Cyclic olefin copolymers containing both linear polyethylene and poly(ethylene-co-norbornene) segments prepared from chain shuttling copolymerization of ethylene and norbornene

2021 ◽  
Author(s):  
Huan Gao ◽  
Shangtao Chen ◽  
Bin Du ◽  
Zhenyu Dai ◽  
Xu Lu ◽  
...  

The semicrystalline polyethylene (PE) and amorphous poly(ethylene-co-norbornene) copolymer have been used in a wide variety of applications, especially in packaging. It is a big challenge to improve the transparency of...

2005 ◽  
Vol 45 (2) ◽  
pp. 116-123 ◽  
Author(s):  
Gwan Kyo Oh ◽  
Tadashi Inoue

Polymer ◽  
2018 ◽  
Vol 136 ◽  
pp. 109-113 ◽  
Author(s):  
Ryo Tanaka ◽  
Akane Sasaki ◽  
Takuma Takenaka ◽  
Yuushou Nakayama ◽  
Takeshi Shiono

2012 ◽  
Vol 126 (3) ◽  
pp. 1121-1128 ◽  
Author(s):  
Zhen-hua Chen ◽  
Changchun Zeng ◽  
Chuck Zhang ◽  
Ben Wang ◽  
Kun Cao ◽  
...  

2017 ◽  
Vol 34 (2) ◽  
pp. 140-159 ◽  
Author(s):  
Ali Durmus ◽  
Mine B Alanalp ◽  
Ismail Aydin

In this study, cyclic olefin copolymer/poly(ethylene- co-vinyl acetate) 90/10, 80/20, and 70/30 blends were prepared by melt processing in a twin screw extruder equipped with a cast film haul-off unit to make films. Microstructural, rheological, mechanical, and viscoelastic properties of film samples were investigated by various tests performed in scanning electron microscope, rotational rheometer, dynamic mechanical analyzer, and tensile test machine. We observed that the films exhibited characteristic immiscible “matrix–droplet” or “cocontinuous” blend morphology, depending on the sample composition. Based on the melt rheology and dynamic mechanical analyzer tests, we found that poly(ethylene- co-vinyl acetate) addition changed the viscoelastic properties of cyclic olefin copolymer such as increasing short-term creep strain and relaxation time but reducing relaxation rate in solid state. One can conclude that such effects became more pronounced by adding a compatibilizer (PE-g-MA) at 50% of poly(ethylene- co-vinyl acetate) present in the composition. We also found that poly(ethylene- co-vinyl acetate) addition into cyclic olefin copolymer reduced the Young’s modulus and yield stress and increased the strain at break for the blends.


2019 ◽  
Vol 97 ◽  
pp. 377-387
Author(s):  
Mélisande Bernard ◽  
Emile Jubeli ◽  
Joudi Bakar ◽  
Johanna Saunier ◽  
Najet Yagoubi

2007 ◽  
Vol 107 (4) ◽  
pp. 2584-2587 ◽  
Author(s):  
Kyusoon Shin ◽  
Byeong Uk Nam ◽  
Joona Bang ◽  
Jae Young Jho

Sign in / Sign up

Export Citation Format

Share Document