scholarly journals Inhibition effect of ZrF4 on UO2 precipitation in the LiF–BeF2 molten salt

RSC Advances ◽  
2021 ◽  
Vol 11 (31) ◽  
pp. 18708-18716
Author(s):  
Hao Peng ◽  
Yulong Song ◽  
Nan Ji ◽  
Leidong Xie ◽  
Wei Huang ◽  
...  
Keyword(s):  
Molten Salt ◽  
Nuclear Fuel ◽  
Molten Salt Reactor ◽  
Effective Solution ◽  
Safe Operation ◽  
Inhibition Effect ◽  
Fuel Salt ◽  
Molten Fluorides

This study provides an effective solution for controlling and monitoring the nuclear fuel precipitation (UO2) in molten fluorides, which is of great importance for the safe operation and fuel salt design of molten salt reactor (MSR).

A new method for monitoring the redox potential of fuel salt based on the deposition of 95Nb on Hastelloy C276

2021 ◽  
Vol 109 (5) ◽  
pp. 357-365
Author(s):  
Zhiqiang Cheng ◽  
Zhongqi Zhao ◽  
Junxia Geng ◽  
Xiaohe Wang ◽  
Jifeng Hu ◽  
...  
Keyword(s):  
Redox Potential ◽  
Molten Salt ◽  
Specific Activity ◽  
Chemical Reduction ◽  
Quantitative Approach ◽  
Experimental Results ◽  
New Method ◽  
Molten Salt Reactor ◽  
Fuel Salt ◽  
Well Correlation

Abstract To develop the application of 95Nb as an indicator of redox potential for fuel salt in molten salt reactor (MSR), the specific activity of 95Nb in FLiBe salt and its deposition of 95Nb on Hastelloy C276 have been studied. Experimental results indicated that the amount of 95Nb deposited on Hastelloy C276 resulted from its chemical reduction exhibited a positive correlation with the decrease of 95Nb activity in FLiBe salt and the relative deposition coefficient of 95Nb to 103Ru appeared a well correlation with 95Nb activity in FLiBe salt. Both correlations implied that the measurement of 95Nb activity deposited on Hastelloy C276 specimen might provide a quantitative approach for monitoring the redox potential of fuel salt in MSR.

Molten-Salt Reactor for Nuclear Fuel Cycle Closure on All Actinides

Atomic Energy ◽  
2019 ◽  
Vol 125 (5) ◽  
pp. 279-283 ◽  
Author(s):  
V. V. Ignatiev ◽  
M. V. Kormilitsyn ◽  
L. A. Kormilitsyna ◽  
Yu. M. Semchenkov ◽  
Yu. S. Fedorov ◽  
...  
Keyword(s):  
Molten Salt ◽  
Nuclear Fuel ◽  
Fuel Cycle ◽  
Nuclear Fuel Cycle ◽  
Molten Salt Reactor

Steady Thermal Hydraulics Analysis for a Graphite-Moderated Channel Type Molten Salt Reactor

2008 ◽  
Author(s):  
Dalin Zhang ◽  
Suizheng Qiu
Keyword(s):  
Molten Salt ◽  
Flow Distribution ◽  
Axial Direction ◽  
Theoretical Models ◽  
Outer Wall ◽  
Molten Salt Reactor ◽  
Thermal Hydraulics ◽  
The Core ◽  
Fuel Salt ◽  
Channel Type

The Molten Salt Reactor (MSR) is one of the six GENIV systems capable of breading and burning. In this paper, a graphite-moderated channel type MSR was selected for conceptual research. For this MSR, a ternary system of 0.15LiF-0.58NaF-0.27BeF2 was proposed as the reactor fuel solvent, coolant and also moderator simultaneously with ca.1 mol% UF4 dissolving in it, which circulates through the whole primary loop accompanying fission reaction only in the core. 169 hexagonal graphite elements, each with a central fuel channel, are arranged in the core symmetrically by 30° angles. The theoretical models of the thermal hydraulics under steady condition are conducted in one-twelfth of the core and calculated by the numerical method. The DRAGON code is adopted to calculate the axial and radial power factors. The flow and heat transfer models in the fuel salt and graphite are founded basing on the fundamental mass, momentum and energy equations. The calculated results show the detailed mass flow distribution in the core; and the temperature of the fuel salt, inner and outer wall in the calculated elements along the axial direction are also obtained.

