scholarly journals Imidazolium-modification enables enhanced photocatalytic CO2 reduction on ZnSe quantum dots

2021 ◽  
Author(s):  
Constantin Sahm ◽  
Eric Mates-Torres ◽  
Nora Eliasson ◽  
Kamil Sokolowski ◽  
Andreas Wagner ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Low Cost ◽  
Co2 Reduction ◽  
Solar Light ◽  
Product Selectivity ◽  
Carbon Based

Colloidal photocatalysts are a promising, low-cost material to utilize solar light for the conversion of CO2 to carbon-based fuels, but controlling the product selectivity for CO2 reduction remains challenging, in...

scholarly journals Defect Engineering on Carbon-Based Catalysts for Electrocatalytic CO2 Reduction

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Dongping Xue ◽  
Huicong Xia ◽  
Wenfu Yan ◽  
Jianan Zhang ◽  
Shichun Mu
Keyword(s):  
High Performance ◽  
Carbon Materials ◽  
Catalytic Mechanism ◽  
Low Cost ◽  
Co2 Reduction ◽  
Research Progress ◽  
Long Term Stability ◽  
Challenges And Opportunities ◽  
Carbon Based Nanomaterials ◽  
Carbon Based

Abstract Electrocatalytic carbon dioxide (CO2) reduction (ECR) has become one of the main methods to close the broken carbon cycle and temporarily store renewable energy, but there are still some problems such as poor stability, low activity, and selectivity. While the most promising strategy to improve ECR activity is to develop electrocatalysts with low cost, high activity, and long-term stability. Recently, defective carbon-based nanomaterials have attracted extensive attention due to the unbalanced electron distribution and electronic structural distortion caused by the defects on the carbon materials. Here, the present review mainly summarizes the latest research progress of the construction of the diverse types of defects (intrinsic carbon defects, heteroatom doping defects, metal atomic sites, and edges detects) for carbon materials in ECR, and unveil the structure–activity relationship and its catalytic mechanism. The current challenges and opportunities faced by high-performance carbon materials in ECR are discussed, as well as possible future solutions. It can be believed that this review can provide some inspiration for the future of development of high-performance ECR catalysts.

Graphene Supported Tungsten Carbide as Catalyst for Electrochemical Reduction of CO2

2019 ◽  
Author(s):  
Sahithi Ananthaneni ◽  
Rees Rankin
Keyword(s):  
Tungsten Carbide ◽  
Electrochemical Reduction ◽  
Low Cost ◽  
Co2 Reduction ◽  
Platinum Group Metal ◽  
Reduction Reaction ◽  
Metal Carbides ◽  
Depth Study ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

<div>Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) are proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence can be good substitutes for some important reduction reactions. In this work, we test graphenesupported WC (Tungsten Carbide) nanocluster as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform DFT studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and develop more efficient electrocatalysts for CO2 reduction.<br></div>

scholarly journals Titanium Nitride Nanodonuts Synthesized from Natural Ilmenite Ore as a Novel and Efficient Thermoplasmonic Material

Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 76
Author(s):  
Thanh-Lieu Thi Le ◽  
Lam Tan Nguyen ◽  
Hoai-Hue Nguyen ◽  
Nguyen Van Nghia ◽  
Nguyen Minh Vuong ◽  
...  
Keyword(s):  
Titanium Nitride ◽  
Low Cost ◽  
Visible Region ◽  
Resonance Absorption ◽  
Solar Light ◽  
Localized Surface Plasmon ◽  
Water Evaporation ◽  
Energy Applications ◽  
Simulated Solar Light ◽  
New Class

Nanostructures of titanium nitride (TiN) have recently been considered as a new class of plasmonic materials that have been utilized in many solar energy applications. This work presents the synthesis of a novel nanostructure of TiN that has a nanodonut shape from natural ilmenite ore using a low-cost and bulk method. The TiN nanodonuts exhibit strong and spectrally broad localized surface plasmon resonance absorption in the visible region centered at 560 nm, which is well suited for thermoplasmonic applications as a nanoscale heat source. The heat generation is investigated by water evaporation experiments under simulated solar light, demonstrating excellent solar light harvesting performance of the nanodonut structure.

scholarly journals Effects of CsSnxPb1−xI3 Quantum Dots as Interfacial Layer on Photovoltaic Performance of Carbon-Based Perovskite Solar Cells

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Chi Zhang ◽  
Zhiyuan He ◽  
Xuanhui Luo ◽  
Rangwei Meng ◽  
Mengwei Chen ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Solar Cells ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Photogenerated Electron ◽  
Depletion Region ◽  
Band Alignment ◽  
Back Surface ◽  
The One ◽  
Carbon Based

