A novel Cd-MOF with enhanced thermo-sensitivity：The rational design, synthesis and multipurpose applications

2021 ◽  
Author(s):  
Ping Ju ◽  
Meng-Ting Li ◽  
Hua Yang ◽  
Long Jiang ◽  
Lian Xia ◽  
...  
Keyword(s):  
Rational Design ◽  
Design Synthesis ◽  
Sensing Applications ◽  
Sensitive Property

A novel fluorescent Cd-MOF probe [Cd2(btec)(TPB)0.5(H2O)4]•2H2O (complex 1, TPB = 1,2,4,5-Tetra(4-pyridyl)benzene) have been rationally designed, synthesized and its multipurpose sensing applications have been revealed. Thermo-sensitive property of complex 1 was...

scholarly journals Anisotropic, Wrinkled, and Crack-Bridging Structure for Ultrasensitive, Highly Selective Multidirectional Strain Sensors

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Heng Zhang ◽  
Dan Liu ◽  
Jeng-Hun Lee ◽  
Haomin Chen ◽  
Eunyoung Kim ◽  
...  
Keyword(s):  
Rational Design ◽  
Full Range ◽  
Human Motion ◽  
Strain Sensors ◽  
Gauge Factor ◽  
Wearable Electronics ◽  
Trade Off ◽  
Human Motion Detection ◽  
Sensing Applications ◽  
Anisotropic Structures

AbstractFlexible multidirectional strain sensors are crucial to accurately determining the complex strain states involved in emerging sensing applications. Although considerable efforts have been made to construct anisotropic structures for improved selective sensing capabilities, existing anisotropic sensors suffer from a trade-off between high sensitivity and high stretchability with acceptable linearity. Here, an ultrasensitive, highly selective multidirectional sensor is developed by rational design of functionally different anisotropic layers. The bilayer sensor consists of an aligned carbon nanotube (CNT) array assembled on top of a periodically wrinkled and cracked CNT–graphene oxide film. The transversely aligned CNT layer bridge the underlying longitudinal microcracks to effectively discourage their propagation even when highly stretched, leading to superior sensitivity with a gauge factor of 287.6 across a broad linear working range of up to 100% strain. The wrinkles generated through a pre-straining/releasing routine in the direction transverse to CNT alignment is responsible for exceptional selectivity of 6.3, to the benefit of accurate detection of loading directions by the multidirectional sensor. This work proposes a unique approach to leveraging the inherent merits of two cross-influential anisotropic structures to resolve the trade-off among sensitivity, selectivity, and stretchability, demonstrating promising applications in full-range, multi-axis human motion detection for wearable electronics and smart robotics.

scholarly journals Rational Design, Synthesis, and Evaluation of Tetrahydroxamic Acid Chelators for Stable Complexation of Zirconium(IV)

2014 ◽  
Vol 20 (19) ◽  
pp. 5584-5591 ◽  
Author(s):  
François Guérard ◽  
Yong-Sok Lee ◽  
Martin W. Brechbiel
Keyword(s):  
Rational Design ◽  
Design Synthesis

The design, synthesis and fluorescent sensing applications of a thermo-sensitive Zn-MOF

2021 ◽  
pp. 122476
Author(s):  
Ensheng Zhang ◽  
Long Jiang ◽  
Ruijiang lv ◽  
Shiyang Li ◽  
Rongmei Kong ◽  
...  
Keyword(s):  
Design Synthesis ◽  
Fluorescent Sensing ◽  
Sensing Applications

Rational Design, Synthesis, and DNA Binding Properties of Novel Sequence-Selective Peptidyl Congeners of Ametantrone

ChemMedChem ◽  
2010 ◽  
Vol 5 (7) ◽  
pp. 1080-1091 ◽  
Author(s):  
Alessandra Gianoncelli ◽  
Serena Basili ◽  
Matteo Scalabrin ◽  
Alice Sosic ◽  
Stefano Moro ◽  
...  
Keyword(s):  
Dna Binding ◽  
Rational Design ◽  
Binding Properties ◽  
Design Synthesis ◽  
Dna Binding Properties
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