scholarly journals Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission

RSC Advances ◽  
2021 ◽  
Vol 11 (55) ◽  
pp. 34735-34741
Author(s):  
Karina Nigoghossian ◽  
Alena N. Kulakova ◽  
Gautier Félix ◽  
Victor N. Khrustalev ◽  
Elena S. Shubina ◽  
...  

Tetranuclear silsesquioxane cages with tunable thermosensitive Tb3+-to-Eu3+ energy transfer were used for temperature sensing based on the Tb3+-to-Eu3+ emission intensity ratio (LIR) with excellent linearity and sensitivity.

2016 ◽  
Vol 4 (11) ◽  
pp. 2165-2169 ◽  
Author(s):  
Peng Li ◽  
Huanrong Li

We develop a luminescent platform based on Eu3+ and Tb3+ co-doped nanozeolite to realize the probing of amine solvents. Such a luminescence sensor can classify amine solvents and achieve an excellent fingerprint correlation between the amine solvents (with larger pKa values) and the emission intensity ratio (IEu/ITb), which is ratiometric.


2014 ◽  
Vol 1736 ◽  
Author(s):  
Kenjo Matsui ◽  
Kosuke Horikawa ◽  
Yugo Kozuka ◽  
Kazuki Ikeyama ◽  
Daisuke Komori ◽  
...  

ABSTRACTWe have fabricated light emitting diodes (LEDs) in which two active regions separated with a Mg-doped GaN intermediate layer were placed in a single pn junction toward periodic gain structures (PGS) for blue vertical-cavity surface emitting lasers (VCSELs). By current density dependence on a emission intensity ratio from two different active regions, we obtained a very stable emission intensity ratio over 1 kA/cm2. This result is also confirmed with the simulation result. Furthermore, we found that the difference of emission wavelength affect the carrier injection and the emission intensity ratio. On the basis of this result, the optimized well-balanced Mg concentration in the intermediate layer for the two identical active regions were estimated approximately 5 x 1018 cm-3.


Eos ◽  
2011 ◽  
Vol 92 (35) ◽  
pp. 291-292 ◽  
Author(s):  
Tom G. Slanger ◽  
Brian D. Sharpee ◽  
Dušan A. Pejaković ◽  
David L. Huestis ◽  
Manuel A. Bautista ◽  
...  

Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1375 ◽  
Author(s):  
Kniec ◽  
Ledwa ◽  
Marciniak

In this work the influence of the Ga3+ concentration on the luminescent properties and the abilities of the Y3Al5−xGaxO12: V nanocrystals to noncontact temperature sensing were investigated. It was shown that the increase of the Ga3+ amount enables enhancement of V4+ emission intensity in respect to the V3+ and V5+ and thus modify the color of emission. The introduction of Ga3+ ions provides the appearance of the crystallographic sites, suitable for V4+ occupation. Consequently, the increase of V4+ amount facilitates V5+ → V4+ interionic energy transfer throughout the shortening of the distance between interacting ions. The opposite thermal dependence of V4+ and V5+ emission intensities enables to create the bandshape luminescent thermometr of the highest relative sensitivity of V-based luminescent thermometers reported up to date (Smax, 2.64%/°C, for Y3Al2Ga3O12 at 0 °C). An approach of tuning the performance of Y3Al5−xGaxO12: V nanocrystals to luminescent temperature sensing, including the spectral response, maximal relative sensitivity and usable temperature range, by the Ga3+ doping was presented and discussed.


RSC Advances ◽  
2017 ◽  
Vol 7 (2) ◽  
pp. 694-703 ◽  
Author(s):  
Shuvaraj Ghosh ◽  
Durga Basak

An enhanced UV/VIS emission intensity ratio and UV photoresponse have been evidenced in the rapidly cooled sol–gel ZnO films.


2017 ◽  
Vol 36 (1) ◽  
Author(s):  
Seiichi Uchiyama ◽  
Chie Gota

AbstractRecently, numerous luminescent molecular thermometers that exhibit temperature-dependent emission properties have been developed to measure the temperatures of tiny spaces. Intracellular temperature is the most interesting and exciting applications of luminescent molecular thermometers because this temperature is assumed to be correlated with all cell events, such as cell division, gene expression, enzyme reaction, metabolism, and pathogenesis. Among the various types of temperature-dependent emission parameters of luminescent molecular thermometers, the emission intensity ratio at two different wavelengths is suitable for accurate and accessible intracellular temperature measurements. In this review article, luminescent molecular thermometers that exhibit a temperature-dependent emission intensity ratio in living cells are summarized, and current progress in intracellular thermometry is outlined.


2016 ◽  
Vol 7 (19) ◽  
pp. 3277-3299 ◽  
Author(s):  
Alaa S. Abd-El-Aziz ◽  
Amani A. Abdelghani ◽  
Brian D. Wagner ◽  
Elsayed M. Abdelrehim

A series of fluorescent dendrimers with pyrene moieties exhibited aggregation enhanced excimer emission (AEEE). Increases in the dendrimer generation caused emission at 480 nm with a high excimer/monomer emission intensity ratio.


2006 ◽  
Vol 60 (1) ◽  
pp. 61-64 ◽  
Author(s):  
Kenichiro Tsuyuki ◽  
Satoru Miura ◽  
Nasrullah Idris ◽  
Koo Hendrik Kurniawan ◽  
Tjung Jie Lie ◽  
...  

1968 ◽  
Vol 40 (1) ◽  
pp. 2-5
Author(s):  
Rodney K. Skogerboe ◽  
Rosemary. Todd ◽  
George Harold. Morrison

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