scholarly journals Enhanced Surface Area and Reduced Pore Collapse of Methylated, Imine-Linked Covalent Organic Frameworks

Nanoscale ◽  
2021 ◽  
Author(s):  
Ellen Dautzenberg ◽  
Milena Lam ◽  
Guanna Li ◽  
Louis de Smet
Keyword(s):  
Energy Storage ◽  
Surface Area ◽  
Gas Separation ◽  
High Surface ◽  
Nanoporous Materials ◽  
Covalent Organic Frameworks ◽  
Pore Collapse ◽  
Surface Areas ◽  
Enhanced Surface

Covalent Organic Frameworks (COFs) are thermally and chemically stable, nanoporous materials with high surface areas, making them interesting for a large variety of applications including energy storage, gas separation, catalysis...

scholarly journals Rapid Synthesis of High Surface Area Imine‐Linked 2D Covalent Organic Frameworks by Avoiding Pore Collapse During Isolation

2019 ◽  
Vol 32 (2) ◽  
pp. 1905776 ◽  
Author(s):  
Cameron H. Feriante ◽  
Samik Jhulki ◽  
Austin M. Evans ◽  
Raghunath R. Dasari ◽  
Kaitlin Slicker ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Covalent Organic Frameworks ◽  
Pore Collapse ◽  
Rapid Synthesis

scholarly journals Mitigating the Agglomeration of Nanofiller in a Mixed Matrix Membrane by Incorporating an Interface Agent

Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 328
Author(s):  
Manh-Tuan Vu ◽  
Gloria M. Monsalve-Bravo ◽  
Rijia Lin ◽  
Mengran Li ◽  
Suresh K. Bhatia ◽  
...  
Keyword(s):  
Gas Separation ◽  
Polymer Matrix ◽  
Ion Beam ◽  
High Surface ◽  
Mixed Matrix Membrane ◽  
Mechanical And Thermal Properties ◽  
Separation Membranes ◽  
Surface Areas ◽  
Separation Membrane ◽  
Focus Ion Beam

Nanodiamonds (ND) have recently emerged as excellent candidates for various applications including membrane technology due to their nanoscale size, non-toxic nature, excellent mechanical and thermal properties, high surface areas and tuneable surface structures with functional groups. However, their non-porous structure and strong tendency to aggregate are hindering their potential in gas separation membrane applications. To overcome those issues, this study proposes an efficient approach by decorating the ND surface with polyethyleneimine (PEI) before embedding it into the polymer matrix to fabricate MMMs for CO2/N2 separation. Acting as both interfacial binder and gas carrier agent, the PEI layer enhances the polymer/filler interfacial interaction, minimising the agglomeration of ND in the polymer matrix, which is evidenced by the focus ion beam scanning electron microscopy (FIB-SEM). The incorporation of PEI into the membrane matrix effectively improves the CO2/N2 selectivity compared to the pristine polymer membranes. The improvement in CO2/N2 selectivity is also modelled by calculating the interfacial permeabilities with the Felske model using the gas permeabilities in the MMM. This study proposes a simple and effective modification method to address both the interface and gas selectivity in the application of nanoscale and non-porous fillers in gas separation membranes.

Synthesis of high surface area and functionalized nanoporous biocarbons and their efficiency for CO2 capture and supercapacitors

2021 ◽  
Author(s):  
Gurwinder Singh ◽  
Rohan Bahadur ◽  
Ajanya Maria Ruban ◽  
Jefrin Marykala Davidraj ◽  
Dawei Su ◽  
...  
Keyword(s):  
Energy Storage ◽  
Surface Area ◽  
Co2 Capture ◽  
Water Purification ◽  
High Surface ◽  
High Surface Area ◽  
Energy Storage And Conversion ◽  
Waste Biomass ◽  
Fabrication Technology ◽  
Significant Attention

Nanoporous biocarbons derived from waste biomass have created significant attention owing to their great potential for energy storage and conversion and water purification. However, the fabrication technology for these materials...

scholarly journals The Effects of Methane Storage Capacity Using Upgraded Activated Carbon by KOH

2018 ◽  
Vol 8 (9) ◽  
pp. 1596 ◽  
Author(s):  
Jung Park ◽  
Gi Lee ◽  
Sang Hwang ◽  
Ji Kim ◽  
Bum Hong ◽  
...  
Keyword(s):  
Surface Area ◽  
Storage Capacity ◽  
Activated Carbons ◽  
Chemical Activation ◽  
High Surface ◽  
Heat Of Adsorption ◽  
Low Grade ◽  
Surface Areas ◽  
Ch4 Adsorption ◽  
Ch4 Storage

