Reversible-deactivation radical polymerization of vinyl acetate mediated by tralen, an organomediator

2021 ◽  
Vol 12 (36) ◽  
pp. 5159-5167
Author(s):  
Chun-Wei Chang ◽  
Yu-Yu Jen ◽  
Shan-Cheng Tang ◽  
Pan Zhang ◽  
Changle Chen ◽  
...  
Keyword(s):  
Organic Compound ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Vinyl Pyrrolidone ◽  
Acetate Methyl ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

An organic compound, tralen, has been developed as a mediator to control the radical polymerization of vinyl acetate, methyl acrylate, and N-vinyl pyrrolidone via the reversible termination mechanism.

Aluminum Tralen Complex Meditated Reversible-Deactivation Radical Polymerization of Vinyl Acetate

2020 ◽  
Vol 9 (10) ◽  
pp. 1423-1428
Author(s):  
Shih-Ji Chen ◽  
Shan-Cheng Tang ◽  
Pan Zhang ◽  
Changle Chen ◽  
Chi-How Peng
Keyword(s):  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

Morpholine‐based RAFT agents for the reversible deactivation radical polymerization of vinyl acetate and N ‐vinylimidazole

2020 ◽  
Vol 69 (9) ◽  
pp. 883-890
Author(s):  
Kari Vijayakrishna ◽  
Kasina Manojkumar ◽  
PM Haribabu ◽  
Behera GyanaRanjan ◽  
Baisakhi Tilottama ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

Facile access to functional polyacrylates with dual stimuli response and tunable surface hydrophobicity

2021 ◽  
Author(s):  
Sk Arif Mohammad ◽  
Subrata Dolui ◽  
Devendra Kumar ◽  
Shivshankar R. Mane ◽  
Sanjib Banerjee
Keyword(s):  
Ambient Temperature ◽  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Surface Hydrophobicity ◽  
Alloy Nanoparticles ◽  
Reversible Deactivation ◽  
Stimuli Response ◽  
Magnetically Separable ◽  
Reversible Deactivation Radical Polymerization ◽  
First Time

Magnetically separable and reusable Ni-Co alloy nanoparticles was employed to achieve ambient temperature reversible deactivation radical polymerization (RDRP) of methyl acrylate (MA), for the first time, yielding well-defined PMA (at...

Photocontrolled iodine-mediated reversible-deactivation radical polymerization with a semifluorinated alternating copolymer as the macroinitiator

2020 ◽  
Vol 11 (47) ◽  
pp. 7497-7505
Author(s):  
Jiannan Cheng ◽  
Kai Tu ◽  
Enjie He ◽  
Jinying Wang ◽  
Lifen Zhang ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Room Temperature ◽  
Blue Led ◽  
Led Light ◽  
Alternating Copolymers ◽  
Alternating Copolymer ◽  
Reversible Deactivation ◽  
Novel Strategy ◽  
Reversible Deactivation Radical Polymerization

A novel strategy for preparing block copolymers with semifluorinated alternating copolymers as macroinitiators was established by photocontrolled iodine-mediated RDRP under irradiation with blue LED light at room temperature.

Copolymerization of simple methacrylates by Cu(0)-mediated reversible deactivation radical polymerization

2018 ◽  
Vol 51 (5) ◽  
pp. 449-459 ◽  
Author(s):  
Jongwon Choe ◽  
Woo Jung Lee ◽  
Han Gyeol Jang ◽  
Youngjoo Song ◽  
Jae Hyun Sim ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization
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