun Cai

A cobalt catalyst derived from a unique core–shell structure based on hollow ZIF-8 and ZIF-67 is prepared for the synthesis of nitriles from alcohols in water under mild conditions.


RSC Advances ◽  
2016 ◽  
Vol 6 (92) ◽  
pp. 89450-89456 ◽  
Author(s):  
Qilu Yao ◽  
Zhang-Hui Lu ◽  
Yujuan Hu ◽  
Xiangshu Chen

Silver nanoparticles anchored on core–shell Co@SiO2 nanospheres (Co@SiO2/Ag) have been facilely prepared by using an in situ generated approach, and exhibited higher catalytic activity than their monometallic counterparts for the hydrolysis of AB.


2015 ◽  
Vol 3 (16) ◽  
pp. 8369-8379 ◽  
Author(s):  
Philippe Knauth ◽  
Howard Saltsburg ◽  
Johanna Engel ◽  
Harry L. Tuller

The impact of temperature and pO2 driven dopant redistribution and phase separation on thermo-mechanical, electrical and catalytic properties of Cu–doped CeO2 nanoparticles is explored.


1980 ◽  
Vol 45 (8) ◽  
pp. 2219-2223 ◽  
Author(s):  
Marie Jakoubková ◽  
Martin Čapka

Kinetics of homogenous hydrogenation of 1-heptene catalysed by rhodium(I) complexes prepared in situ from μ,μ'-dichloro-bis(cyclooctenerhodium) and phosphines of the type RP(C6H5)2 (R = -CH3, -(CH2)nSi(CH3)3; n = 1-4) have been studied. The substitution of the ligands by the trimethylsilyl group was found to increase significantly the catalytic activity of the complexes. The results are discussed in relation to the electron density on the phosphorus atom determined by 31P NMR spectroscopy and to its proton acceptor ability determined by IR spectroscopy.


2021 ◽  
Vol 714 (3) ◽  
pp. 032008
Author(s):  
Hongmei Li ◽  
Zhisheng Nong ◽  
Qian Xu ◽  
Qiushi Song ◽  
Ying Chen ◽  
...  

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