In this study, a feasible experiment on adsorbed natural gas (ANG) was performed using activated carbons (ACs) with high surface areas. Upgraded ACs were prepared using chemical activation with potassium hydroxide, and were then applied as adsorbents for methane (CH4) storage. This study had three principal objectives: (i) upgrade ACs with high surface areas; (ii) evaluate the factors regulating CH4 adsorption capacity; and (iii) assess discharge conditions for the delivery of CH4. The results showed that upgraded ACs with surface areas of 3052 m2/g had the highest CH4 storage capacity (0.32 g-CH4/g-ACs at 3.5 MPa), which was over two times higher than the surface area and storage capacity of low-grade ACs (surface area = 1152 m2/g, 0.10 g-CH4/g-ACs). Among the factors such as surface area, packing density, and heat of adsorption in the ANG system, the heat of adsorption played an important role in controlling CH4 adsorption. The released heat also affected the CH4 storage and enhanced available applications. During the discharge of gas from the ANG system, the residual amount of CH4 increased as the temperature decreased. The amount of delivered gas was confirmed using different evacuation flow rates at 0.4 MPa, and the highest efficiency of delivery was 98% at 0.1 L/min. The results of this research strongly suggested that the heat of adsorption should be controlled by both recharging and discharging processes to prevent rapid temperature change in the adsorbent bed.

scholarly journals From double-helix structured seaweed to S-doped carbon aerogel with ultra-high surface area for energy storage

2019 ◽  
Vol 17 ◽  
pp. 22-30 ◽  
Author(s):  
Daohao Li ◽  
Guojing Chang ◽  
Lu Zong ◽  
Pan Xue ◽  
Yu Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Surface Area ◽  
Double Helix ◽  
High Surface ◽  
High Surface Area ◽  
Carbon Aerogel

Synthesis of Nanoporous Materials Al-MCM-41 from Natural Halloysite

NANO ◽  
2015 ◽  
Vol 10 (01) ◽  
pp. 1550005 ◽  
Author(s):  
Yaling Xie ◽  
Aidong Tang ◽  
Huaming Yang
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Halloysite Nanotubes ◽  
Nanoporous Materials ◽  
Molar Ratio ◽  
Molar Ratios ◽  
Naoh Solution ◽  
The One ◽  
Mcm 41

Nanoporous materials Al -MCM-41 with varying Si / Al molar ratios have been successfully synthesized from natural clay mineral halloysite nanotubes (HNTs). Hydrothermal treatment of acid-pretreated HNTs and NaOH solution resulted in the one-step synthesis of final nanoporous products by using surfactant. The effects of Si / Al molar ratios (7.7, 61.0 and 176.5) on the surface area, porosity and degree of structural order of Al -MCM-41 materials have been investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), N 2 adsorption–desorption measurements and Fourier transform infrared (FTIR) spectra techniques. The results indicated that Si / Al molar ratio had important effect on the characteristics of nanoporous materials, and Al -MCM-41 with an intermediate Si / Al molar ratio of 61.0 exhibited excellent characteristics with high degree of order, high surface area (S BET ) of 1033 m2/g and pore volume of 0.92 mL/g.

Enhancing the Storage Capacity of Supercapacitors Using PVA/CNT Nanocomposite Electrolytes

2014 ◽  
Author(s):  
T. Coskun ◽  
R. Asmatulu
Keyword(s):  
Energy Storage ◽  
High Surface ◽  
Internal Resistance ◽  
Test Results ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Surface Areas ◽  
Reduced Graphene ◽  
New Generation ◽  
Graphene Nanoflake

The ability to achieve high surface areas with nanomaterials brought several advancements in energy storage devices and their applications in different industries. Supercapacitors, a new generation of energy storage devises, have quick charge and discharge abilities, and hold as much energy as batteries and other chemical storage devices. The present study focuses on the effects of carbon nanotubes (CNTs) inclusions in polyvinyl alcohol (PVA) electrolytes for the improved capacitance values, which may affect the lifetime, charge holding, and charging and discharging rates of the graphene nanoflake-based supercapacitors. In this research, various supercapacitors were constructed using the reduced graphene oxide nanoflakes, PVA and PVA incorporated with CNTs, and the best candidates were selected for the future considerations. The test results showed that the CNT concentrations of 0.1–1.0wt% in PVA enhanced the capacitance (charge holding capacity) and reduced the internal resistance of the electrolytes significantly. This study may open up new possibilities for the supercapacitors and other energy storage devices currently under developments.

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