scholarly journals Alloying a Single and a Double Perovskite: A Cu+/2+ Mixed-Valence Layered Halide Perovskite with Strong Optical Absorption

2021 ◽  
Author(s):  
Bridget Connor ◽  
Rebecca Smaha ◽  
Jiayi Li ◽  
Aryeh Gold-Parker ◽  
Alexander Heyer ◽  
...  

Introducing heterovalent cations at the octahedral sites of halide perovskites can substantially change their optoelectronic properties. Yet, in most cases, only small amounts of such metals can be incorporated as...

2020 ◽  
Vol 8 (20) ◽  
pp. 10439-10449
Author(s):  
Klara Suchan ◽  
Justus Just ◽  
Pascal Becker ◽  
Eva L. Unger ◽  
Thomas Unold

Optical in situ monitoring tracks crystallization and optoelectronic properties of halide perovskites during growth in a glovebox environment.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Chunlong Li ◽  
Jie Li ◽  
Zhengping Li ◽  
Huayong Zhang ◽  
Yangyang Dang ◽  
...  

Nanostructured halide perovskites have highly yielded record LEDs due to their higher versatility in the local management of charge carriers, which has enabled photoluminescence quantum yields (PLQYs) close to 100%....


2021 ◽  
Author(s):  
Arindam Mondal ◽  
Akash Lata ◽  
Aarya Prabhakaran ◽  
Satyajit Gupta

Application of three-dimensional (3D)-halide perovskites (HaP) in photocatalysis encourages the new exercise with two-dimensional (2D) HaP based thin-films for photocatalytic degradation of dye. The reduced dimensionality to 2D-HaPs, with a...


2021 ◽  
Vol 91 ◽  
pp. 106077
Author(s):  
Faiza Jan Iftikhar ◽  
Qamar Wali ◽  
Shengyuan Yang ◽  
Yaseen Iqbal ◽  
Rajan Jose ◽  
...  

Author(s):  
Qiuqi Li ◽  
Dan Cao ◽  
Xueyin Liu ◽  
Xiangyu Zhou ◽  
Xiaoshuang Chen ◽  
...  

A hierarchical computational screening method is used to find layered lead-free metal halide perovskites with high stability and outstanding optoelectronic properties.


Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Zhifang Tan ◽  
Jincong Pang ◽  
Guangda Niu ◽  
Jun-Hui Yuan ◽  
Kan-Hao Xue ◽  
...  

Abstract Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x Te x Cl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators.


Author(s):  
Avija Ajayakumar ◽  
Chinnadurai Muthu ◽  
Amarjith V. Dev ◽  
Johnpaul K. Pious ◽  
Chakkooth Vijayakumar

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