scholarly journals Analysis of sodium generation by sodium oxide decomposition on corrosion resistance materials: a new approach towards sodium redox water-splitting cycle

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 21017-21022
Author(s):  
Rajesh Kumar ◽  
Hiroki Miyaoka ◽  
Keita Shinzato ◽  
Takayuki Ichikawa
Keyword(s):  
Corrosion Resistance ◽  
Water Splitting ◽  
Sodium Oxide ◽  
Side Reactions ◽  
Redox Cycle ◽  
New Approach ◽  
Operational Conditions ◽  
Oxide Decomposition

In this study, investigation of materials with corrosion resistance was carried out to prevent side reactions by sodium oxide (Na2O) in the Na-redox cycle, and essential operational conditions for Na generation from Na2O were investigated.

scholarly journals Exploring the Effect of Silicon on the High Temperature Corrosion of Lean FeCrAl Alloys in Humid Air

2021 ◽  
Author(s):  
T. Sand ◽  
A. Edgren ◽  
C. Geers ◽  
V. Asokan ◽  
J. Eklund ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Oxidation Behavior ◽  
High Temperature Corrosion ◽  
The Other ◽  
Oxide Scales ◽  
Protective Oxide ◽  
New Approach ◽  
Fecral Alloys ◽  
Cr Evaporation

AbstractA new approach to reduce the chromium and aluminium concentrations in FeCrAl alloys without significantly impairing corrosion resistance is to alloy with 1–2 wt.% silicon. This paper investigates the “silicon effect” on oxidation by comparing the oxidation behavior and scale microstructure of two FeCrAl alloys, one alloyed with silicon and the other not, in dry and wet air at 600 °C and 800 °C. Both alloys formed thin protective oxide scales and the Cr-evaporation rates were small. In wet air at 800 °C the Si-alloyed FeCrAl formed an oxide scale containing mullite and tridymite together with α- and γ-alumina. It is suggested that the reported improvement of the corrosion resistance of Al- and Cr-lean FeCrAl’s by silicon alloying is caused by the appearance of Si-rich phases in the scale.

scholarly journals Kinetics of Non-Enzymatic Synthesis of Dipeptide Cbz-Phe-Leu with AOT Reversed Micelles

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1003
Author(s):  
Michiaki Matsumoto ◽  
Tadashi Hano
Keyword(s):  
Enzymatic Synthesis ◽  
Maximum Yield ◽  
Side Reactions ◽  
Experimental Conditions ◽  
Operational Conditions ◽  
Ph Dependency ◽  
Optimum Water Content ◽  
Short Time ◽  
Kinetics Of ◽  
Aot Reversed Micelles

The non-enzymatic synthesis of N-benzyloxycarbonyl-L-phenylalanyl-L-leucine (Cbz-Phe-Leu) from lipophilic N-benzyloxycarbonyl-L-phenylalanine (Cbz-Phe) and hydrophilic L-leucine (Leu), by N, N’-dicyclohexylcarbodiimide (DCC) as a condensing agent, was carried out using a reversed micellar system composed of bis(2-ethylhexyl) sodium sulfosuccinate (AOT) as a surfactant and isooctane. We successfully synthesized Cbz-Phe-Leu in a short time and investigated the effects of its operational conditions, the DCC concentration, w0, and the pH on the kinetic parameters and the maximum yields. For dipeptide synthesis, we had to add an excess of DCC with the substrates because of the side reactions of Cbz-Phe. From the pH dependency of the reactivity, a partially cationic form of Leu was better for a synthesis reaction because of the enrichment of Leu at the interface by anionic AOT. The optimum water content on the dipeptide synthesis was w0 = 28 due to the competition of the peptide synthesis and the side reactions. The maximum yield of Cbz-Phe-Leu was 0.565 at 80 h under optimum experimental conditions.

Highly-efficient and autocatalytic reduction of NaHCO3 into formate by in situ hydrogen from water splitting with metal/metal oxide redox cycle

2017 ◽  
Vol 26 (5) ◽  
pp. 881-890 ◽  
Author(s):  
Guodong Yao ◽  
Jia Duo ◽  
Binbin Jin ◽  
Heng Zhong ◽  
Lingyun Lyu ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Water Splitting ◽  
Redox Cycle ◽  
Highly Efficient ◽  
Metal Metal

A Thermochemical Study of Iron Aluminate-Based Materials: A Preferred Class for Isothermal Water Splitting