Fuel Salt for the Molten-Salt Reactor

Atomic Energy ◽  
2013 ◽  
Vol 115 (1) ◽  
pp. 5-10 ◽  
Author(s):  
L. I. Ponomarev ◽  
M. B. Seregin ◽  
A. P. Parshin ◽  
S. A. Mel’nikov ◽  
A. A. Mikhalichenko ◽  
...  
Keyword(s):  
Molten Salt ◽  
Molten Salt Reactor ◽  
Fuel Salt

scholarly journals MODERATOR TO FUEL RATIO AND URANIUM FRACTION ANALYSIS OF SQUARE LATTICE MOLTEN SALT TRANSATOMIC POWER

2017 ◽  
Vol 19 (1) ◽  
pp. 1
Author(s):  
Dion Bagus Nugraha B ◽  
Andang Widi Harto ◽  
Sihana Sihana
Keyword(s):  
Molten Salt ◽  
Nuclear Fuel ◽  
Mole Fraction ◽  
Spent Nuclear Fuel ◽  
Light Water Reactor ◽  
Zirconium Hydride ◽  
Molten Salt Reactor ◽  
Inherent Safety ◽  
Light Water ◽  
Optimum Variation

Molten Salt Reactor Transatomic Power (MSR TAP) is a further development of the nuclear reactor Generation IV Reactor Molten Salt Reactor (MSR). MSR TAP generates clean electric power. It has a passive safety, resistance to proliferation, and low cost. MSR TAP can consume the rest of the nuclear fuel/spent nuclear fuel (SNF) of a commercial Light Water Reactor (LWR) fuel or use the main fuel, a salt solution UF4 - LiF - BeF2. MSR TAP uses Zirconium Hydride material for the moderator. This research has a purpose to determine the optimal size of uranium mole fraction on fuel and moderator radius from core design in order to produce optimum enrichment with the value 1 < keff <1.0065 using MCNP5 program. On the other hand, this research also aims to look for the optimum enrichment, which have inherent safety characteristics with αVoid < 0. Variations were made including the changes in the geometry of the moderator radius with a variation of 0.5 cm, 1 cm, 1.5 cm, 2 cm, 2.5 cm, 3 cm, 3.5 cm, 4 cm, and 4.5 cm; and the changes in the fuel uranium molar UF4 - LiF - BeF2 with molar variation of 15%, 20%, 25% and 30%. The geometry of Transatomic Power (MSR TAP) of companies Transatomic Power Corporation was used. The results show that the optimum variation is the salt solution UF4 - LiF - BeF2 with 25 % uranium mole fraction, 2.6 % enrichment and moderator radius of 1.5 cm. The optimum variation gives the keff value of 1.00124 ± 0.00078. The optimum value of reactivity void coefficient is -0.0684. It indicates an inherently safe design.Keywords : Molten Salt Reactor Transatomic Power, MCNP5, Uranium Fuel Mole Fraction, Optimum Variation, Moderator, Inherent Safety. ANALISIS FRAKSI URANIUM DAN RASIO MODERATOR – BAHAN BAKAR PADA SQUARE LATTICED MOLTEN SALT TRANSATOMIC POWER. Molten Salt Reactor Transatomic Power (MSR TAP) merupakan reaktor nuklir pengembangan lebih lanjut dari Reaktor Generasi IV Molten Salt Reactor (MSR). Reaktor MSR TAP ini menghasilkan daya listrik yang bersih, memiliki keselamatan pasif, mempunyai resistensi terhadap proliferasi, dan memiliki biaya yang rendah. Reaktor ini dapat mengkonsumsi bahan bakar nuklir sisa/spent nuclear fuel (SNF) dari penggunaan bahan bakar Light Water Reactor (LWR) yang komersial atau menggunakan bahan bakar utama yaitu larutan garam UF4 – LiF – BeF2. Moderator yang digunakan pada MSR TAP ini adalah moderator berbahan Zirconium Hydride. Penelitian ini bertujuan untuk menentukan ukuran perbandingan nilai fraski mol uranium dan jari-jari moderator yang optimal dari dari desain teras Reaktor MSR TAP agar dihasilkan pengayaan yang optimum dengan nilai 1 < keff < 1,0065 menggunakan program MCNP5. Selain itu penelitian ini juga bertujuan mecari pengayaan optimum yang mempunyai sifat keselamatan melekat dengan . Variasi yang dilakukan meliputi perubahan geometri jari-jari moderator dengan variasi 0,5 cm, 1 cm, 1,5 cm, 2 cm, 2,5 cm, 3 cm, 3,5 cm, 4 cm, dan 4,5 cm; dan perubahan molar uranium pada bahan bakar UF4 – LiF – BeF2  dengan variasi persen molar 15%, 20%, 25%, dan 30%. Geometri reaktor yang digunakan dalam silmulasi adalah MSR TAP dari perusahaan Transatomic Power Corporation. Hasil penelitian menunjukkan variasi optimum perbandingan moderator bahan dan fraksi mol bahan bakar larutan garam UF4 – LiF – BeF2 pada fraksi mol uranium bahan bakar pada variasi molar uranium 25% dengan pengayaan 2,6% dan jari-jari moderator 1,5 cm, dengan nilai keff 1,00124±0,00078. Koefisien reaktivitas void yang didapatkan dari variasi optimum tersebut adalah -0,0684 yang menandakan bahwa desain ini telah memenuhi syarat keselamatan melekat.Kata kunci: Molten Salt Reactor Transatomic Power, MCNP5, Fraksi mol uranium, Variasi optimum, Moderator, Keselamatan melekat. 

