scholarly journals Enhanced simultaneous adsorption of As(iii), Cd(ii), Pb(ii) and Cr(vi) ions from aqueous solution using cassava root husk-derived biochar loaded with ZnO nanoparticles

RSC Advances ◽  
2021 ◽  
Vol 11 (31) ◽  
pp. 18881-18897
Author(s):  
P. T. Tho ◽  
Huu Tap Van ◽  
Lan Huong Nguyen ◽  
Trung Kien Hoang ◽  
Thi Ngoc Ha Tran ◽  
...  

This study presents the modification of cassava root husk-derived biochar (CRHB) with ZnO nanoparticles (ZnO-NPs) for the simultaneous adsorption of As(iii), Cd(ii), Pb(ii) and Cr(vi).

NANO ◽  
2014 ◽  
Vol 09 (04) ◽  
pp. 1450052 ◽  
Author(s):  
LIHUA SHEN ◽  
BEI YAN ◽  
XIAOXIA LI ◽  
CHENGXIAO ZHANG

A strong electrochemiluminescence (ECL) emission from ZnO nanoparticles (NPs) suspended in aqueous solution at a Pt electrode or in NPs layers modified on a Pt or graphite electrode, which occurred between -1.0 V(versus Ag / AgCl , Sat. KCl ) and -2.0 V, was observed in 0.25 M NaOH in the presence of peroxydisulfate. The ECL intensity was linear to the concentration of suspended ZnO NPs in the range from 1.0 × 10-5 to 1.0 × 10-3 g/mL. The ECL spectrum of ZnO NPs revealed that both ZnO and peroxydisulfate-dissolved oxygen have been involved in the ECL process, and ECL spectrum has a red shift compared with photoluminescence (PL). The electrochemical redox behavior of ZnO NPs was also studied at a ZnO NPs modified carbon paste electrode by entrapping ZnO NPs in carbon paste, which reveals that the alkaline medium changed the surface state of ZnO NPs. The surface passivation has a significant effect on the ZnO NPs'electrochemical behaviors.


RSC Advances ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 5801-5814
Author(s):  
Huu Tap Van ◽  
Lan Huong Nguyen ◽  
N. V. Dang ◽  
Huan-Ping Chao ◽  
Quang Trung Nguyen ◽  
...  

In this study, two types of agricultural wastes, sugarcane bagasse (SB) and cassava root husks (CRHs), were used to fabricate biochars.


Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2072
Author(s):  
Maria Antonia Tănase ◽  
Maria Marinescu ◽  
Petruta Oancea ◽  
Adina Răducan ◽  
Catalin Ionut Mihaescu ◽  
...  

In the present work, the properties of ZnO nanoparticles obtained using an eco-friendly synthesis (biomediated methods in microwave irradiation) were studied. Saponaria officinalis extracts were used as both reducing and capping agents in the green nanochemistry synthesis of ZnO. Inorganic zinc oxide nanopowders were successfully prepared by a modified hydrothermal method and plant extract-mediated method. The influence of microwave irradiation was studied in both cases. The size, composition, crystallinity and morphology of inorganic nanoparticles (NPs) were investigated using dynamic light scattering (DLS), powder X-ray diffraction (XRD), SEM-EDX microscopy. Tunings of the nanochemistry reaction conditions (Zn precursor, structuring agent), ZnO NPs with various shapes were obtained, from quasi-spherical to flower-like. The optical properties and photocatalytic activity (degradation of methylene blue as model compound) were also investigated. ZnO nanopowders’ antibacterial activity was tested against Gram-positive and Gram-negative bacterial strains to evidence the influence of the vegetal extract-mediated synthesis on the biological activity.


RSC Advances ◽  
2016 ◽  
Vol 6 (111) ◽  
pp. 110108-110111 ◽  
Author(s):  
Zhenghui Liu ◽  
Huifang Zhou ◽  
Jiefeng Liu ◽  
Xudong Yin ◽  
Yufeng Mao ◽  
...  

Zinc oxide nanoparticles (ZnO NPs) have been monitored in wastewater treatment plants as their potential adverse effects on functional microorganisms have been causing increasing concern.


