scholarly journals New insights for titanium(iv) speciation in acidic media based on UV-visible and 31P NMR spectroscopies and molecular modeling

RSC Advances ◽  
2021 ◽  
Vol 11 (43) ◽  
pp. 27059-27073
Author(s):  
Lucas Mangold ◽  
Hubert Halleux ◽  
Sébastien Leclerc ◽  
Aurélien Moncomble ◽  
Gérard Cote ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Molecular Modeling ◽  
Phosphoric Acid ◽  
Aqueous Solutions ◽  
Spectroscopic Study ◽  
31P Nmr ◽  
Acidic Media ◽  
Polynuclear Species ◽  
Uv Visible

A spectroscopic study of titanium(iv) speciation in diluted nitric acid (model of non-complexing medium) and 0.1–12.7 mol L−1 phosphoric acid aqueous solutions. Evidence for the presence of polynuclear species is supported by molecular modeling.

IR and 31P NMR spectroscopic study of complexation of carbamoyl methyl phosphinates with UVI and ThIV in nitric acid solutions

2005 ◽  
Vol 54 (11) ◽  
pp. 2540-2544 ◽  
Author(s):  
T. A. Mastryukova ◽  
O. I. Artyushin ◽  
M. P. Pasechnik ◽  
E. V. Sharova ◽  
I. L. Odinets ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Spectroscopic Study ◽  
31P Nmr ◽  
Acid Solutions ◽  
Nitric Acid Solutions

Sorption of Cadmium and Lead by Chelating Ion Exchangers Ostsorb OXIN, Ostsorb DETA, and Ostsorb DTTA

1994 ◽  
Vol 59 (6) ◽  
pp. 1311-1318 ◽  
Author(s):  
Ladislav Svoboda ◽  
Petr Vořechovský
Keyword(s):  
Ionic Strength ◽  
Aqueous Solutions ◽  
Sodium Perchlorate ◽  
Exchange Capacity ◽  
Chloride Ions ◽  
Point Of View ◽  
Alkaline Media ◽  
Ion Exchangers ◽  
Acidic Media ◽  
Cadmium And Lead

The properties of cellulose chelating ion exchangers Ostsorb have been studied in the sorption of cadmium and lead from aqueous solutions. The Cd(II) and Pb(II) ions are trapped by the Ostsorb OXIN and Ostsorb DETA ion exchangers most effectively in neutral and alkaline media but at these conditions formation of stable hydrolytic products of both metals competes with the exchange equilibria. From this point of view, Ostsorb DTTA appears to be a more suitable sorbent since it traps the Pb(II) and Cd(II) ions in acidic media already. Chloride ions interfere with the sorption of the two metals by Ostsorb DTTA whereas the ionic strength adjusted by the addition of sodium perchlorate does not affect the exchange capacity of this ion exchanger.

Sorption of Lead by the Selective Ion Exchanger Ostsorb DETA

1992 ◽  
Vol 57 (7) ◽  
pp. 1393-1404 ◽  
Author(s):  
Ladislav Svoboda ◽  
Jan Uhlíř ◽  
Zdeněk Uhlíř
Keyword(s):  
Phosphoric Acid ◽  
Aqueous Solutions ◽  
Functional Groups ◽  
Ion Exchanger ◽  
Preconcentration Procedure ◽  
Bead Cellulose

The properties of Ostsorb DETA, a selective ion exchanger based on modified bead cellulose with chemically bonded diethylenetriamine functional groups, were studied, and its applicability to the preconcentration of trace amounts of lead from aqueous solutions was verified. The conditions of the preconcentration procedure in the column and batch modes were optimized for this purpose. The results obtained were applied to the determination of lead in phosphoric acid.

scholarly journals A Raman, SERS and UV-circular dichroism spectroscopic study of N-acetyl-l-cysteine in aqueous solutions

2019 ◽  
Vol 43 (38) ◽  
pp. 15201-15212 ◽  
Author(s):  
R. A. Cobos Picot ◽  
M. Puiatti ◽  
A. Ben Altabef ◽  
R. J. G. Rubira ◽  
S. Sanchez-Cortes ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Circular Dichroism ◽  
Aqueous Solutions ◽  
Spectroscopic Study ◽  
Electronic Properties ◽  
Structural Properties ◽  
Amine Groups ◽  
Circular Dichroïsm

The aim of this work is to evaluate the vibrational and structural properties of N-acetyl-l-cysteine (NAC), and its molecular structure and electronic properties in relation to the action of thiol and amine groups at different pH.

Removal of naphthalene from aqueous solutions by phosphorus doped-titanium dioxide coated on silica phosphoric acid under visible light

2021 ◽  
Vol 224 ◽  
pp. 187-196
Author(s):  
Bahman Banaei ◽  
Amir Hessam Hassani ◽  
Farhang Tirgir ◽  
Abdolmajid Fadaei ◽  
Seyed Mehdi Borghaei
Keyword(s):  
Titanium Dioxide ◽  
Phosphoric Acid ◽  
Aqueous Solutions ◽  
Visible Light ◽  
Doped Titanium Dioxide ◽  
Phosphorus Doped
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