Single- and mixed-metal-organic framework photocatalysts for carbon dioxide reduction

2021 ◽  
Author(s):  
Xiao-Yao Dao ◽  
Wei-Yin Sun
Keyword(s):  
Carbon Dioxide ◽  
Co2 Emission ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Value Added ◽  
Carbon Dioxide Reduction ◽  
Photocatalytic Reduction ◽  
Metal Organic ◽  
Carbon Dioxide Co2 ◽  
Working Out

Photocatalytic reduction of carbon dioxide (CO2) into high value-added chemical fuels is deemed as a charming way for working out energy dilemma and ameliorate the extreme CO2 emission. Metal-organic frameworks...

scholarly journals Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO2 with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization

Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3905
Author(s):  
Suleiman Gani Musa ◽  
Zulkifli Merican Aljunid Merican ◽  
Omid Akbarzadeh
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Cycloaddition Reaction ◽  
Value Added ◽  
Industrial Applications ◽  
Organic Carbonates ◽  
Metal Organic ◽  
Organic Framework

The level of carbon dioxide in the atmosphere is growing rapidly due to fossil fuel combustion processes, heavy oil, coal, oil shelter, and exhausts from automobiles for energy generation, which lead to depletion of the ozone layer and consequently result in global warming. The realization of a carbon-neutral environment is the main focus of science and academic researchers of today. Several processes were employed to minimize carbon dioxide in the air, some of which include the utilization of non-fossil sources of energy like solar, nuclear, and biomass-based fuels. Consequently, these sources were reported to have a relatively high cost of production and maintenance. The applications of both homogeneous and heterogeneous processes in carbon capture and storage were investigated in recent years and the focus now is on the conversion of CO2 into useful chemicals and compounds. It was established that CO2 can undergo cycloaddition reaction with epoxides under the influence of special catalysts to give cyclic carbonates, which can be used as value-added chemicals at a different level of pharmaceutical and industrial applications. Among the various catalysts studied for this reaction, metal-organic frameworks are now on the frontline as a potential catalyst due to their special features and easy synthesis. Several metal-organic framework (MOF)-based catalysts were studied for their application in transforming CO2 to organic carbonates using epoxides. Here, we report some recent studies of porous MOF materials and an in-depth discussion of two repeatedly used metal-organic frameworks as a catalyst in the conversion of CO2 to organic carbonates.

Synergistic effect of phosphomolybdic acid on rhodium-based metal-organic frameworks for the efficient selective photocatalytic reduction of CO2 to CO

2021 ◽  
Author(s):  
Yurong Shan ◽  
Dexiang Liu ◽  
Chunyan Xu ◽  
Peng Zhan ◽  
Hui Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electronic Structure ◽  
Synergistic Effect ◽  
Metal Organic Frameworks ◽  
Phosphomolybdic Acid ◽  
Photocatalytic Reduction ◽  
Structure And Morphology ◽  
Spherical Structure ◽  
Metal Organic ◽  
Reduction Of Co2

In this work, PMA@NH2-MIL-68(Rh) with a mangosteen spherical structure was successfully synthesized by a hydrothermal method for the photocatalytic reduction of carbon dioxide. The electronic structure and morphology of the...

scholarly journals A Cofacial Metal-Organic Framework Based Photocathode for Carbon Dioxide Reduction

2021 ◽  
Author(s):  
Bowen Ding ◽  
Bun Chan ◽  
Nicholas Proschogo ◽  
Marcello Solomon ◽  
Cameron Kepert ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Energy Harvesting ◽  
Solar Energy ◽  
Metal Organic Framework ◽  
Carbon Dioxide Reduction ◽  
Solar Energy Harvesting ◽  
Metal Organic ◽  
Organic Framework

Innovative and robust photosensitisation materials play a cardinal role in advancing the combined effort towards efficient solar energy harvesting. Here, we demonstrate the photocathode functionality of a Metal-Organic Framework (MOF)...

