Triptycene-supported bimetallic salen porous organic polymers for high efficiency CO2 fixation to cyclic carbonates

2021 ◽  
Author(s):  
Jianzhuang Jiang ◽  
Yingting Zheng ◽  
Xiqian Wang ◽  
Chao Liu ◽  
Baoqiu Yu ◽  
...  
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Co2 Fixation ◽  
High Efficiency ◽  
Two Dimensional ◽  
Cyclic Carbonates ◽  
Organic Polymers ◽  
Porous Organic Polymers

Exposing active sites of heterogeneous catalysts is very important for catalysis. Herein, a series of two-dimensional (2D) bimetallic salen-based porous organic polymers BSPOPs (BSPOP-Al, BSPOP-Co, and BSPOP-Ni) have been elaborated...

Mg–porphyrin complex doped divinylbenzene based porous organic polymers (POPs) as highly efficient heterogeneous catalysts for the conversion of CO2 to cyclic carbonates

2018 ◽  
Vol 47 (37) ◽  
pp. 13135-13141 ◽  
Author(s):  
Wenlong Wang ◽  
Cunyao Li ◽  
Jutao Jin ◽  
Li Yan ◽  
Yunjie Ding
Keyword(s):  
Heterogeneous Catalysts ◽  
Cyclic Carbonates ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Porphyrin Complex ◽  
Highly Efficient

Mg–porphyrin complex doped divinylbenzene based POPs were afforded as heterogeneous catalysts for the conversion of CO2 to cyclic carbonates.

Recent advances in CO2 capture and simultaneous conversion into cyclic carbonates over porous organic polymers having accessible metal sites

2020 ◽  
Vol 8 (36) ◽  
pp. 18408-18424 ◽  
Author(s):  
Rongchang Luo ◽  
Min Chen ◽  
Xiangying Liu ◽  
Wei Xu ◽  
Jiayi Li ◽  
...  
Keyword(s):  
Active Sites ◽  
Cycloaddition Reaction ◽  
Cyclic Carbonates ◽  
Organic Polymers ◽  
Structure Property ◽  
Porous Organic Polymers ◽  
Design And Synthesis ◽  
Recent Advances ◽  
Structure Property Relationship ◽  
Metal Catalyzed

This review describes the recent advances in the design and synthesis of metal-functionalized porous organic polymers featuring accessible active sites and discloses the structure–property relationship in the metal-catalyzed CO2 cycloaddition reaction to epoxides.

Phosphorus Containing Porous Organic Polymers: Synthetic Techniques and Applications in Organic Synthesis and Catalysis

2021 ◽  
Author(s):  
Pramod Kumar ◽  
Animesh Das ◽  
Biplab Maji
Keyword(s):  
Organic Synthesis ◽  
Homogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Organic Polymer ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Porous Organic Polymer ◽  
Phosphorus Containing

The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...

Hydroxyl-anchored covalent organic crown-based polymers for CO2 fixation into cyclic carbonates at mild condition

2021 ◽  
Author(s):  
Yongjing Hao ◽  
Xiuli Yan ◽  
Tao Chang ◽  
Xiaohuan Liu ◽  
Lianwei Kang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mild Condition ◽  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Organic Polymers ◽  
Carbon Dioxide Co2

The covalent organic polymers (COPs) are a kind of promising materials for carbon dioxide (CO2) reutilization. Herein, a series of covalent organic crown-based polymers (COCP-H, COCP-OH, COCP-CH3, COCP-Bu) were designed...

Synthesis of metalloporphyrin-based porous organic polymers and their functionalization for conversion of CO2 into cyclic carbonates: recent advances, opportunities and challenges

2021 ◽  
Author(s):  
Rongchang Luo ◽  
Min Chen ◽  
Farong Zhou ◽  
Jiamin Zhan ◽  
Qi Deng ◽  
...  
Keyword(s):  
Cyclic Carbonates ◽  
Organic Polymers ◽  
Specific Design ◽  
Porous Organic Polymers ◽  
Design And Synthesis ◽  
Recent Advances ◽  
Made In

This review summarized the recent advances made in the task-specific design and synthesis of metalloporphyrin-based porous organic polymers (POPs) and their functionalization for conversion of CO2 into cyclic carbonates.

Porous noria polymer: a cage-to-network approach toward a robust catalyst for CO2 fixation and nitroarene reduction

2021 ◽  
Author(s):  
Arkaprabha Giri ◽  
Niraj Nitish Patil ◽  
Abhijit Patra
Keyword(s):  
Catalytic Activity ◽  
Co2 Fixation ◽  
Organic Polymers ◽  
Network Approach ◽  
Porous Organic Polymers ◽  
Nitroarene Reduction

A ‘preporous’ waterwheel-like molecular cage, noria, was knitted with rigid aromatic linkers to obtain porous organic polymers exhibiting excellent catalytic activity toward CO2 fixation and nitroarene reduction.

Ni and Zn N-confused porphyrin complexes as recyclable catalysts for high efficiency solvent-free CO2 fixation into cyclic carbonates

2021 ◽  
Author(s):  
Jay-ar B. dela Cruz ◽  
Chen-Hsiung Hung
Keyword(s):  
Co2 Fixation ◽  
High Efficiency ◽  
Bifunctional Catalyst ◽  
Solvent Free ◽  
Glycerol Carbonate ◽  
Cyclic Carbonates ◽  
Recyclable Catalysts

ZnII[2-N(CH2)5N+(CH3)3Br−NCTPP] is a bifunctional catalyst that exhibits efficiency for CO2 fixation with epoxides with TOF up to 370 000 h−1 and TON 1.3 × 106. It can also be recycled for the formation of glycerol carbonate from CO2 and glycidol.

Porous Organic Polymers Constructed from Tröger's Base as Efficient Carbon Dioxide Adsorbents and Heterogeneous Catalysts

ChemCatChem ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 1900-1904 ◽  
Author(s):  
Zhifeng Dai ◽  
Yongquan Tang ◽  
Qi Sun ◽  
Xiaolong Liu ◽  
Xiangju Meng ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalysts ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Troger's Base
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