Dielectric switching, SHG response and Pd(ii) adsorption of a multifunctional phase-transition complex

2021 ◽  
Author(s):  
Yu-Zhen Wang ◽  
Ping-Ping Shi ◽  
Ke Xu ◽  
Lei He ◽  
Xin Meng ◽  
...  
Keyword(s):  
Phase Transition ◽  
Coordination Polymer ◽  
Dielectric Anomaly ◽  
One Dimensional ◽  
Transition Complex

One-dimensional coordination polymer [(C2H4OH)C4H9NS]CdCl3 has the performance of dielectric switching and SHG response. And the compound can adsorb precious Pd(ii) and the adsorption could be monitored by dielectric anomaly and SHG signal.

A Porous Coordination-Polymer Crystal Containing One-Dimensional Water Chains Exhibits Guest-Induced Lattice Distortion and a Dielectric Anomaly

2008 ◽  
Vol 120 (18) ◽  
pp. 3424-3428 ◽  
Author(s):  
HengBo Cui ◽  
Biao Zhou ◽  
La-Sheng Long ◽  
Yoshinori Okano ◽  
Hayao Kobayashi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Lattice Distortion ◽  
Dielectric Anomaly ◽  
One Dimensional ◽  
Polymer Crystal ◽  
Porous Coordination Polymer

scholarly journals Topological phase transition between a normal insulator and a topological metal state in a quasi-one-dimensional system

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Milad Jangjan ◽  
Mir Vahid Hosseini
Keyword(s):  
Phase Transition ◽  
Dimensional System ◽  
Inversion Symmetry ◽  
Topological Phase ◽  
Edge States ◽  
Zero Energy ◽  
One Dimensional ◽  
Topological Phase Transition ◽  
Metal State ◽  
Topological Metal

AbstractWe theoretically report the finding of a new kind of topological phase transition between a normal insulator and a topological metal state where the closing-reopening of bandgap is accompanied by passing the Fermi level through an additional band. The resulting nontrivial topological metal phase is characterized by stable zero-energy localized edge states that exist within the full gapless bulk states. Such states living on a quasi-one-dimensional system with three sublattices per unit cell are protected by hidden inversion symmetry. While other required symmetries such as chiral, particle-hole, or full inversion symmetry are absent in the system.

scholarly journals Copper(II) 2,2-Bis(Hydroxymethyl)Propionate Coordination Compounds with Hexamethylenetetramine: From Mononuclear Complex to One-Dimensional Coordination Polymer

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3358
Author(s):  
Sadaf Rauf ◽  
Agata Trzesowska-Kruszynska ◽  
Tomasz Sierański ◽  
Marcin Świątkowski
Keyword(s):  
Coordination Polymer ◽  
Coordination Compounds ◽  
Structural Diversity ◽  
Structural Features ◽  
Mononuclear Complex ◽  
Molar Ratio ◽  
One Dimensional ◽  
1D Coordination Polymer ◽  
Copper Coordination ◽  
Stretching Vibrations

Three new copper coordination compounds derived from 2,2-bis(hydroxymethyl)propionic acid (dmpa) and hexamethylenetetramine (hmta) were obtained and their crystal structures were determined. The stoichiometry of the reagents applied in the syntheses reflects the metal to ligand molar ratio in the formed solid products. Due to the multiple coordination modes of the used ligands, wide structural diversity was achieved among synthesized compounds, i.e., mononuclear [Cu(dmp)2(hmta)2(H2O)] (1), dinuclear [Cu2(dmp)4(hmta)2] (2), and 1D coordination polymer [Cu2(dmp)4(hmta)]n (3). Their supramolecular structures are governed by O—H•••O and O—H•••N hydrogen bonds. The compounds were characterized in terms of absorption (UV-Vis and IR) and thermal properties. The relationships between structural features and properties were discussed in detail. Owing to discrepancies in the coordination mode of a dmp ligand, bidentate chelating in 1, and bidentate bridging in 2 and 3, there is a noticeable change in the position of the bands corresponding to the stretching vibrations of the carboxylate group in the IR spectra. The differences in the structures of the compounds are also reflected in the nature and position of the UV-Vis absorption maxima, which are located at lower wavelengths for 1.

scholarly journals Pressure-induced Jahn-Teller Switch in the Homoleptic Hybrid Perovskite [(CH3)2NH2]Cu(HCOO)3: Orbital Reordering by Unconventional Degrees of Freedom

2021 ◽  
Author(s):  
Rebecca Scatena ◽  
Michał Andrzejewski ◽  
Roger D Johnson ◽  
Piero Macchi
Keyword(s):  
Phase Transition ◽  
High Pressure ◽  
Coordination Polymer ◽  
Degrees Of Freedom ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hybrid Perovskite ◽  
Jahn Teller

Through in-situ, high-pressure x-ray diffraction experiments we have shown that the homoleptic perovskite-like coordination polymer [(CH3)2NH2]Cu(HCOO)3 undergoes a pressure-induced orbital reordering phase transition above 5.20 GPa. This transition is distinct...

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