2022 ◽  
Author(s):  
Kent John Warren ◽  
Justin T. Tran ◽  
Alan W. Weimer
Keyword(s):  
Water Splitting ◽  
Thermochemical Study ◽  
Redox Cycle ◽  
Renewable Fuel ◽  
Solar Thermochemical ◽  
Isothermal Water

The use of hydrogen as a renewable fuel has been stymied by our inability to produce it cleanly and economically. The conventional solar thermochemical approach considers a two-step redox cycle...

scholarly journals Effect of Inclusions on the Corrosion Properties of the Nickel-Based Alloys 718 and EP718

Metals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1177 ◽  
Author(s):  
Ekaterina Alekseeva ◽  
Andrey Karasev ◽  
Pär G. Jönsson ◽  
Aleksey Alkhimenko
Keyword(s):  
Corrosion Resistance ◽  
Alloy 718 ◽  
Corrosion Properties ◽  
Electrolytic Extraction ◽  
Operational Conditions ◽  
Large Size ◽  
Size Number ◽  
Resistance To Deformation ◽  
The Given ◽  
Harmful Effects

Inclusions in steels and alloys are known to lower the resistance to deformation, as well as to lower the mechanical, corrosion and other properties. Studies of inclusions in nickel-based alloys are important since these materials could suffer from corrosion degradation in harsh operational conditions. This, in fact, could lead to a pitting initiation around the inclusions. Two industrial Ni-based alloys (alloy 718 and EP718) were investigated to determine the harmful effects of different inclusions on the corrosion resistance of Ni-based alloys. Specifically, the inclusion characteristics (such as composition, morphology, size, number and location) were determined for inclusions collected on film filters after electrolytic extraction and dissolution of a metal matrix around different inclusions on surfaces of metal samples after electrolytic extraction (EE). It was found that both Ni-based alloys contain various inclusion types: carbides (large size NbTi-C and small multicomponent carbides), nitrides TiNb-N and sulphides (TiNb-S in EP718 alloy). The most harmful effects on the corrosion resistance of metal were detected around sulphides and small carbides containing Mo, W, Cr. Dissolution effects were also observed around large carbides and nitrides, especially around inclusions larger than 10 µm. Moreover, the dissolution of a matrix around inclusions and clusters located on the grain boundaries were found to be 2.1–2.7 times larger compared to inclusions found inside of grains of the given alloy samples.

scholarly journals Cointegration: a novel approach for the removal of environmental trends in structural health monitoring data

2011 ◽  
Vol 467 (2133) ◽  
pp. 2712-2732 ◽  
Author(s):  
Elizabeth J. Cross ◽  
Keith Worden ◽  
Qian Chen
Keyword(s):  
Structural Health Monitoring ◽  
Health Monitoring ◽  
Environmental Variability ◽  
Stationary Time Series ◽  
New Approach ◽  
Operational Conditions ◽  
Structural Health ◽  
Original Dataset ◽  
Novel Approach ◽  
Static Responses

Before structural health monitoring (SHM) technologies can be reliably implemented on structures outside laboratory conditions, the problem of environmental variability in monitored features must be first addressed. Structures that are subjected to changing environmental or operational conditions will often exhibit inherently non-stationary dynamic and quasi-static responses, which can mask any changes caused by the occurrence of damage. The current work introduces the concept of cointegration , a tool for the analysis of non-stationary time series, as a promising new approach for dealing with the problem of environmental variation in monitored features. If two or more monitored variables from an SHM system are cointegrated, then some linear combination of them will be a stationary residual purged of the common trends in the original dataset. The stationary residual created from the cointegration procedure can be used as a damage-sensitive feature that is independent of the normal environmental and operational conditions.

System Identification of Mistuned Bladed Disks From Traveling Wave Response Measurements

2003 ◽  
Author(s):  
D. M. Feiner ◽  
J. H. Griffin ◽  
K. W. Jones ◽  
J. A. Kenyon ◽  
O. Mehmed ◽  
...  
Keyword(s):  
System Identification ◽  
Modal Analysis ◽  
Traveling Wave ◽  
Natural Frequencies ◽  
Wave Excitation ◽  
New Approach ◽  
Operational Conditions ◽  
System Identification Method ◽  
Bladed Disk ◽  
Identification Method

A new approach to modal analysis is presented that allows the modes and natural frequencies of a mistuned bladed disk to be determined from its response to a traveling wave excitation. The resulting modes and natural frequencies are then used as input to a system identification method to determine the bladed disk’s mistuning while it is rotating. This capability is useful since it provides a basis for determining blade frequencies under engine operational conditions and could help monitor the health of the engine.

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