scholarly journals Adjusting the photovoltaic performance of big fused ring-based small molecules by tailoring with different modifications

RSC Advances ◽  
2021 ◽  
Vol 11 (63) ◽  
pp. 39625-39635
Author(s):  
Min Li ◽  
Manjun Xiao ◽  
Zuojia Li

Three novel A–D–A type small-molecule donor materials, with anthanthrene (AAN) as the electron-donating core, and thiophene as π-bridge units, have been designed and synthesized for application in bulk-heterojunction (BHJ) organic solar cells (OSCs).

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ruimin Zhou ◽  
Zhaoyan Jiang ◽  
Chen Yang ◽  
Jianwei Yu ◽  
Jirui Feng ◽  
...  

AbstractThe high efficiency all-small-molecule organic solar cells (OSCs) normally require optimized morphology in their bulk heterojunction active layers. Herein, a small-molecule donor is designed and synthesized, and single-crystal structural analyses reveal its explicit molecular planarity and compact intermolecular packing. A promising narrow bandgap small-molecule with absorption edge of more than 930 nm along with our home-designed small molecule is selected as electron acceptors. To the best of our knowledge, the binary all-small-molecule OSCs achieve the highest efficiency of 14.34% by optimizing their hierarchical morphologies, in which the donor or acceptor rich domains with size up to ca. 70 nm, and the donor crystals of tens of nanometers, together with the donor-acceptor blending, are proved coexisting in the hierarchical large domain. All-small-molecule photovoltaic system shows its promising for high performance OSCs, and our study is likely to lead to insights in relations between bulk heterojunction structure and photovoltaic performance.


RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 93579-93590 ◽  
Author(s):  
C. H. Pavan Kumar ◽  
K. Ganesh ◽  
T. Suresh ◽  
Abhishek Sharma ◽  
K. Bhanuprakash ◽  
...  

Four new small molecules CSDPP9–CSDPP12 were obtained with appended electron donating units in the molecular terminals of a DPP core. On solvent and thermal annealing, for the CSDPP11:PC71BM blend, the BHJ device displayed a PCE of 5.47%.


2018 ◽  
Vol 20 (9) ◽  
pp. 6321-6329 ◽  
Author(s):  
Yogajivan Rout ◽  
Rajneesh Misra ◽  
Rahul Singhal ◽  
Subhayan Biswas ◽  
Ganesh D. Sharma

We have used two unsymmetrical small molecules with a D–A–D–π–D configuration as small molecule donors, along with PC71BM as an acceptor, for solution processed bulk heterojunction solar cells.


2016 ◽  
Vol 18 (25) ◽  
pp. 16950-16957 ◽  
Author(s):  
Yuvraj Patil ◽  
Rajneesh Misra ◽  
Abhishek Sharma ◽  
Ganesh D. Sharma

Two organic small molecules based on diketopyrrolopyrrole (DPP) units having a D–A–D–π–D–A–D structure denoted as DPP-DPP and DPPTDPP were synthesized.


2020 ◽  
Vol 4 (7) ◽  
pp. 2168-2175
Author(s):  
B. Yadagiri ◽  
K. Narayanaswamy ◽  
Towhid H. Chowdhury ◽  
Ashraful Islam ◽  
Vinay Gupta ◽  
...  

We report the synthesis and characterization of a dithienogermole (DTGe) based small molecule, named Ge-PO-2CN, as a donor material for bulk heterojunction (BHJ) organic solar cells (OSCs) and as a hole transport material (HTM) for dopant-free perovskite solar cells (PSCs).


2016 ◽  
Vol 4 (13) ◽  
pp. 4952-4961 ◽  
Author(s):  
Jianhua Chen ◽  
Linrui Duan ◽  
Manjun Xiao ◽  
Qiong Wang ◽  
Bin Liu ◽  
...  

A series of Ar(A–D)2 type small molecules containing a pyrene core were synthesized. A significantly improved power conversion efficiency of 5.88% was obtained for ThDPP2Py based organic solar cells.


2016 ◽  
Vol 18 (33) ◽  
pp. 22999-23005 ◽  
Author(s):  
Yuvraj Patil ◽  
Rajneesh Misra ◽  
F. C. Chen ◽  
Ganesh D. Sharma

We report two acetylene-bridged small molecules DPP5 and DPP6 with low HOMO–LUMO gaps as donors along with PC71BM as an acceptor for the fabrication of solution-processed bulk heterojunction solar cells.


RSC Advances ◽  
2015 ◽  
Vol 5 (9) ◽  
pp. 6286-6293 ◽  
Author(s):  
M. Nazim ◽  
Sadia Ameen ◽  
M. Shaheer Akhtar ◽  
Hyung-Kee Seo ◽  
Hyung-Shik Shin

Novel furan-bridged thiazolo[5,4-d]thiazole based π-conjugated organic chromophore (RFTzR) was formulated and utilized for the fabrication of solution-processed small molecule organic solar cells (SMOSCs).


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