Chlorine doped Li1.3Al0.3Ti1.7(PO4)3 as an electrolyte for solid lithium metal batteries

2021 ◽  
Author(s):  
Shuyuan Li ◽  
Zhongyuan Huang ◽  
Yinguo Xiao ◽  
Chunwen Sun
Keyword(s):  
Solid State ◽  
Mechanical Strength ◽  
Lithium Metal ◽  
Existing Problems ◽  
Lithium Metal Batteries ◽  
Liquid Electrolytes ◽  
Solid State Electrolytes

Solid-state electrolytes (SSEs) are expected to replace liquid electrolytes in lithium metal batteries (LMBs) with good safety and mechanical strength. However, the existing problems of Li1.3Al0.3Ti1.7(PO4)3 (LATP) electrolyte like their...

Interface engineering of inorganic solid-state electrolytes for high-performance lithium metal batteries

2020 ◽  
Vol 13 (11) ◽  
pp. 3780-3822 ◽  
Author(s):  
Xianguang Miao ◽  
Huiyang Wang ◽  
Rui Sun ◽  
Chengxiang Wang ◽  
Zhiwei Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
High Performance ◽  
Lithium Metal ◽  
Interface Engineering ◽  
Lithium Metal Batteries ◽  
Solid State Electrolytes

This review presents the mechanisms, challenges, strategies, and perspectives in the interface engineering of inorganic-based solid-state Li metal batteries.

scholarly journals Perovskite Solid-State Electrolytes for Lithium Metal Batteries

Batteries ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 75
Author(s):  
Shuo Yan ◽  
Chae-Ho Yim ◽  
Vladimir Pankov ◽  
Mackenzie Bauer ◽  
Elena Baranova ◽  
...  
Keyword(s):  
Solid State ◽  
Organic Liquid ◽  
Lithium Ion ◽  
Polymeric Materials ◽  
Inorganic Materials ◽  
Lithium Metal ◽  
Structure Property ◽  
Lithium Metal Batteries ◽  
Electrochemical Window ◽  
Solid State Electrolytes

Solid-state lithium metal batteries (LMBs) have become increasingly important in recent years due to their potential to offer higher energy density and enhanced safety compared to conventional liquid electrolyte-based lithium-ion batteries (LIBs). However, they require highly functional solid-state electrolytes (SSEs) and, therefore, many inorganic materials such as oxides of perovskite La2/3−xLi3xTiO3 (LLTO) and garnets La3Li7Zr2O12 (LLZO), sulfides Li10GeP2S12 (LGPS), and phosphates Li1+xAlxTi2−x(PO4)3x (LATP) are under investigation. Among these oxide materials, LLTO exhibits superior safety, wider electrochemical window (8 V vs. Li/Li+), and higher bulk conductivity values reaching in excess of 10−3 S cm−1 at ambient temperature, which is close to organic liquid-state electrolytes presently used in LIBs. However, recent studies focus primarily on composite or hybrid electrolytes that mix LLTO with organic polymeric materials. There are scarce studies of pure (100%) LLTO electrolytes in solid-state LMBs and there is a need to shed more light on this type of electrolyte and its potential for LMBs. Therefore, in our review, we first elaborated on the structure/property relationship between compositions of perovskites and their ionic conductivities. We then summarized current issues and some successful attempts for the fabrication of pure LLTO electrolytes. Their electrochemical and battery performances were also presented. We focused on tape casting as an effective method to prepare pure LLTO thin films that are compatible and can be easily integrated into existing roll-to-roll battery manufacturing processes. This review intends to shed some light on the design and manufacturing of LLTO for all-ceramic electrolytes towards safer and higher power density solid-state LMBs.

Highly Conjugated Three-Dimensional Covalent Organic Frame- works with Enhanced Li-ion Conductivity as Solid-State Electrolytes for High-Performance Lithium Metal Batteries

2022 ◽  
Author(s):  
Shi Wang ◽  
Xiang-Chun Li ◽  
Tao Cheng ◽  
Yuan-Yuan Liu ◽  
Qiange Li ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
High Performance ◽  
Three Dimensional ◽  
Ion Conductivity ◽  
Covalent Organic Frameworks ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Li Ion ◽  
Solid State Electrolytes

Covalent organic frameworks (COFs) with well-tailored channels have the potential to efficiently transport ions yet remain to be explored. The ion transport capability is generally limited due to the lack...

scholarly journals Challenges and prospects of the role of solid electrolytes in the revitalization of lithium metal batteries

2016 ◽  
Vol 4 (44) ◽  
pp. 17251-17259 ◽  
Author(s):  
Alberto Varzi ◽  
Rinaldo Raccichini ◽  
Stefano Passerini ◽  
Bruno Scrosati
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
High Energy ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Solid State Electrolytes

Solid-state electrolytes for high energy lithium metal batteries are reviewed and critically discussed.

Nanocomposites of Titanium Dioxide and Polystyrene-Poly(ethylene oxide) Block Copolymer as Solid-State Electrolytes for Lithium Metal Batteries

2013 ◽  
Vol 160 (9) ◽  
pp. A1611-A1617 ◽  
Author(s):  
Inna Gurevitch ◽  
Raffaella Buonsanti ◽  
Alexander A. Teran ◽  
Bernd Gludovatz ◽  
Robert O. Ritchie ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Solid State ◽  
Block Copolymer ◽  
Ethylene Oxide ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Poly Ethylene Oxide ◽  
Solid State Electrolytes ◽  
Poly Ethylene

Electrospun Li1.3Al0.3Ti1.7(PO4)3 Nanofibers to Develop Solid-State Electrolytes for Lithium Metal Batteries

2020 ◽  
Vol MA2020-01 (4) ◽  
pp. 564-564
Author(s):  
Andrea La Monaca ◽  
Andrea Paolella ◽  
Abdelbast Guerfi ◽  
Federico Rosei ◽  
Karim Zaghib
Keyword(s):  
Solid State ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Solid State Electrolytes

Mesoporous silica/ionic liquid quasi-solid-state electrolytes and their application in lithium metal batteries

2015 ◽  
Vol 278 ◽  
pp. 128-132 ◽  
Author(s):  
Xiaowei Li ◽  
Zhengxi Zhang ◽  
Kun Yin ◽  
Li Yang ◽  
Kazuhiro Tachibana ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Mesoporous Silica ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Solid State Electrolytes

Functional polyethylene glycol based solid electrolytes with enhanced interfacial compatibility for room-temperature lithium metal batteries

2021 ◽  
Author(s):  
Yuhang Zhang ◽  
Shimou Chen ◽  
Yong Chen ◽  
Lingdong Li
Keyword(s):  
Polyethylene Glycol ◽  
Solid State ◽  
Solid Electrolytes ◽  
Room Temperature ◽  
In Situ Polymerization ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Interfacial Compatibility ◽  
Solid State Electrolytes

The interface issues of electrodes/solid-state electrolytes have been limiting the application for room-temperature lithium metal batteries. In-situ polymerization technology achieved the establishment of solid-solid ultra-conformal interface contacts. However, few considerations...

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