Conversion of a double‐tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process

2022 ◽  
Author(s):  
Sandra Fernández-Fariña ◽  
Luis Miguel González-Barcia ◽  
María José Romero ◽  
Javier García-Tojal ◽  
Marcelino Maneiro ◽  
...  
Keyword(s):  
Electrochemical Synthesis ◽  
Tetranuclear Cluster ◽  
Desulfurization Process

We present the first example of a silver double‐tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform...

ELECTROCHEMICAL SYNTHESIS OF NANOSTRUCTURED COATING BASED ON TITANIUM DIOXIDE

2017 ◽  
Vol 62 ◽  
pp. 171-177
Author(s):  
D. V. Suvorov ◽  
◽  
G. P. Gololobov ◽  
M. А. Serpova ◽  
Yu. M. Stryuchkova ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Electrochemical Synthesis ◽  
Nanostructured Coating

scholarly journals Investigation of the emission control of sulfur trioxide aerosols based on heterogeneous condensation and the deflectors tray of the desulfurization tower

RSC Advances ◽  
2020 ◽  
Vol 10 (63) ◽  
pp. 38515-38523
Author(s):  
Rui Zhang ◽  
Xiaodong Si ◽  
Lingling Zhao ◽  
Linjun Yang ◽  
Hao Wu
Keyword(s):  
Flue Gas ◽  
Sulfur Trioxide ◽  
Emission Control ◽  
Flue Gas Desulfurization ◽  
Heterogeneous Condensation ◽  
Desulfurization Process

In this paper, control over the emission of sulfur trioxide aerosols was investigated based on heterogeneous condensation in the wet flue gas desulfurization process.

scholarly journals In-situ Electrochemical Synthesis of Core-shell Structural NbC@Nb5Si3/Nb Composites in Molten Salt

2021 ◽  
Vol 714 (3) ◽  
pp. 032008
Author(s):  
Hongmei Li ◽  
Zhisheng Nong ◽  
Qian Xu ◽  
Qiushi Song ◽  
Ying Chen ◽  
...  
Keyword(s):  
Molten Salt ◽  
Electrochemical Synthesis ◽  
Core Shell

scholarly journals Kinetic and deuterium isotope analyses of ammonia electrochemical synthesis

RSC Advances ◽  
2021 ◽  
Vol 11 (29) ◽  
pp. 17891-17900
Author(s):  
Chien-I. Li ◽  
Hiroki Matsuo ◽  
Junichiro Otomo
Keyword(s):  
Electrochemical Synthesis ◽  
Surface Reaction ◽  
Electrochemical Promotion ◽  
Isotope Analyses ◽  
Ammonia Formation

Electrochemical promotion of ammonia formation is mainly governed by surface reaction with N2 and H2 in the cathode.

scholarly journals Metal‐free Electrochemical Synthesis of Sulfonamides Directly from (Hetero)arenes, SO2 and Amines

2020 ◽  
Author(s):  
Stephan P. Blum ◽  
Tarik Karakaya ◽  
Dieter Schollmeyer ◽  
Siegfried R Waldvogel ◽  
Artis Klapars
Keyword(s):  
Electrochemical Synthesis ◽  
Metal Free

Electrochemical synthesis of Isobenzofuran-1-imines using Oxidative Halocyclization of o‑Alkynylbenzamides

2021 ◽  
Author(s):  
Anandhan Ramasamy ◽  
Mandapati Bhargava Reddy ◽  
Raja Gopal P ◽  
Muthuraaman B
Keyword(s):  
Electrochemical Synthesis ◽  
Reaction Conditions

Electrochemical oxidative 5-exo-dig-oxo-halocyclization of o-alkynylbenzamides was achieved using readily available NaX (X = Cl, Br and I) salts under mild reaction conditions. The use of cheap and highly stable sodium...

Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates

2021 ◽  
Author(s):  
Vera A. Vil’ ◽  
Valentina M. Merkulova ◽  
Alexey I. Ilovaisky ◽  
Stanislav A. Paveliev ◽  
Gennady I. Nikishin ◽  
...  
Keyword(s):  
Electrochemical Synthesis ◽  
Enol Acetates

scholarly journals A Radiometric Technique for Monitoring the Desulfurization Process of Blister Copper

Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 842
Author(s):  
Alejandro Vásquez ◽  
Francisco Pérez ◽  
Maximiliano Roa ◽  
Ignacio Sanhueza ◽  
Hugo Rojas ◽  
...  
Keyword(s):  
Near Infrared ◽  
Spectral Emissivity ◽  
Optical Probe ◽  
Blister Copper ◽  
Optical Absorption Spectroscopy ◽  
Total Irradiance ◽  
Desulfurization Process ◽  
Radiometric Technique ◽  
Collimating Lens ◽  
Total Emissivity

In this paper, a novel optical technique for following the progress of the blister copper desulfurization process is presented. The technique is based on the changes observed in the continuous spectrum of the visible–near-infrared (VIS–NIR) radiation that the blister melt emits while the chemical reactions of the sulfur elimination process are taking place. Specifically, the proposed technique uses an optical probe composed of an optical fiber, a collimating lens, and a quartz tube, which is immersed in the melt. This optical probe provides a field of view of the blowing zone where the desulfurization reaction occurs. The experimental results show that the melt VIS–NIR total irradiance evolves inversely to the SO2 concentration reported by a gas analyzer based on differential optical absorption spectroscopy. Furthermore, the blister copper spectral emissivity as well as the total emissivity observed throughout the process show strong correlation with the sulfur content during desulfurization reaction.

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