An activated carbon fiber supported Fe2O3@bismuth carbonate heterojunction for enhanced visible light degradation of emerging pharmaceutical pollutants

Author(s):  
Prasenjit Kar ◽  
Komal Shukla ◽  
Pratyush Jain ◽  
Raju Kumar Gupta

The developed Fe2O3@BC heterojunction photocatalyst supported over activated carbon fiber exhibited efficient photocatalytic activity for degradation of antipyrine under visible light irradiation.

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Kui Mao ◽  
Xiaowen Wu ◽  
Xin Min ◽  
Zhaohui Huang ◽  
Yan-gai Liu ◽  
...  

Abstract To improve the catalyst properties of TiO2 under visible light irradiation, chitin-modified TiO2 was synthesized via a hydrothermal method on the surface of carbon fibers. The microstructure and interface properties of the so-prepared photocatalyst were investigated via X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-visible diffuse reflectance spectroscopy. Our results indicated that the synergetic effect of the crystal phase of TiO2, carbon fiber, and chitin is the main reason leading to the improvement of the photocatalytic activity of the composite catalyst. The modified TiO2 sample with chitin content of 0.6 wt% exhibited the highest photocatalytic activity under visible light irradiation when RhB was chosen as the target degradation product. Compared to the pure TiO2/carbon fiber, the sample of TiO2/carbon fiber with 0.6 wt% of chitin exhibits enhanced visible light activity with an apparent rate of degradation about 2.25 times. The enhancement of the photocatalytic performance of the sample with chitin can be attributed to the relatively high adsorption capacity of the particular network structure and photosensitivity of chitin, which can effectively separate the photoelectron-hole pair recombination. Furthermore, the new composite photocatalyst shows excellent catalytic stability after multiple degradation cycles, indicating that it is a promising photocatalytic material for degrading organic pollutants in wastewater.


2015 ◽  
Vol 44 (5) ◽  
pp. 2267-2275 ◽  
Author(s):  
Tingting Lu ◽  
Xinxin Xu ◽  
Huili Li ◽  
Zhenyu Li ◽  
Xia Zhang ◽  
...  

NCC/POM/ACF composite material was successfully fabricated, and displays excellent photocatalytic activity in visible light.


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