scholarly journals A highly selective pyridoxal-based chemosensor for the detection of Zn(ii) and application in live-cell imaging; X-ray crystallography of pyridoxal-TRIS Schiff-base Zn(ii) and Cu(ii) complexes

RSC Advances ◽  
2021 ◽  
Vol 11 (54) ◽  
pp. 34181-34192
Author(s):  
Anwar Hussain ◽  
Kadarkaraisamy Mariappan ◽  
Dawson C. Cork ◽  
Luke D. Lewandowski ◽  
Prem K. Shrestha ◽  
...  

The synthesis, characterization, X-ray crystallography, and live-cell imaging of pyridoxal-TRIS Schiff-base ligand which is selective as a luminescence sensor to detect Zn(ii) ion, and the corresponding Zn(ii) and Cu(ii) complexes are described.

The Analyst ◽  
2020 ◽  
Vol 145 (13) ◽  
pp. 4576-4586
Author(s):  
S. G. Jebastin Andrews ◽  
S. Benita Jeba Silviya ◽  
Dharmaraj Jeyanthi ◽  
E. Sathya Devi ◽  
J. Winfred Jebaraj ◽  
...  

An alkyne arms containing salen-type Schiff base ligand L acts as a dual sensor for CdII and PbII with well-separated excitation and emission wavelengths. The ligand L has been utilized in cell imaging studies for both metal ions.


Polyhedron ◽  
2021 ◽  
pp. 115288
Author(s):  
Krishna Chattopadhyay ◽  
Sayanti Datta ◽  
Santanu Dhara ◽  
Velerio Bertolasi ◽  
Debashis Ray

Author(s):  
Shabana Noor ◽  
Richard Goddard ◽  
Fehmeeda Khatoon ◽  
Sarvendra Kumar ◽  
Rüdiger W. Seidel

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.


2018 ◽  
Vol 42 (21) ◽  
pp. 17351-17358 ◽  
Author(s):  
Anup Kumar Bhanja ◽  
Snehasis Mishra ◽  
Ketaki Kar ◽  
Kaushik Naskar ◽  
Suvendu Maity ◽  
...  

An allyl-rhodamine Schiff base shows excellent palladium sensitivity (LOD, 95 nM) irrespective of Pd(0,ii,iv) and practical applicability is judged in living cells of RAW 264.7 (macrophage) cells.


Author(s):  
Bhaskar Sen ◽  
Sanjoy Kumar Sheet ◽  
Romita Thounaojam ◽  
Ramen Jamatia ◽  
Amarta Kumar Pal ◽  
...  

2015 ◽  
Vol 39 (4) ◽  
pp. 2523-2531 ◽  
Author(s):  
Muthaiah Shellaiah ◽  
Yesudoss Christu Rajan ◽  
Perumal Balu ◽  
Arumugam Murugan

A novel pyrene based free thiol containing a Schiff base derivative PT1 was synthesized and reported as a fluorescence turn-on sensor for Hg2+ ions, via CHEF and excimer (PT1-PT1*) formation with live cell imaging.


2017 ◽  
Vol 239 ◽  
pp. 1194-1204 ◽  
Author(s):  
Barnali Naskar ◽  
Ritwik Modak ◽  
Yeasin Sikdar ◽  
Dilip K. Maiti ◽  
Antonio Bauzá ◽  
...  

Author(s):  
Bhriguram Das ◽  
Atanu Jana ◽  
Ananya Das Mahapatra ◽  
Debprasad Chattopadhyay ◽  
Anamika Dhara ◽  
...  

2021 ◽  
Author(s):  
Anil Kuwar ◽  
In-ho Song ◽  
Pritam D. Torawane ◽  
Jung-Seop Lee ◽  
Shrikant Warkad ◽  
...  

A new Schiff base receptor (3) was synthesized by an equimolar reaction between the isonicotinic hydrazide and 2,4-dihydroxybenzaldehyde in ethanol. Receptor 3 based demonstrated excellent selectivity and sensitivity towards Cu2+...


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