Oriental and robust anchoring of Fe via anodic interfacial coordination assembly on ultrathin Co hydroxides for efficient water oxidation

Nanoscale ◽  
2021 ◽  
Author(s):  
Ya-Nan Zhou ◽  
Ruo-Yao Fan ◽  
Yu-Ning Cao ◽  
Hui-Ying Wang ◽  
Bin Dong ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Active Sites

The oriental distribution and strong conjunction of Fe active sites in multiple metals hydroxides are very crucial to modulate the activity and stability for efficient oxygen evolution reaction (OER). Whereas,...

Capturing the active sites of multimetallic (oxy)hydroxides for the oxygen evolution reaction

2020 ◽  
Vol 13 (11) ◽  
pp. 4225-4237
Author(s):  
Xin Bo ◽  
Rosalie K Hocking ◽  
Si Zhou ◽  
Yibing Li ◽  
Xianjue Chen ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Active Sites ◽  
Alkaline Water ◽  
Catalytic Active Sites

The catalytic active sites of NiFe and NiFeCr (oxy)hydroxides are revealed by operando spectroscopic techonologies for alkaline water oxidation.

scholarly journals Engineering Ternary Copper-Cobalt Sulfide Nanosheets as High-performance Electrocatalysts toward Oxygen Evolution Reaction

Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 459 ◽  
Author(s):  
Heng Luo ◽  
Hang Lei ◽  
Yufei Yuan ◽  
Yongyin Liang ◽  
Yi Qiu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Noble Metal ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Active Sites ◽  
High Performance ◽  
Rational Design ◽  
Renewable Energy Sources ◽  
Cobalt Sulfide ◽  
Carbon Cloth

The rational design and development of the low-cost and effective electrocatalysts toward oxygen evolution reaction (OER) are essential in the storage and conversion of clean and renewable energy sources. Herein, a ternary copper-cobalt sulfide nanosheets electrocatalysts (denoted as CuCoS/CC) for electrochemical water oxidation has been synthesized on carbon cloth (CC) via the sulfuration of CuCo-based precursors. The obtained CuCoS/CC reveals excellent electrocatalytic performance toward OER in 1.0 M KOH. It exhibits a particularly low overpotential of 276 mV at current density of 10 mA cm−2, and a small Tafel slope (58 mV decade−1), which is superior to the current commercialized noble-metal electrocatalysts, such as IrO2. Benefiting from the synergistic effect of Cu and Co atoms and sulfidation, electrons transport and ions diffusion are significantly enhanced with the increase of active sites, thus the kinetic process of OER reaction is boosted. Our studies will serve as guidelines in the innovative design of non-noble metal electrocatalysts and their application in electrochemical water splitting

Strong hydrophilicity NiS2/Fe7S8 heterojunctions encapsulated in N-doped carbon nanotubes for enhanced oxygen evolution reaction

2020 ◽  
Vol 56 (10) ◽  
pp. 1489-1492 ◽  
Author(s):  
Jing-Yu Wang ◽  
Wen-Ting Liu ◽  
Xiao-Peng Li ◽  
Ting Ouyang ◽  
Zhao-Qing Liu
Keyword(s):  
Carbon Nanotubes ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Active Sites ◽  
Oxidation Activity

The construction of active sites with excellent water oxidation activity is of great significance in the design of OER electrocatalysts.

scholarly journals Carbon dots with tunable concentrations of trapped anti-oxidant as an efficient metal-free catalyst for electrochemical water oxidation

2016 ◽  
Vol 4 (38) ◽  
pp. 14614-14624 ◽  
Author(s):  
Abheek Datta ◽  
Sutanu Kapri ◽  
Sayan Bhattacharyya
Keyword(s):  
Oxygen Evolution ◽  
Alkaline Medium ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Carbon Dots ◽  
Active Sites ◽  
Metal Free ◽  
Anti Oxidant

Carbon dots, containing keto-groups as active sites and the highest abundance of an anti-oxidant, 5-hydroxymethyl-2-furaldehyde, efficiently catalyse oxygen evolution reaction in alkaline medium and generate 10 mA cm−2at 0.21 V overpotential..

Controllable growth of graphdiyne layered nanosheets for high-performance water oxidation

2021 ◽  
Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
High Performance ◽  
Low Cost ◽  
Highly Active ◽  
Controllable Growth

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.

Bifunctional citrate-Ni0.9Co0.1(OH)x layer coated fluorine-doped hematite for simultaneous hole extraction and injection towards efficient photoelectrochemical water oxidation

Nanoscale ◽  
2021 ◽  
Author(s):  
Peng Wang ◽  
Feng Li ◽  
Xuefeng Long ◽  
Tong Wang ◽  
Huan Chai ◽  
...  
Keyword(s):  
Surface Modification ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Surface Oxygen ◽  
Co Catalyst ◽  
Photoelectrochemical Water Oxidation

Surface modification by loading a water oxidation co-catalyst (WOC) is generally considered to be an efficient means to optimize the sluggish surface oxygen evolution reaction (OER) of hematite photoanode for...

scholarly journals The Effect of Iron Impurities on Transition Metal Catalysts for the Oxygen Evolution Reaction in Alkaline Environment: Activity Mediators or Active Sites?

2020 ◽  
Author(s):  
Ioannis Spanos ◽  
Justus Masa ◽  
Aleksandar Zeradjanin ◽  
Robert Schlögl
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Active Sites ◽  
Water Electrolysis ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Alkaline Water Electrolysis ◽  
Co Catalysts ◽  
Model Transition

AbstractThere is an ongoing debate on elucidating the actual role of Fe impurities in alkaline water electrolysis, acting either as reactivity mediators or as co-catalysts through synergistic interaction with the main catalyst material. This perspective summarizes the most prominent oxygen evolution reaction (OER) mechanisms mostly for Ni-based oxides as model transition metal catalysts and highlights the effect of Fe incorporation on the catalyst surface in the form of impurities originating from the electrolyte or co-precipitated in the catalyst lattice, in modulating the OER reaction kinetics, mechanism and stability. Graphic Abstract

Cathodic Corrosion Activated Fe-based Nanoglass as Highly-Active and -Stable Oxygen Evolution Catalyst for Water Splitting

2021 ◽  
Author(s):  
Kaiyao Wu ◽  
Fei Chu ◽  
Yuying Meng ◽  
Kaveh Edalati ◽  
Qingsheng Gao ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Amorphous Alloys ◽  
Precious Metal ◽  
Active Sites ◽  
Metal Free ◽  
Highly Active ◽  
Stable Oxygen ◽  
Surface Active

Transition metal-based amorphous alloys have attracted increasing attention as precious-metal-free electrocatalysts for oxygen evolution reaction (OER) of water splitting due to their high macro-conductivity and abundant surface active sites. However,...

scholarly journals Intrinsic activity modulation and structural design of NiFe alloy catalysts for an efficient oxygen evolution reaction

2021 ◽  
Author(s):  
Qiaoling Kang ◽  
Dawei Lai ◽  
Wenyin Tang ◽  
Qingyi Lu ◽  
Feng Gao
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Structural Design ◽  
Active Sites ◽  
Intrinsic Activity ◽  
Effective Strategies ◽  
Alloy Catalysts

Effective strategies to increase the intrinsic activity by electronic modulation and to increase the number of active sites by structural design are discussed for improving the oxygen evolution activities of NiFe alloys.

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