Synthesis of core-crosslinked star polymers via organocatalyzed living radical polymerization

2021 ◽  
Author(s):  
Yichao Zheng ◽  
Jit Sarkar ◽  
Hiroshi Niino ◽  
Shunsuke Chatani ◽  
Shu Yao Hsu ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Star Polymers ◽  
Living Radical Polymerization ◽  
Grafting Through

Core-crosslinked star polymers synthesized via a grafting-through approach using RCMP.

Poly(vinyl ester) Star Polymers via Xanthate-Mediated Living Radical Polymerization:  From Poly(vinyl alcohol) to Glycopolymer Stars

2005 ◽  
Vol 38 (13) ◽  
pp. 5475-5484 ◽  
Author(s):  
Julien Bernard ◽  
Arnaud Favier ◽  
Ling Zhang ◽  
Anastasia Nilasaroya ◽  
Thomas P. Davis ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Vinyl Alcohol ◽  
Vinyl Ester ◽  
Star Polymers ◽  
Living Radical Polymerization ◽  
Poly Vinyl Alcohol

One-Pot Synthesis of Star Polymers by Living Radical Polymerization

2003 ◽  
Vol 36 (8) ◽  
pp. 2990-2993 ◽  
Author(s):  
Koji Ishizu ◽  
Jaebum Park ◽  
Takeshi Shibuya ◽  
Atsushi Sogabe
Keyword(s):  
Radical Polymerization ◽  
Star Polymers ◽  
Living Radical Polymerization ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals Living Radical Polymerization by the RAFT Process

2005 ◽  
Vol 58 (6) ◽  
pp. 379 ◽  
Author(s):  
Graeme Moad ◽  
Ezio Rizzardo ◽  
San H. Thang
Keyword(s):  
Radical Polymerization ◽  
Polymer Brushes ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Star Polymers ◽  
Living Radical Polymerization ◽  
Factors Influencing ◽  
Reversible Addition ◽  
Complex Architectures

This paper presents a review of living radical polymerization achieved with thiocarbonylthio compounds [ZC(=S)SR] by a mechanism of reversible addition–fragmentation chain transfer (RAFT). Since we first introduced the technique in 1998, the number of papers and patents on the RAFT process has increased exponentially as the technique has proved to be one of the most versatile for the provision of polymers of well defined architecture. The factors influencing the effectiveness of RAFT agents and outcome of RAFT polymerization are detailed. With this insight, guidelines are presented on how to conduct RAFT and choose RAFT agents to achieve particular structures. A survey is provided of the current scope and applications of the RAFT process in the synthesis of well defined homo-, gradient, diblock, triblock, and star polymers, as well as more complex architectures including microgels and polymer brushes.

Highly Efficient Synthesis of Low Polydispersity Core Cross-Linked Star Polymers by Ru-Catalyzed Living Radical Polymerization

2011 ◽  
Vol 32 (5) ◽  
pp. 456-461 ◽  
Author(s):  
Tor Kit Goh ◽  
Satoshi Yamashita ◽  
Kotaro Satoh ◽  
Anton Blencowe ◽  
Masami Kamigaito ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Star Polymers ◽  
Living Radical Polymerization ◽  
Efficient Synthesis ◽  
Highly Efficient
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