scholarly journals Cost-effective and sensitive anthocyanin-based paper sensors for rapid ammonia detection in aqueous solutions

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 24387-24397
Author(s):  
Shamshad Ul Haq ◽  
Maryam Aghajamali ◽  
Hassan Hassanzadeh

In this work, we studied the effect of different factors such as anthocyanin source, extraction technique, and extracting solvent on the sensitivity and optical visibility of anthocyanin-based paper sensors.

2014 ◽  
Vol 2014 ◽  
pp. 1-12 ◽  
Author(s):  
Bayram Kizilkaya ◽  
A. Adem Tekınay

Removal of lead (II) from aqueous solutions was studied by using pretreated fish bones as natural, cost-effective, waste sorbents. The effect of pH, contact time, temperature, and metal concentration on the adsorption capacities of the adsorbent was investigated. The maximum adsorption capacity for Pb (II) was found to be 323 mg/g at optimum conditions. The experiments showed that when pH increased, an increase in the adsorbed amount of metal of the fish bones was observed. The kinetic results of adsorption obeyed a pseudo second-order model. Freundlich and Langmuir isotherm models were applied to experimental equilibrium data of Pb (II) adsorption and the value ofRLfor Pb (II) was found to be 0.906. The thermodynamic parameters related to the adsorption process such asEa,ΔG°,ΔH°, andΔS° were calculated andEa,ΔH°, andΔS° were found to be 7.06, 46.01 kJ mol−1, and 0.141 kJ mol−1K−1for Pb (III), respectively.ΔH° values (46.01 kJmol−1) showed that the adsorption mechanism was endothermic. Weber-Morris and Urano-Tachikawa diffusion models were also applied to the experimental equilibrium data. The fish bones were effectively used as sorbent for the removal of Pb (II) ions from aqueous solutions.


2018 ◽  
Vol 78 (4) ◽  
pp. 827-836 ◽  
Author(s):  
Aysun Bulut ◽  
Sabriye Yusan ◽  
Sule Aytas ◽  
Senol Sert

Abstract This study aimed to investigate and explore the possibility of using ground sea shell powder (Donax trunculus) (SSP) for sorption of Sr(II) ions from aqueous solutions. The maximum removal of Sr(II) removal in SSP was 60% at initial Sr(II) concentration of 25 mg/L, at pH 6.0, contact time 120 min, temperature 25 °C and volume/mass ratio equivalent to 500. Sorption data were interpreted considering the adsorption isotherms and thermodynamic parameters calculated. The maximum Sr(II) adsorption on SSP was 25.45 mg/g at pH 6.0. Freundlich isotherm and Dubinin–Radushkevich models were seen to be more compatible with the sorption equilibrium. The nature of the process was spontaneous and exothermic. The results suggest that SSP could be used as an efficient and cost-effective adsorbent to remove strontium ion.


2016 ◽  
Vol 19 (1) ◽  
pp. 7-16 ◽  

<p>In this study, nanocomposite of ceria sawdust (CeO<sub>2</sub>/SD) synthesized by precipitation method was utilized for removal of As (III) ions from aqueous solutions. Study of the process was done in column system. Characterization of the nano sized adsorbent particles was carried out using XRD and SEM techniques. The effects of important parameters, such as the value of initial pH, the flow rate, the influent concentration of arsenic and bed depth were studied in the column system. The Thomas model was applied for treatment of the adsorption data at different flow rate, influent concentration and bed depth. The bed-depth/service time analysis (BDST) model was also applied at different bed depth to predict the breakthrough curves. The two models were found suitable for describing the bio sorption process of the dynamic behavior of the CeO<sub>2</sub>/SD adsorbent in column investigation. Based on Thomas model, the equilibrium adsorption reached 8.28 mg g<sup>−</sup><sup>1</sup> when a As(III) polluted solution with influent concentration of As 10 mg l<sup>-1 </sup>passed through the column with a flow rate of 2 ml min<sup>−</sup><sup>1</sup>. All the results suggested the presented nanocomposite as an efficient and cost effective adsorbent for removal of As (III) ions from aqueous solutions.</p>


Author(s):  
Leela Gopal ◽  
V. V. Hanuman ◽  
G. Chakrapani

Investigations were carried out for separation/pre concentration of uranium from aqueous solutions of different TDS using Powdered Activated Carbon (PAC). Parameters like amount of PAC, contact time, pH, volume of solutions and reagents for desorption were optimized. The sorption of uranium is more than 95% at pH 4-5 using 0.5 gram PAC with a contact time of 10 minutes.  The sorbed uranium on PAC is recovered using 0.8N HNO<sub>3</sub> and determined by LED Fluorimetry.  Method was successfully applied to ground water, sea water and brine water.  Methodology is simple, selective, cost effective with minimal skills. RSD of the method varies ± 6-14 %.


2021 ◽  
Vol 55 (5-6) ◽  
pp. 705-722
Author(s):  
JEYAGOWRI BALAKRISHNAN ◽  
YAMUNA RANGAIYA THIAGARAJAN

The present study investigates the potential of Simarouba glauca seed shell powder as a cost-effective adsorbent for the removal of the cationic dyes Malachite green (MG), Methylene blue (MB) and Rhodamine B (RB) from aqueous solutions. The adsorbent was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD), as well as by Brunauer–Emmett–Teller (BET) and elemental (CHNS) analyses. Batch mode adsorption studies were carried out varying the experimental conditions, such as initial dye concentration and contact time, adsorbent dose, pH and particle size, in order to assess the adsorbent capacity for the removal of cationic dyes from wastewater. The experimental data were analysed using the Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms. The data fitted well the Langmuir model for the dyes studied. Kinetic data were analysed using the pseudo-first order, pseudo-second order, intraparticle diffusion and Boyd models. The experimental results showed that the pseudo-second order model fitted well.


2016 ◽  
Vol 75 (1) ◽  
pp. 196-206 ◽  
Author(s):  
V. E. Pakade ◽  
O. B. Nchoe ◽  
L. Hlungwane ◽  
N. T. Tavengwa

The purpose of this study was to investigate the feasibility of activated carbons prepared from Macadamia nutshells as an efficient adsorbent for the removal of hexavalent chromium (Cr(VI)) from aqueous solutions. The activated carbon was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), CHNS analyzer and Brunauer–Emmett–Teller (BET). For effective removal of Cr(VI), the optimum parameters found were pH 2, 120 min of contact time and 0.2 g of sorbent. The adsorption data fitted well into the Freundlich model, suggesting a multilayer sorption process. The results demonstrated that Macadamia activated carbon could be used as cost-effective biosorbent for the treatment of aqueous solutions contaminated by Cr(VI) with an adsorption capacity of 22.3 mg g−1. The mode of removal involved adsorption and reduction of Cr(VI) to Cr(III).


2015 ◽  
Vol 57 (12) ◽  
pp. 5567-5578 ◽  
Author(s):  
Mahdi Chiha ◽  
Fatiha Ahmedchekkat ◽  
Abeer Al-Bsoul

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