Self-Breeding and Radiotoxicity Analysis on Thorium-Based Molten Salt Reactors

2013 ◽  
Author(s):  
Chun-yan Zou ◽  
Jin-gen Chen ◽  
Xiang-zhou Cai ◽  
Cheng-gang Yu ◽  
Da-zhen Jiang ◽  
...  
Keyword(s):  
Molten Salt ◽  
Nuclear Energy ◽  
Fuel Cycle ◽  
Molten Salt Reactor ◽  
Nuclear System ◽  
Energy Sustainability ◽  
Waste Production ◽  
Breeding Ratio ◽  
Fuel Salt ◽  
System Project

As one of the candidates in the Generation IV reactors program., the molten salt reactor (MSR) has the properties of online refueling and fuel salt reprocessing, MSR is especially attractive for the Thorium fuel cycle, which is very ideal for nuclear non-proliferation, radiotoxicity and nuclear energy sustainability. Therefore, the “Thorium-based Molten Salt Reactor (TMSR) nuclear system” project has been proposed as one of the “Strategic Priority Research Program” of Chinese Academy of Science (CAS). In this paper, we mainly investigated the influence on the breeding ratio and waste radiotoxicity with different reprocessing schemes. By considering the key parameters mentioned above, the aim is to choose an efficient reprocessing scheme for TMSR to reach self-breeding with Th/U fuel cycle and minimize the radioactive waste production of the molten salt.

Reactor Controllability of 3-Region-Core Molten Salt Reactor System: A Study on Load Following Capability

2006 ◽  
Author(s):  
Takahisa Yamamoto ◽  
Koshi Mitachi ◽  
Masatoshi Nishio
Keyword(s):  
Molten Salt ◽  
Solid Fuel ◽  
Molten Salt Reactor ◽  
Delayed Neutron ◽  
Reactor Kinetics ◽  
External Loop ◽  
Fuel Salt ◽  
Salt Flow ◽  
Point Reactor Kinetics ◽  
Graphite Moderator

The Molten Salt Reactor (MSR) systems are liquid-fueled reactors that can be used for actinide burning, production of electricity, production of hydrogen, and production of ssile fuels (breeding). Thorium (Th) and uranium-233 (233U) are fertile and ssile of the MSR systems, and dissolved in a high-temperature molten fluoride salt (fuel salt) with a very high boiling temperature (up to 1650K), that is both the reactor nuclear fuel and the coolant. The MSR system is one of the six advanced reactor concepts identified by the Generation IV International Forum (GIF) as a candidate for cooperative development [1]. In the MSR system, fuel salt flows through a fuel duct constructed around a reactor core and fuel channel of a graphite moderator accompanied by fission reaction and heat generation, and flows out to an external-loop system consisted of a heat exchanger and a circulation pump. Due to the motion of fuel salt, delayed neutron precursors that are one of the source of neutron production make to change their position between the ssion reaction and neutron emission events and decay even occur in the external loop system. Hence the reactivity and effective delayed neutron precursor fraction of the MSR system are lower than those of solid fuel reactor systems such as Boiling Water Reactors (BWRs) and Pressurised Water Reactor (PWRs). Since all of the presently operating nuclear power reactors utilize solid fuel, little attention had been paid to the MSR analysis of the reactivity loss and reactor characteristics change caused by the fuel salt circulation. Sides et al. [2] and Shimazu et al. [3] developed MSR analytical models based on the point reactor kinetics model to consider the effect of fuel salt flow. Their models represented a reactor as having six zones for fuel salt and three zones for the graphite moderator. Since their models employed the point reactor kinetics model and the rough temperature approximation, their results were not sufficiently accurate to consider the effect of fuel salt flow.

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