scholarly journals A high-spin diradical dianion and its bridged chemically switchable single-molecule magnet

2021 ◽  
Author(s):  
Haiyan Cui ◽  
Zhaobo Hu ◽  
Chao Chen ◽  
Huapeng Ruan ◽  
Yong Fang ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Triplet Energy ◽  
Single Molecule Magnet ◽  
Organic Spintronics ◽  
Energy Gaps ◽  
Organic Magnets ◽  
Spin Filters ◽  
Promising Application

Triplet diradicals have attracted tremendous attention due to their promising application in organic spintronics, organic magnets and spin filters. However, very few examples of triplet diradicals with singlet-triplet energy gaps...

scholarly journals A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

2017 ◽  
Vol 53 (39) ◽  
pp. 5416-5419 ◽  
Author(s):  
Pavel E. Kazin ◽  
Mikhail A. Zykin ◽  
Lev A. Trusov ◽  
Artem A. Eliseev ◽  
Oxana V. Magdysyuk ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Energy Barrier ◽  
High Energy ◽  
Magnetization Relaxation ◽  
Single Molecule Magnet ◽  
High Energy Barrier ◽  
Spin Reversal ◽  
Type Lattice ◽  
Apatite Type

A Co-ion introduced into the trigonal channel of an apatite-type lattice forms a magnetically anisotropic two-coordinated Co-complex with a record-high spin-reversal energy barrier.

High-Spin Cyclopentadienyl Complexes: A Single-Molecule Magnet Based on the Aryl-Iron(II) Cyclopentadienyl Type

2011 ◽  
Vol 17 (17) ◽  
pp. 4700-4704 ◽  
Author(s):  
Daniel Weismann ◽  
Yu Sun ◽  
Yanhua Lan ◽  
Gotthelf Wolmershäuser ◽  
Annie K. Powell ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Cyclopentadienyl Complexes

“Spin Tweaking” of a High-Spin Molecule: An Mn25 Single-Molecule Magnet with anS=61/2 Ground State

2007 ◽  
Vol 46 (6) ◽  
pp. 884-888 ◽  
Author(s):  
Theocharis C. Stamatatos ◽  
Khalil A. Abboud ◽  
Wolfgang Wernsdorfer ◽  
George Christou
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Ground State ◽  
Single Molecule Magnet

A new Mn25 single-molecule magnet with an S=61/2 ground state arising from ligand-induced ‘spin-tweaking’ in a high-spin molecule

Polyhedron ◽  
2007 ◽  
Vol 26 (9-11) ◽  
pp. 2095-2100 ◽  
Author(s):  
Theocharis C. Stamatatos ◽  
Khalil A. Abboud ◽  
Wolfgang Wernsdorfer ◽  
George Christou
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Ground State ◽  
Single Molecule Magnet

scholarly journals Cover Picture: High-Spin Cyclopentadienyl Complexes: A Single-Molecule Magnet Based on the Aryl-Iron(II) Cyclopentadienyl Type (Chem. Eur. J. 17/2011)

2011 ◽  
Vol 17 (17) ◽  
pp. 4661-4661 ◽  
Author(s):  
Daniel Weismann ◽  
Yu Sun ◽  
Yanhua Lan ◽  
Gotthelf Wolmershäuser ◽  
Annie K. Powell ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Cyclopentadienyl Complexes

Air stable high-spin blatter diradicals: non-Kekulé versus Kekulé structures

2019 ◽  
Vol 7 (22) ◽  
pp. 6559-6563 ◽  
Author(s):  
Xiaoguang Hu ◽  
Lei Zhao ◽  
Hanjiao Chen ◽  
Yousong Ding ◽  
Yan-Zhen Zheng ◽  
...  
Keyword(s):  
Excited State ◽  
High Spin ◽  
Ground States ◽  
Triplet Excited State ◽  
Kekulé Structures ◽  
Triplet Energy ◽  
Energy Gaps

1,2,4-Benzotriazinyl based stable diradicals possess singlet ground states and small singlet–triplet energy gaps with a thermal accessible triplet excited state.

Analyzing the enforcement of a high-spin ground state for a metallacrown single-molecule magnet

2016 ◽  
Vol 93 (17) ◽  
Author(s):  
P. Happ ◽  
A. Sapozhnik ◽  
J. Klanke ◽  
P. Czaja ◽  
A. Chernenkaya ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Ground State ◽  
Single Molecule Magnet ◽  
Spin Ground State
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