scholarly journals Correction: When Mayo falls short (Ctr ≫ 1): the use of cumulative chain length distribution data in the determination of chain transfer constants (Ctr) for radical polymerizations

2021 ◽  
Vol 12 (6) ◽  
pp. 947-947
Author(s):  
Matt K. Donald ◽  
Stefan A. F. Bon
Keyword(s):  
Chain Length ◽  
Chain Transfer ◽  
Length Distribution ◽  
Distribution Data ◽  
Chain Length Distribution ◽  
Radical Polymerizations

Correction for ‘When Mayo falls short (Ctr ≫ 1): the use of cumulative chain length distribution data in the determination of chain transfer constants (Ctr) for radical polymerizations’ by Matt K. Donald and Stefan A. F. Bon, Polym. Chem., 2020, 11, 4281–4289, DOI: 10.1039/D0PY00348D.

When Mayo falls short (Ctr ≫ 1): the use of cumulative chain length distribution data in the determination of chain transfer constants (Ctr) for radical polymerizations

2020 ◽  
Vol 11 (26) ◽  
pp. 4281-4289
Author(s):  
Matt K. Donald ◽  
Stefan A. F. Bon
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Chain Length ◽  
Weight Distribution ◽  
Chain Transfer ◽  
Length Distribution ◽  
Distribution Data ◽  
Chain Length Distribution ◽  
Radical Polymerizations

A method to determine chain transfer constants in free radical polymerizations that are >1 using molecular weight distribution data.

scholarly journals Fundamentals of reversible addition–fragmentation chain transfer (RAFT)

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Catherine L. Moad ◽  
Graeme Moad
Keyword(s):  
Radical Polymerization ◽  
Chain Length ◽  
Molar Mass ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Length Distribution ◽  
Chain Length Distribution ◽  
Reversible Addition ◽  
Raft Agent ◽  
End Group

Abstract Radical polymerization is transformed into what is known as reversible addition–fragmentation chain transfer (RAFT) polymerization by the addition of a RAFT agent. RAFT polymerization enables the preparation of polymers with predictable molar mass, narrow chain length distribution, high end-group integrity and provides the ability to construct macromolecules with the intricate architectures and composition demanded by modern applications in medicine, electronics and nanotechnology. This paper provides a background to understanding the mechanism of RAFT polymerization and how this technique has evolved.

Comparison of the Mayo and Chain Length Distribution Procedures for the Measurement of Chain Transfer Constants

1999 ◽  
Vol 32 (19) ◽  
pp. 6019-6030 ◽  
Author(s):  
Johan P. A. Heuts ◽  
Thomas P. Davis ◽  
Gregory T. Russell
Keyword(s):  
Chain Length ◽  
Chain Transfer ◽  
Length Distribution ◽  
Chain Length Distribution
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