scholarly journals Role of oxide support in Ni based catalysts for CO2 methanation

RSC Advances ◽  
2021 ◽  
Vol 11 (29) ◽  
pp. 17648-17657
Author(s):  
Ye Hwan Lee ◽  
Jeong Yoon Ahn ◽  
Dinh Duc Nguyen ◽  
Soon Woong Chang ◽  
Sung Su Kim ◽  
...  
Keyword(s):  
Co2 Methanation ◽  
Methanation Reaction ◽  
Support Interaction ◽  
Oxide Support ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Catalytic Performances

The effect of metal–support interaction and role of support on catalytic performances during Ni based CO2 methanation reaction were investigated.

The role of metal–support interaction in catalytic activity of nanodiamond-supported nickel in selective phenylacetylene hydrogenation

2016 ◽  
Vol 344 ◽  
pp. 90-99 ◽  
Author(s):  
E.V. Golubina ◽  
E.S. Lokteva ◽  
A.V. Erokhin ◽  
A.A. Veligzhanin ◽  
Ya.V. Zubavichus ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support

scholarly journals The role of metal–support interaction for CO-free hydrogen from low temperature ethanol steam reforming on Rh–Fe catalysts

2017 ◽  
Vol 19 (6) ◽  
pp. 4199-4207 ◽  
Author(s):  
Catherine K. S. Choong ◽  
Luwei Chen ◽  
Yonghua Du ◽  
Martin Schreyer ◽  
S. W. Daniel Ong ◽  
...  
Keyword(s):  
Steam Reforming ◽  
Active Sites ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Free Hydrogen ◽  
Metal Support ◽  
Fe Catalysts ◽  
Ethanol Steam

Effect of metal–support interaction on the generation of Rh–FexOy active sites is investigated via various in situ techniques.

scholarly journals Study Ni Nanoparticles on Reducible Metal Oxides (Sm2O3, CeO2, ZnO) as Catalysts for CO2 Methanation

2021 ◽  
Vol 16 (3) ◽  
pp. 641-650
Author(s):  
Athirah Ayub ◽  
Hasliza Bahruji ◽  
Abdul Hanif Mahadi
Keyword(s):  
Oxygen Vacancies ◽  
Interfacial Interaction ◽  
Co2 Conversion ◽  
Ni Nanoparticles ◽  
Co2 Methanation ◽  
Methanation Reaction ◽  
Metal Support ◽  
Reducing Environment ◽  
Open Access Article ◽  
Catalytic Performances

The activity of reducible metal oxide Sm2O3, CeO2, and ZnO as Ni nanoparticles support was investigated for CO2 methanation reaction. CO2 methanation was carried out between 200 °C to 450 °C with the optimum catalytic activity was observed at 450 °C. The reducibility of the catalysts has been comparatively studied using H2-Temperature Reduction Temperature (TPR) method. The H2-TPR analysis also elucidated the formation of surface oxygen vacancies at temperature above 600 °C for 5Ni/Sm2O3 and 5Ni/CeO2. The Sm2O3 showed superior activity than CeO2 presumably due to the transition of the crystalline phases under reducing environment. However, the formation of NiZn alloy in 5Ni/ZnO reduced the ability of Ni to catalyze methanation reaction. A highly dispersed Ni on Sm2O3 created a large metal/support interfacial interaction to give 69% of CO2 conversion with 100% selectivity at 450 °C. The 5Ni/Sm2O3 exhibited superior catalytic performances with an apparent phase transition from cubic to a mixture of cubic and monoclinic phases over a long reaction, presumably responsible for the enhanced conversion after 10 h of reaction. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

The role of metal–support interaction on catalytic methane activation

2014 ◽  
Vol 488 ◽  
pp. 138-147 ◽  
Author(s):  
Vesna Havran Mueller ◽  
Milorad P. Duduković ◽  
Cynthia S. Lo
Keyword(s):  
Methane Activation ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support
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