The power of trichlorosilylation: isolable trisilylated allyl anions, allyl radicals, and allenyl anions

Chemical Science ◽

10.1039/d1sc03958j ◽

2021 ◽

Author(s):

Isabelle Georg ◽

Markus Bursch ◽

Burkhard Endeward ◽

Michael Bolte ◽

Hans-Wolfram Lerner ◽

...

Keyword(s):

Allyl Anions

Treatment of hexachloropropene (Cl2C=C(Cl)–CCl3) with Si2Cl6 and [nBu4N]Cl (1:4:1) in CH2Cl2 results in a quantitative conversion to the trisilylated, dichlorinated allyl anion salt [nBu4N][Cl2C=C(SiCl3)−C(SiCl3)2] ([nBu4N][1]). Tetrachloroallene Cl2C=C=CCl2 was identified as...

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ChemInform Abstract: BLDG. EINES ALLYL-ANIONS AUS DEM DELTA(1)-PYRAZOLINYL-(4)-ANION DURCH CYCLOREVERSION, ELEKTRONISCHER PROTOTYP DER 1,3-DIPOLAREN CYCLOADDITION

Chemischer Informationsdienst ◽

10.1002/chin.197220130 ◽

1972 ◽

Vol 3 (20) ◽

pp. no-no

Author(s):

PETER EBERHARD ◽

ROLF HUISGEN

Keyword(s):

Allyl Anions

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Heteroatom-Substituted Allyl Anions

Category 4, Compounds with Two Carbon Heteroatom Bonds ◽

10.1055/sos-sd-025-00262 ◽

2007 ◽

pp. 1

Author(s):

R. Göttlich

Keyword(s):

Allyl Anions

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ChemInform Abstract: FORMATION AND REACTIVITY OF 1-PHOSPHORYL-1-(PHOSPHORYLOXY)ALLYL ANIONS AND RELATED COMPOUNDS

Chemischer Informationsdienst ◽

10.1002/chin.198445256 ◽

1984 ◽

Vol 15 (45) ◽

Author(s):

H. AHLBRECHT ◽

W. FARNUNG ◽

H. SIMON

Keyword(s):

Allyl Anions ◽

Related Compounds

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ChemInform Abstract: Regioselective Control of Allyl Anions with Cadmium Chloride: α vs. γ Condensation with Aldehydes.

ChemInform ◽

10.1002/chin.198713172 ◽

1987 ◽

Vol 18 (13) ◽

Author(s):

L. BO ◽

A. G. FALLIS

Keyword(s):

Cadmium Chloride ◽

Allyl Anions

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Substituent effects in the gas phase: 1-substituted allyl anions

Journal of the American Chemical Society ◽

10.1021/ja00015a008 ◽

1991 ◽

Vol 113 (15) ◽

pp. 5566-5573 ◽

Cited By ~ 17

Author(s):

Gregg D. Dahlke ◽

Steven R. Kass

Keyword(s):

Gas Phase ◽

Phase 1 ◽

Substituent Effects ◽

Allyl Anions

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A DFT proton affinity study of vinyl and allyl anions of cyclic vinyl ethers and cycloalkenes

Tetrahedron Letters ◽

10.1016/s0040-4039(99)01201-0 ◽

1999 ◽

Vol 40 (34) ◽

pp. 6149-6152 ◽

Cited By ~ 3

Author(s):

Trevor D. Power ◽

John F. Sebastian

Keyword(s):

Proton Affinity ◽

Vinyl Ethers ◽

Allyl Anions

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The photoexcited states of allyl anions

Accounts of Chemical Research ◽

10.1021/ar00129a002 ◽

1986 ◽

Vol 19 (9) ◽

pp. 268-273 ◽

Cited By ~ 19

Author(s):

Laren M. Tolbert

Keyword(s):

Allyl Anions

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ChemInform Abstract: REGIO- AND STEREOSELECTIVE REACTION OF 1,3-DISUBSTITUTED ALLYL ANIONS WITH ALDEHYDES VIA η3-ALLYLTITANIUM COMPOUNDS

Chemischer Informationsdienst ◽

10.1002/chin.198352254 ◽

1983 ◽

Vol 14 (52) ◽

Author(s):

F. SATO ◽

H. UCHIYAMA ◽

K. IIDA ◽

Y. KOBAYASHI ◽

M. SATO

Keyword(s):

Stereoselective Reaction ◽

Allyl Anions

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ChemInform Abstract: Palladium-Catalyzed Selective Activation of Allyl Alcohols as Allyl Cations, Allyl Anions, and Zwitterionic Trimethylenemethanes

ChemInform ◽

10.1002/chin.200843244 ◽

2008 ◽

Vol 39 (43) ◽

Author(s):

Yoshinao Tamaru ◽

Masanari Kimura

Keyword(s):

Selective Activation ◽

Palladium Catalyzed ◽

Allyl Alcohols ◽

Allyl Anions

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ChemInform Abstract: Ring-Opening of N-Tosylaziridines by Heterosubstituted Allyl Anions. Application to the Synthesis of Azetidines and Pyrrolidines.

ChemInform ◽

10.1002/chin.199945058 ◽

2010 ◽

Vol 30 (45) ◽

pp. no-no

Author(s):

Hans-Joachim Breternitz ◽

Ernst Schaumann

Keyword(s):

Ring Opening ◽

Allyl Anions

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