2013 ◽  
Vol 54 (9) ◽  
pp. 1969-1975 ◽  
Author(s):  
Tongsai Jamnongkan ◽  
Ryo Shirota ◽  
Sathish K. Sukumaran ◽  
Masataka Sugimoto ◽  
Kiyohito Koyama

RSC Advances ◽  
2014 ◽  
Vol 4 (75) ◽  
pp. 39732-39742 ◽  
Author(s):  
Ajay Devidas Hiwarkar ◽  
Vimal Chandra Srivastava ◽  
Indra Deo Mall

Granular activated carbon used for simultaneous adsorption of pyrrole and indole from aqueous solution.


2014 ◽  
Vol 1024 ◽  
pp. 83-86 ◽  
Author(s):  
Mohamad Sahban Alnarabiji ◽  
Noorhana Yahya ◽  
Sharifa Bee Abd Hamid ◽  
Khairun Azizi Azizli ◽  
Afza Shafie ◽  
...  

Synthesising zinc oxide nanoparticles to get certain specific characteristics to be applied in Enhanced oil recovery (EOR) is still challenging to date. In this work, zinc oxide (ZnO) nanoparticles were synthesised using the sol-gel method by dissolving zinc nitrate hexahydrate in nitric acid. The ZnO crystal and particles morphology and structure were determined using X-ray Diffractometer (XRD) and Field Emission Scanning Electron Microscope (FESEM). In this study, a microwave oven was used for annealing ZnO without insulating a sample in any casket. The results show that 30 and 40 minutes of annealing and stirring for 1 hour influenced the morphology and size of zinc oxide particles in nanoscale. These parameters could be tailored to generate a range of nanoparticle morphology (agglomerated nanoparticles in a corn-like morphology), a crystal size with the mean size of 70.5 and 74.9 nm and a main growth at the peak [10. EOR experiment were conducted by dispersing 0.10 wt% ZnO NPs in distilled water to form a ZnO nanofluid. Then the fluid was injected into the medium in the 3rd stage of the oil recovery to present EOR stage. It was found that ZnO nanofluid has the ability to extract 8% of the original oil in place (OOIP).


Insects ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1017
Author(s):  
Sarayut Pittarate ◽  
Julius Rajula ◽  
Afroja Rahman ◽  
Perumal Vivekanandhan ◽  
Malee Thungrabeab ◽  
...  

Fall armyworm Spodoptera frugiperda is a major pest of corn, rice, and sorghum among other crops usually controlled using synthetic or biological insecticides. Currently, the new invention of nanotechnology is taking root in the agricultural industry as an alternative source of pest management that is target-specific, safe, and efficient. This study sought to determine the efficacy of commercial Zinc Oxide (ZnO) nanoparticles (NPs) towards S. frugiperda under laboratory conditions. ZnO NPs were diluted into different concentrations (100–500 ppm), where the baby corn used to feed the S. frugiperda larvae was dipped. The development of the insect feeding on food dipped in ZnO solution was significantly (p < 0.05) affected, and the number of days that the insect took to complete its life cycle had a significant difference compared to the control. There was a significant difference in the adults’ emergence in all the concentrations of ZnO NPs compared to the control, with over 90% of the eggs successfully going through the life cycle until adult emergence. Additionally, several body malformations were observed throughout the lifecycle of the insect. Also, the fecundity of the females was greatly affected. The findings of this study suggest the possibility of exploitation of ZnO nanoparticles not only to manage S. frugiperda but to significantly reduce their population in the ecosystem through body deformations, reduced fecundity, reduced oviposition, and hatchability of eggs. It will be a valuable tool in integrated pest management regimens.


2021 ◽  
Author(s):  
Rania Farouq ◽  
Ehsan Kh. Ismaeel ◽  
Aliaa M. Monazie

Abstract The present study is set out to determine the photocatalytic degradation potential of ZnO nanoparticles for effective degradation of Eosin dye. The heterogeneous photocatalytic experiments were carried out by irradiating aqueous dye solutions with ultraviolet light. The influence of effective parameters like flow rate, pH, catalyst dose, and dye concentration was examined. The best degradation efficiency (66.82%) of ZnO Nanoparticles against Eosin dye was achieved within 90 min of reaction time. The Box–Behnken design under the Response Surface Methodology (RSM) was chosen as a statistical tool to obtain the correlation of influential parameters. The optimum values were recorded as follows: 0.59 g, 15.75 ppm and 136.12 ml/min for amount of catalyst, dye concentration and flow rate, respectively. The maximum percent degradation achieved at these conditions was 71.44%.


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