AbstractIn this work, inorganic tin-doped perovskite quantum dots (PQDs) are incorporated into carbon-based perovskite solar cells (PSCs) to improve their photovoltaic performance. On the one hand, by controlling the content of Sn2+ doping, the energy level of the tin-doped PQDs can be adjusted, to realize optimized band alignment and enhanced separation of photogenerated electron–hole pairs. On the other hand, the incorporation of tin-doped PQDs provided with a relatively high acceptor concentration due to the self-p-type doping effect is able to reduce the width of the depletion region near the back surface of the perovskite, thereby enhancing the hole extraction. Particularly, after the addition of CsSn0.2Pb0.8I3 quantum dots (QDs), improvement of the power conversion efficiency (PCE) from 12.80 to 14.22% can be obtained, in comparison with the pristine device. Moreover, the experimental results are analyzed through the simulation of the one-dimensional perovskite/tin-doped PQDs heterojunction.

scholarly journals Defect and Doping Co-Engineered Non-Metal Nanocarbon ORR Electrocatalyst

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Jian Zhang ◽  
Jingjing Zhang ◽  
Feng He ◽  
Yijun Chen ◽  
Jiawei Zhu ◽  
...  
Keyword(s):  
Rational Design ◽  
Low Cost ◽  
Reduction Reaction ◽  
Defect Engineering ◽  
Heteroatom Doping ◽  
Competitive Activity ◽  
Design And Manufacturing ◽  
Earth Abundant ◽  
Induced Defects ◽  
Carbon Based

AbstractExploring low-cost and earth-abundant oxygen reduction reaction (ORR) electrocatalyst is essential for fuel cells and metal–air batteries. Among them, non-metal nanocarbon with multiple advantages of low cost, abundance, high conductivity, good durability, and competitive activity has attracted intense interest in recent years. The enhanced ORR activities of the nanocarbons are normally thought to originate from heteroatom (e.g., N, B, P, or S) doping or various induced defects. However, in practice, carbon-based materials usually contain both dopants and defects. In this regard, in terms of the co-engineering of heteroatom doping and defect inducing, we present an overview of recent advances in developing non-metal carbon-based electrocatalysts for the ORR. The characteristics, ORR performance, and the related mechanism of these functionalized nanocarbons by heteroatom doping, defect inducing, and in particular their synergistic promotion effect are emphatically analyzed and discussed. Finally, the current issues and perspectives in developing carbon-based electrocatalysts from both of heteroatom doping and defect engineering are proposed. This review will be beneficial for the rational design and manufacturing of highly efficient carbon-based materials for electrocatalysis.

Surface Passivation by Congeneric Quantum Dots for High-Performance and Stable CsPbBr3-Based Photodetectors

2021 ◽  
Author(s):  
Shikai Yan ◽  
Sheng Tang ◽  
Manman Luo ◽  
Lu Xue ◽  
Shilin Liu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
High Performance ◽  
Surface Passivation ◽  
Low Cost ◽  
Optoelectronic Properties ◽  
Solution Processing

CsPbBr3-based photodetectors (PDs) have aroused enormous attention owing to their low-cost solution processing, outstanding optoelectronic properties, and remarkable stability. However, their performances remain a big challenge to meet the requirement...

scholarly journals Three-dimensional self-attaching perovskite quantum dots/polymer platform for efficient solar-driven CO2 reduction

2021 ◽  
Vol 17 ◽  
pp. 100358
Author(s):  
R. Cheng ◽  
C.-C. Chung ◽  
S. Wang ◽  
B. Cao ◽  
M. Zhang ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Three Dimensional ◽  
Co2 Reduction ◽  
Perovskite Quantum Dots

Effective Measures for CO2 Reduction Harnessing the Potential Water Energy Present in the Water Service Industry

2010 ◽  
Vol 5 (3) ◽  
Author(s):  
Ohbuchi Yoshihiro ◽  
Sasaki Takanori ◽  
Sumitomo Hiroaki ◽  
Saito Susumu ◽  
Tanaka Yoshiaki
Keyword(s):  
Power Generation ◽  
Water Purification ◽  
Service Industry ◽  
Low Cost ◽  
Co2 Reduction ◽  
Clean Energy ◽  
Net Benefit ◽  
Private Company ◽  
Joint Project ◽  
Purification Plant

Sapporo Waterworks Bureau's (SWB's) measures for CO2 reduction started in 1982 with a hydropower project at the Moiwa Water Purification Plant (MWPP) (cap. 155,000 m3/day). Operation of the generator was temporarily discontinued in 2001 for full-scale reconstruction of the water purification plant (WPP); after the completion of the reconstruction, the power generation equipment was renewed, and the operation resumed as a joint project with a private company in 2007. Power generation is on-site since the hydropower generator within the MWPP area provides energy consumed at the MWPP and the adjoining Waterworks Museum. This power generation is expected to create an energy saving effect equivalent to 1,500 tons of CO2 and over 10 million yen of annual net benefit. In order to increase the usage rate of low-cost, clean energy like hydropower at the WPP, SWB has made a series of adjustments to the operating methods of the plant. Then, as a result, the generation covers 97% of the energy used on-site at present. Furthermore, SWB is considering introducing other hydropower facilities of this kind that harness water transmission energy from the Shiraikawa WPP (cap. 650,000 m3/day) to the major distribution reservoirs.

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