Propylene Homopolymerization and Copolymerization with Ethylene by Acenaphthene-Based α-Diimine Nickel Complexes to Access EPR-Like Elastomers

2021 ◽  
Author(s):  
Beibei Wang ◽  
Heng Liu ◽  
Chunyun Zhang ◽  
Tao Tang ◽  
Xuequan Zhang
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nickel Complexes ◽  
Late Transition Metal ◽  
Late Transition ◽  
Chain Walking

Benefiting from the unique chain walking characteristic of late transition metal complexes, branched EPR-like elastomers bearing distinct differences compared to traditional linear EPRs are reported herein. Firstly, a series of...

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

Electron-density distributions in selected ferrocenyl-pyrazolyl late transition-metal complexes

2018 ◽  
Vol 20 (17) ◽  
pp. 11682-11691
Author(s):  
M. A. Peck ◽  
G. R. Hearne ◽  
C. Obuah ◽  
J. Darkwa
Keyword(s):  
Mössbauer Spectroscopy ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electron Density ◽  
Transition Metal Complexes ◽  
Mossbauer Spectroscopy ◽  
Late Transition Metal ◽  
Density Distributions ◽  
Mößbauer Spectroscopy ◽  
Late Transition

57Fe Mössbauer spectroscopy has been used to study electronic dispersions in complexes of Fe, Co, Ni and Pd anchored onto 3-ferrocenyl-5-methylpyrazolylmethylenepyridine and 3-ferrocenylpyrazolylmethylenepyridine ligands.

Donor-Acceptor Couples and Late Transition Metal Complexes of Oxidation-Labile 1,4,5,8-Tetrakis(guanidino)naphthalene Superbases

2011 ◽  
Vol 2011 (10) ◽  
pp. 1593-1604 ◽  
Author(s):  
Viktoriia Vitske ◽  
Pascal Roquette ◽  
Simone Leingang ◽  
Christian Adam ◽  
Elisabeth Kaifer ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Late Transition Metal ◽  
Donor Acceptor ◽  
Late Transition
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