scholarly journals Ion polarisation-assisted hydrogen-bonded ferroelectrics in liquid crystalline domains

2021 ◽  
Author(s):  
Guohao Yuan ◽  
Yuko Kimura ◽  
Takayuki Kobayashi ◽  
Takashi Takeda ◽  
Norihisa Hoshino ◽  
...  

An alkylamide-substituted (−NHCOC10H21) hydrogen-bonded dibenzo[18]crown-6 derivative (1) was prepared to stabilise the ionic channel structure in a discotic hexagonal columnar (Colh) liquid crystal.

Author(s):  
Beatriz Feringán ◽  
Roberto Termine ◽  
Attilio Golemme ◽  
Jose M. Granadino-Roldan ◽  
Amparo Navarro ◽  
...  

Despite the fact that triphenylamine derivatives have been widely explored as hole-transporting materials, studies on charge transport properties in the liquid crystal phase have been overlooked. Here, it is reported...


Sensors ◽  
2020 ◽  
Vol 20 (23) ◽  
pp. 6789
Author(s):  
Katarzyna A. Rutkowska ◽  
Anna Kozanecka-Szmigiel

Tunable diffraction gratings and phase filters are important functional devices in optical communication and sensing systems. Polarization gratings, in particular, capable of redirecting an incident light beam completely into the first diffraction orders may be successfully fabricated in liquid crystalline cells assembled from substrates coated with uniform transparent electrodes and orienting layers that force a specific molecular distribution. In this work, the diffraction properties of liquid crystal (LC) cells characterized by a continually rotating cycloidal director pattern at the cell substrates and in the bulk, are studied theoretically by solving a relevant set of the Euler-Lagrange equations. The electric tunability of the gratings is analyzed by estimating the changes in liquid crystalline molecular distribution and thus in effective birefringence, as a function of external voltage. To the best of our knowledge, such detailed numerical calculations have not been presented so far for liquid crystal polarization gratings showing a cycloidal director pattern. Our theoretical predictions may be easily achieved in experimental conditions when exploiting, for example, photo-orienting material, to induce a permanent LC alignment with high spatial resolution. The proposed design may be for example, used as a tunable passband filter with adjustable bandwidths, thus allowing for potential applications in optical spectroscopy, optical communication networks, remote sensing and beyond.


2002 ◽  
Vol 80 (8) ◽  
pp. 1162-1165 ◽  
Author(s):  
B Henrissat ◽  
G K Hamer ◽  
M G Taylor ◽  
R H Marchessault

A series of dodecyl 1-thio-β-D-glycosides has been synthesized and characterized (DSC, NMR, CP MAS, X-ray diffraction) as possible new marking materials with liquid-crystalline properties. These compounds undergo solid to liquid crystal phase transitions at various temperatures, which depend on the nature of the carbohydrate part of the structure. Their liquid-crystalline phases show extreme shear thinning behaviour.Key words: liquid crystal, powder X-ray diffraction, phase transition, thioglycoside, solid-state NMR, marking material


2002 ◽  
Vol 65 (5) ◽  
Author(s):  
S. Park ◽  
R. L. Leheny ◽  
R. J. Birgeneau ◽  
J.-L. Gallani ◽  
C. W. Garland ◽  
...  

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