scholarly journals Probe metal binding mode of imine covalent organic frameworks: cycloiridation for (photo)catalytic hydrogen evolution from formate

2021 ◽  
Author(s):  
Jiyun Hu ◽  
Hamed Mehrabi ◽  
Yin-Shan Meng ◽  
Maddison Taylor ◽  
Jin-Hui Zhan ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Metal Binding ◽  
High Stability ◽  
Binding Mode ◽  
Covalent Organic Frameworks ◽  
High Efficacy ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Evolution ◽  
Formate Solution

This study describes cyclometallation as a new metal binding mode for imine-based COFs. The iridacycle decorated COF could be used for catalytic hydrogen evolution from aqueous formate solution with high stability and high efficacy.

Chalcogen-vacancy group VI transition metal dichalcogenide nanosheets for electrochemical and photoelectrochemical hydrogen evolution

2021 ◽  
Vol 9 (1) ◽  
pp. 101-109
Author(s):  
In Hye Kwak ◽  
Ik Seon Kwon ◽  
Jong Hyun Lee ◽  
Young Rok Lim ◽  
Jeunghee Park
Keyword(s):  
Transition Metal ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Photoelectrochemical Cells ◽  
Transition Metal Dichalcogenide ◽  
Group Vi ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Evolution

Chalcogen vacancies of MoS2, MoSe2, WS2, and WSe2 nanosheets enhanced the catalytic hydrogen evolution reaction in solar photoelectrochemical cells.

Synthesis of two new copper-sandwiched polyoxotungstates and the influence of nuclear number on catalytic hydrogen evolution activity

2020 ◽  
Vol 44 (26) ◽  
pp. 11035-11041
Author(s):  
Zhao-Min Su ◽  
Mo Zhang ◽  
Qingqing An ◽  
Dan Qin ◽  
Hai-Lou Li ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Hydrogen Evolution ◽  
Catalytic Hydrogen ◽  
Nuclear Number ◽  
Catalytic Hydrogen Evolution ◽  
Two Hybrid

Two hybrid inorganic–organic CuII-sandwiched POM were synthesized and they exhibit photocatalytic activity. This would guide us to prepared copper-substituted polyoxotungstate and apply them toward renew energy.

Intercalation of cobaltocene into WS2 nanosheets for enhanced catalytic hydrogen evolution reaction

2019 ◽  
Vol 7 (14) ◽  
pp. 8101-8106 ◽  
Author(s):  
In Hye Kwak ◽  
Hafiz Ghulam Abbas ◽  
Ik Seon Kwon ◽  
Yun Chang Park ◽  
Jaemin Seo ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Functional Theory ◽  
Spin Polarized ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Evolution ◽  
Ws2 Nanosheets

Cobaltocene-intercalated WS2 nanosheets exhibit excellent catalytic activity toward the hydrogen evolution reaction, which is supported by spin-polarized density functional theory calculations.

Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting

Science ◽  
2014 ◽  
Vol 345 (6202) ◽  
pp. 1326-1330 ◽  
Author(s):  
B. Rausch ◽  
M. D. Symes ◽  
G. Chisholm ◽  
L. Cronin
Keyword(s):  
Metal Oxide ◽  
Hydrogen Evolution ◽  
Water Splitting ◽  
Redox Mediator ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Evolution
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