Asymmetric Hydrogenation of Exocyclic γ,δ-Unsaturated β-Ketoesters to Functionalized Chiral Allylic Alcohols via Dynamic Kinetic Resolution
Keyword(s):
An iridium catalyzed asymmetric hydrogenation of racemic exocyclic γ,δ-unsaturated β-ketoesters via dynamic kinetic resolution to functionalized chiral allylic alcohols was developed. With chiral spiro iridium catalysts Ir-SpiroPAP a series of...
Keyword(s):
2007 ◽
Vol 129
(7)
◽
pp. 1868-1869
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2006 ◽
Vol 17
(4)
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pp. 481-485
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