Hierarchical three-dimensional copper selenide nanocubes microelectrodes for improved carbon dioxide reduction reaction

2021 ◽  
Author(s):  
Rajasekaran Elakkiya ◽  
Govindhan Maduraiveeran
Keyword(s):  
Carbon Dioxide ◽  
High Performance ◽  
Three Dimensional ◽  
Co2 Reduction ◽  
Value Added ◽  
Carbon Dioxide Reduction ◽  
Reduction Reaction ◽  
Earth Abundant ◽  
Carbon Dioxide Co2 ◽  
Co2 Reduction Reaction

Design of high-performance and Earth-abundant electrocatalysts for electrochemical carbon dioxide (CO2) reduction reaction (CO2RR) into fuels and value-added chemicals offers an emergent pathway for environment and energy sustainable concerns. Herein,...

Selective adsorption behaviour of carbon dioxide in OH-functionalized metal–organic framework materials

CrystEngComm ◽  
2017 ◽  
Vol 19 (36) ◽  
pp. 5346-5350 ◽  
Author(s):  
Jinjie Qian ◽  
Jinni Shen ◽  
Qipeng Li ◽  
Yue Hu ◽  
Shaoming Huang
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Adsorption Behaviour ◽  
Weak Hydrogen Bond ◽  
Oh Groups ◽  
Framework Materials ◽  
Metal Organic

The theoretically optimal adsorption locations in hydroxyl (OH)-decorated metal–organic frameworks show that the captured CO2 molecules interact with the cis-μ2-OH groups in an end-on mode, which shows a moderate to weak hydrogen bond.

Highly efficient multi-metal catalysts for carbon dioxide reduction prepared from atomically sequenced metal organic frameworks

Nano Research ◽  
2020 ◽  
Vol 14 (2) ◽  
pp. 493-500 ◽  
Author(s):  
Celia Castillo-Blas ◽  
Consuelo Álvarez-Galván ◽  
Inés Puente-Orench ◽  
Alba García-Sánchez ◽  
Freddy E. Oropeza ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Reduction ◽  
Metal Catalysts ◽  
Highly Efficient ◽  
Metal Organic

Efficient Visible-Light-Driven Carbon Dioxide Reduction by a Single-Atom Implanted Metal-Organic Framework

2016 ◽  
Vol 128 (46) ◽  
pp. 14522-14526 ◽  
Author(s):  
Huabin Zhang ◽  
Jing Wei ◽  
Juncai Dong ◽  
Guigao Liu ◽  
Li Shi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Visible Light ◽  
Metal Organic Framework ◽  
Carbon Dioxide Reduction ◽  
Single Atom ◽  
Visible Light Driven ◽  
Metal Organic ◽  
Organic Framework

Metal–organic redox vehicles to encapsulate organic dyes for photocatalytic protons and carbon dioxide reduction

2016 ◽  
Vol 3 (10) ◽  
pp. 1256-1263 ◽  
Author(s):  
Hao Yu ◽  
Cheng He ◽  
Jing Xu ◽  
Chunying Duan ◽  
Joost N. H. Reek
Keyword(s):  
Carbon Dioxide ◽  
Organic Dyes ◽  
Carbon Dioxide Reduction ◽  
Organic Dye ◽  
Photocatalytic Reduction ◽  
Metal Organic

By encapsulation of an organic dye, a supramolecular nickel–organic macrocycle for the photocatalytic reduction of protons and CO2 has been reported.

scholarly journals Enhanced CO2 adsorption capacity of amine-functionalized MIL-100(Cr) metal–organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 430-437 ◽  
Author(s):  
Carlos Palomino Cabello ◽  
Gloria Berlier ◽  
Giuliana Magnacca ◽  
Paolo Rumori ◽  
Gemma Turnes Palomino
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Capacity ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Sorption Properties ◽  
Amine Functionalized ◽  
Carbon Dioxide Sorption ◽  
Metal Organic ◽  
Co2 Adsorption Capacity

Functionalization of the MIL-100(Cr) metal–organic framework with alkylamines (ethylenediamine and N,N′-dimethylethylenediamine) improves carbon dioxide sorption properties, especially in the case of ethylenediamine.

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