scholarly journals Generation of organo-alkaline earth metal complexes from non-polar unsaturated molecules and their synthetic applications

2021 ◽  
Author(s):  
Kohei Watanabe ◽  
Jia Hao Pang ◽  
Ryo TAKITA ◽  
Shunsuke Chiba
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Grignard Reagents ◽  
Alkaline Earth Metal ◽  
Synthetic Chemistry ◽  
Organomagnesium Compounds

Organomagnesium compounds, representated by the Grignard reagents, are one of the most classical yet versatile carbanion species which have widely been utilized in synthetic chemistry. These reagents are typically prepared...

C–H and C–F coordination of arenes in neutral alkaline earth metal complexes

2021 ◽  
Author(s):  
Jacob S. McMullen ◽  
Alison J. Edwards ◽  
Jamie Hicks
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Calcium Complexes ◽  
Group 2 ◽  
Rare Group

A series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feaure rare group 2 metal···aromatic...

Alkali and alkaline-earth metal complexes of different nuclearities with azamacrocyclic pendant-arms ligands

2009 ◽  
Vol 362 (9) ◽  
pp. 3351-3356 ◽  
Author(s):  
Luis Botana ◽  
Rufina Bastida ◽  
Alejandro Macías ◽  
Paulo Pérez-Lourido ◽  
Laura Valencia
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Pendant Arms

Highly Lewis acidic cationic alkaline earth metal complexes

2018 ◽  
Vol 54 (63) ◽  
pp. 8685-8688 ◽  
Author(s):  
Jürgen Pahl ◽  
Steffen Brand ◽  
Holger Elsen ◽  
Sjoerd Harder
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal

“Naked” cationic β-diketiminate Mg and Ca complexes possess high Lewis acidities and bind strongly to neutral benzene or alkyne ligands.

Sign in / Sign up

Export Citation Format

Share Document