Step-wise and one-pot synthesis of highly substituted conjugated trienes from 2-oxobenzo[h]chromenes/2H-pyran-2-ones

Author(s):  
Amr Elagamy ◽  
Ismail Althagafi ◽  
Ramendra Pratap

The synthesis of conjugated trienes by ring contraction of 2-oxobenzo[h]chromenes/2H-pyran-2-ones followed by decarboxylative rearrangement has been developed.

ChemInform ◽  
1987 ◽  
Vol 18 (47) ◽  
Author(s):  
W. TOCHTERMANN ◽  
K. LUTTMANN ◽  
E.-M. PETERS ◽  
K. PETERS ◽  
H. G. VON SCHNERING

2004 ◽  
Vol 45 (35) ◽  
pp. 6619-6621 ◽  
Author(s):  
Diptesh Sil ◽  
Ashoke Sharon ◽  
Prakas R. Maulik ◽  
Vishnu Ji Ram

ChemInform ◽  
2004 ◽  
Vol 35 (50) ◽  
Author(s):  
Diptesh Sil ◽  
Ashoke Sharon ◽  
Prakas R. Maulik ◽  
Vishnu Ji Ram

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>


2017 ◽  
Vol 7 (12) ◽  
pp. 1192-1195
Author(s):  
Y. I. Shaikh ◽  
G. M. Nazeruddin ◽  
Khursheed Ahmed

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