scholarly journals Titanium anodizing in a choline dihydrogencitrate salt–oxalic acid deep eutectic solvent: a step towards green chemistry in surface finishing of titanium and its alloys

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 21104-21115
Author(s):  
Juliusz Winiarski ◽  
Anna Niciejewska ◽  
Monika Górnik ◽  
Jakub Jakubowski ◽  
Włodzimierz Tylus ◽  
...  
Keyword(s):  
Green Chemistry ◽  
Oxalic Acid ◽  
Deep Eutectic Solvent ◽  
Surface Finishing

Fabrication of nanometric color TiO2 layers through polarization of titanium in a choline dihydrogencitrate–oxalic acid DES anodizing bath.

scholarly journals Study on catalytic conversion of cellulose to 5-Hydroxymethyl furfural by directional degradation in deep eutectic solvent

BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 3344-3355
Author(s):  
Hongyan Yang ◽  
Jinyan Lang ◽  
Junliang Lu ◽  
Ping Lan ◽  
Heng Zhang
Keyword(s):  
Green Chemistry ◽  
Oxalic Acid ◽  
Microcrystalline Cellulose ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Deep Eutectic Solvents ◽  
Direct Conversion ◽  
Metal Chlorides ◽  
Hydroxymethyl Furfural ◽  
New Type

The direct conversion of microcrystalline cellulose (MCC) degrading into 5-hydroxymethyl furfural (5-HMF) was studied using four synthetic deep eutectic solvents (DESs) as solvents and choosing four metal chlorides as catalysts. The factors that affected the yields of the products, such as the type of DESs, the type and dosage of catalysts, the ratio of DESs to MCC, and reaction temperature were researched. It was found that the DES synthesized from oxalic acid and choline chloride (O-DES) and SnCl4 showed the better performance. The highest 5-HMF and glucose yields of 11.0% and 22.0% were obtained, respectively, for a reaction carried out at 160 °C for 90 min in O-DES (the ratio of it to MCC was 25:1) using 1.42 wt% SnCl4 as the catalyst. As a new type of dissolution and catalysis system, the DESs were not only cheaper but also easy to obtain. Most importantly, the realization of the concept of green chemistry was achieved in this study.

Beneficial and detrimental effects of choline chloride–oxalic acid deep eutectic solvent on biogas production

2021 ◽  
Vol 131 ◽  
pp. 368-375
Author(s):  
Filipa Lima ◽  
Luis C. Branco ◽  
Nuno Lapa ◽  
Isabel M. Marrucho
Keyword(s):  
Oxalic Acid ◽  
Biogas Production ◽  
Choline Chloride ◽  
Deep Eutectic Solvent

Deep eutectic solvent delignification: Impact of initial lignin

BioResources ◽  
2017 ◽  
Vol 12 (4) ◽  
pp. 7301-7310
Author(s):  
Veronika Majová ◽  
Silvia Horanová ◽  
Andrea Škulcová ◽  
Jozef Šima ◽  
Michal Jablonský
Keyword(s):  
Lactic Acid ◽  
Oxalic Acid ◽  
Lignin Content ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Deep Eutectic Solvents ◽  
Kappa Number ◽  
Kraft Pulps ◽  
Oxygen Delignification ◽  
Detailed Understanding

This study aimed to resolve the issue of the lack of detailed understanding of the effect of initial lignin content in hardwood kraft pulps on pulp delignification by deep eutectic solvents. The authors used Kappa number of the concerned pulp, intrinsic viscosity, and selectivity and efficiency of delignification as the parameters of the effect. The pulp (50 g oven dry pulp) was treated with four different DESs systems based on choline chloride with lactic acid (1:9), oxalic acid (1:1), malic acid (1:1), and system alanine:lactic acid (1:9); the results were compared to those reached by oxygen delignification. The results showed that the pulp with a higher initial lignin content had a greater fraction of easily removed lignin fragments.

scholarly journals Determination of Selenium and Arsenic Ions in Edible Mushroom Samples by Novel Chloride–Oxalic Acid Deep Eutectic Solvent Extraction Using Graphite Furnace-Atomic Absorption Spectrometry

2018 ◽  
Vol 101 (2) ◽  
pp. 593-600 ◽  
Author(s):  
Rizwan Ali Zounr ◽  
Mustafa Tuzen ◽  
Muhammad Yar Khuhawar
Keyword(s):  
Oxalic Acid ◽  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Graphite Furnace ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Absorption Spectrometry ◽  
Edible Mushroom ◽  
Graphite Furnace Atomic Absorption

