Solvent assisted delamination of the layered copper dithi-enothiophene-dicarboxylate (DUT-134)

2021 ◽  
Author(s):  
Friedrich Schwotzer ◽  
Irena Senkovska ◽  
Volodymyr Bon ◽  
Stefanie Lochmann ◽  
Jack D. Evans ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Research Field ◽  
Shape Anisotropy ◽  
Sophisticated Method ◽  
Metal Organic ◽  
Active Research ◽  
2D Nanosheets

The isolation of 2D nanosheets of layered metal-organic frameworks (MOFs) has become an active research field, due to the various advantages resulting from shape anisotropy. The most sophisticated method to...

scholarly journals Application of MD Simulations to Predict Membrane Properties of MOFs

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Elda Adatoz ◽  
Seda Keskin
Keyword(s):  
Metal Organic Frameworks ◽  
Experimental Studies ◽  
Molecular Simulations ◽  
Md Simulations ◽  
Research Field ◽  
Computational Approach ◽  
Membrane Properties ◽  
Important Research ◽  
Zeolite Membranes ◽  
Metal Organic

Metal organic frameworks (MOFs) are a new group of nanomaterials that have been widely examined for various chemical applications. Gas separation using MOF membranes has become an increasingly important research field in the last years. Several experimental studies have shown that thin-film MOF membranes can outperform well known polymer and zeolite membranes due to their higher gas permeances and selectivities. Given the very large number of available MOF materials, it is impractical to fabricate and test the performance of every single MOF membrane using purely experimental techniques. In this study, we used molecular simulations, Monte Carlo and Molecular Dynamics, to estimate both single-gas and mixture permeances of MOF membranes. Predictions of molecular simulations were compared with the experimental gas permeance data of MOF membranes in order to validate the accuracy of our computational approach. Results show that computational methodology that we described in this work can be used to accurately estimate membrane properties of MOFs prior to extensive experimental efforts.

Fluoride sensing performance of fluorescent NH2-MIL-53(Al): 2D Nanosheets vs. 3D Bulk

2021 ◽  
Author(s):  
Zixuan Li ◽  
Deyi Zhan ◽  
Abdul Saeed ◽  
Nanjing Zhao ◽  
Junfeng Wang ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Metal Organic ◽  
2D Nanosheets ◽  
Fluoride Sensing ◽  
Sensing Performance

Due to the ultra-thin morphology, larger specific surface area and more exposed active sites, two-dimensional (2D) metal-organic frameworks (MOFs) nanosheets can break the limitations of three-dimensional (3D) MOFs in sensitivity,...

An overview: synthesis of thin films/membranes of metal organic frameworks and its gas separation performances

RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54322-54334 ◽  
Author(s):  
Zee Ying Yeo ◽  
Siang-Piao Chai ◽  
Peng Wei Zhu ◽  
Abdul Rahman Mohamed
Keyword(s):  
Thin Films ◽  
Gas Separation ◽  
Materials Science ◽  
Metal Organic Frameworks ◽  
Research Field ◽  
Porous Solid ◽  
Solid Materials ◽  
Metal Organic ◽  
Separation Performances ◽  
Intense Research

Metal organic frameworks (MOFs), an emerging class of porous solid materials, have developed into a constructive research field with intense research interests mainly in the field of materials science and chemistry.

scholarly journals Gas adsorption applications of porous metal–organic frameworks

2009 ◽  
Vol 81 (12) ◽  
pp. 2235-2251 ◽  
Author(s):  
Shengqian Ma
Keyword(s):  
Hydrogen Storage ◽  
Recent Progress ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Functional Materials ◽  
Research Field ◽  
Methane Storage ◽  
Metal Organic ◽  
New Type

Porous metal–organic frameworks (MOFs) represent a new type of functional materials and have recently become a hot research field due to their great potential in various applications. In this review, recent progress of gas adsorption applications of porous MOFs, mainly including hydrogen storage, methane storage, and selective gas adsorption will be briefly summarized.

scholarly journals Facet engineering in metal organic frameworks to improve their electrochemical activity for water oxidation

2020 ◽  
Vol 56 (31) ◽  
pp. 4316-4319 ◽  
Author(s):  
Jiawei Wan ◽  
Di Liu ◽  
Hai Xiao ◽  
Hongpan Rong ◽  
Sheng Guan ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Low Cost ◽  
Metal Organic Frameworks ◽  
Electrochemical Activity ◽  
Excellent Activity ◽  
Metal Organic ◽  
2D Nanosheets

We present a facile and low-cost method to shape ZIF into 2D nanosheets with exposed (002) facets and discover that they exhibit excellent activity for oxygen evolution reaction.

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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