scholarly journals Rapid preparation of PAM/N-CNT nanocomposite hydrogels by DEM frontal polymerization and its performance study

RSC Advances ◽  
2021 ◽  
Vol 11 (56) ◽  
pp. 35268-35273
Author(s):  
Bin Li ◽  
Jizhen Liu ◽  
Dandan Fu ◽  
Yongjing Li ◽  
Xiaojia Xu ◽  
...  

In this study, a simple and eco-friendly method was proposed to efficiently prepare nanocomposite hydrogels with excellent mechanical properties and satisfactory pH response behaviour by frontal polymerization of DEM in close to 4 minutes.

Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1416 ◽  
Author(s):  
Pejman Heidarian ◽  
Abbas Z. Kouzani ◽  
Akif Kaynak ◽  
Ali Zolfagharian ◽  
Hossein Yousefi

It is an ongoing challenge to fabricate an electroconductive and tough hydrogel with autonomous self-healing and self-recovery (SELF) for wearable strain sensors. Current electroconductive hydrogels often show a trade-off between static crosslinks for mechanical strength and dynamic crosslinks for SELF properties. In this work, a facile procedure was developed to synthesize a dynamic electroconductive hydrogel with excellent SELF and mechanical properties from starch/polyacrylic acid (St/PAA) by simply loading ferric ions (Fe3+) and tannic acid-coated chitin nanofibers (TA-ChNFs) into the hydrogel network. Based on our findings, the highest toughness was observed for the 1 wt.% TA-ChNF-reinforced hydrogel (1.43 MJ/m3), which is 10.5-fold higher than the unreinforced counterpart. Moreover, the 1 wt.% TA-ChNF-reinforced hydrogel showed the highest resistance against crack propagation and a 96.5% healing efficiency after 40 min. Therefore, it was chosen as the optimized hydrogel to pursue the remaining experiments. Due to its unique SELF performance, network stability, superior mechanical, and self-adhesiveness properties, this hydrogel demonstrates potential for applications in self-wearable strain sensors.


2015 ◽  
Vol 1088 ◽  
pp. 444-448
Author(s):  
Xiao Wang ◽  
Pei Min Hou ◽  
Yuan Hao Xu ◽  
Jian Lei

In this paper, waterborne damping coating with excellent performance was prepared by self-made acrylic resin, and its physical and mechanical properties, chemical resistance, and damping properties (damping factor) were studied.


2014 ◽  
Vol 1022 ◽  
pp. 30-33
Author(s):  
Yi Chen ◽  
Jun Hong Yang ◽  
Wen Yong Liu ◽  
Guang Sheng Zeng

A novel POSS hybrid nanocomposite hydrogels were synthesized by introducing water-soluble Oa-POSS into the PVA hydrogels. The mechanical properties are obviously dependent on the composition of gels. With the increase of Oa-POSS, the tensile strength and modulus increases significantly while the elongation break decreases. The gels exhibit higher compression strength than pure PVA hydrogels. This phenomenon is attributed to the effective entanglement of polymer chains around nanoparticles and enhanced interaction between PVA chains.


2012 ◽  
Vol 706-709 ◽  
pp. 461-466 ◽  
Author(s):  
Alejandra Reyna-Valencia ◽  
P. Chevallier ◽  
D. Mantovani

Collagen hydrogels are widely used as three-dimensional scaffolds for cells and tissue in culture environments. These materials, which consist of crosslinked biopolymer (protein-based) networks in aqueous media, are particularly suitable for recreating part of the extra-cellular matrix, but their poor mechanical properties represent a major limitation. One strategy to enhance the strength of this kind of hydrogels might be to incorporate clay nanoscopic particles. In fact, it has been observed that the charged surface of clay nanosheets can interact with certain functional groups belonging to polymer molecules, yielding stronger networks. Moreover, clay particles are recognized to be biocompatible. In the present work, the gelation process and the resulting morphological and mechanical properties of collagen/laponite clay nanocomposite hydrogels were invastigated. Upon gelation, the biopolymer molecules assemble into nanoscale fibrils, which bundle into fibers and entangle into a three-dimensional network. The network characteristics depend on tunable parameters such as pH and clay concentration.


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