Abstract In present study, we proposed the application of a deep eutectic solvent (DES) made up of choline chloride (ChCl) and oxalic acid (Ox) for the dissolution of different edible mushroom samples for the determination of selenium (Se) and arsenic (As) ions. Therefore, an innovative, green, novel, and inexpensive method based on ChCl–Ox as the DES was developed for the determination of Se and As ions in mushroom species by graphite furnace-atomic absorption spectrometry. The important analytical parameters were also optimized. The LODs for Se and As ions were found to be 0.32 and 0.50 µg/L, respectively. The LOQs for Se and As ions were found to be 1.06 and 1.65 µg/L, respectively. The RSD was observed to be less than 5% for both analyte ions. The accuracy of the developed method was confirmed by analyzing mushroom powder Certified Reference Material CS-M-3 (Boletus edulis). The developed technique was effectively useful for the determination of Se and As ions in different species of mushroom samples from Turkey.

scholarly journals One-pot multi-component process for the synthesis of 4-azaphenanthrene-3,10-dione, 1,8-dioxo-octahydroxanthene and tetrahydrobenzo[b]pyran derivatives catalyzed by the deep eutectic solvent choline chloride-oxalic acid

2020 ◽  
Vol 75 (3) ◽  
pp. 269-279
Author(s):  
Mohammad Hosein Sayahi ◽  
Maryam Gorjizadeh ◽  
Melan Meheiseni ◽  
Soheil Sayyahi
Keyword(s):  
Oxalic Acid ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Reaction Times ◽  
Eutectic Mixture ◽  
Reaction Yield ◽  
One Pot ◽  
Experimental Procedure ◽  
Component Process ◽  
High Yields

AbstractAn effective method based on choline chloride (ChCl)-oxalic acid (Ox) deep eutectic solvent was proposed for the synthesis of 4-azaphenanthrene-3,10-dione, 1,8-dioxo-octahydroxanthene and tetrahydrobenzo[b]pyran derivatives. The eutectic mixture worked as both the solvent and acidic catalyst for conversion. The impacts of different variables, including the composition and volume of ChCl-Ox, and temperature, on reaction yield were studied for optimization. The crucial advantages of this process are simplicity of the experimental procedure, high yields, short reaction times, high recyclability, and the use of safe and inexpensive components.

Impact of solution variables on the removal of heavy metals from wastewaters by a recycled iron sorbent

2000 ◽  
Vol 42 (1-2) ◽  
pp. 347-352
Author(s):  
E.H. Smith ◽  
S. Chatterjee
Keyword(s):  
Heavy Metals ◽  
Oxalic Acid ◽  
Metal Speciation ◽  
Surface Finishing ◽  
Complexing Agents ◽  
Lead Removal ◽  
Adsorption Equilibria ◽  
Removal Of Heavy Metals ◽  
Cadmium And Lead ◽  
The Impact

Waste shot-blast fines from surface finishing processes have been demonstrated to be effective for removing heavy metals from solution by adsorption.The technology offers the potential for inexpensive recovery and reuse of a material normally discarded as a solid waste. While metal removals compare favorably with those achieved by commercial sorbents, applications issues such as the impact of background metal-complexing agents require investigation. The presence of oxalic acid, a complexing organic compound, impacted cadmium and lead adsorption in accordance with predictions from metal speciation equilibria; i.e., a small but measurable reduction in lead removal was observed, but cadmium adsorption was relatively unaffected. The effects were repeated in dynamic column experiments, with lead removals reduced by 15 to 20% in the presence of the ligand. Efforts to model adsorption equilibria in the presence of oxalic acid did not fully capture the reduced lead removal, presumably because the model does not consider the complete formation of metal-oxalic acid complexes prior to contact with the sorbent.

A review on the properties and applications of chitosan, cellulose and deep eutectic solvent in green chemistry

2021 ◽  
Author(s):  
Xin Xiong Chang ◽  
Nabisab Mujawar Mubarak ◽  
Shaukat Ali Mazari ◽  
Abdul Sattar Jatoi ◽  
Awais Ahmad ◽  
...  
Keyword(s):  
Green Chemistry ◽  
Deep Eutectic Solvent
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