Single- and Bi-Exciton Character in Ligand-Modified Silicon Nanoparticles as Demonstrated via Single Particle Photon Statistics and Plasmonic Effects

Nanoscale ◽  
2021 ◽  
Author(s):  
Woong Young So ◽  
Sikandar Abbas ◽  
Qi Li ◽  
Rongchao Jin ◽  
Linda Anne Peteanu

Silicon nanoparticles (Si NPs) are of great interest to researchers due to their fluorescence properties, low toxicity, and the low cost of the Si precursor. Recent studies have shown that...

2020 ◽  
Vol 21 (9) ◽  
pp. 661-673 ◽  
Author(s):  
Mohammed Asadullah Jahangir ◽  
Chettupalli Anand ◽  
Abdul Muheem ◽  
Sadaf Jamal Gilani ◽  
Mohamad Taleuzzaman ◽  
...  

Herbal medicines are being used since ancient times and are an important part of the alternative and traditional medicinal system. In recent decades, scientists are embracing herbal medicines based on the fact that a number of drugs that are currently in use are derived directly or indirectly from plant sources. Moreover, herbal drugs have lesser side effects, albeit are potentially strong therapeutic agents. The herbal medicine market is estimated to be around US $62 billion globally. Herbal medicine has gained widespread acceptance due to its low toxicity, low cost, ease of accessibility and efficacy in treating difficult diseases. Safety and efficacy are another important factors in the commercialization process of herbal medicines. Nanotechnology has been shown to be potentially effective in improving the bioactivity and bioavailability of herbal medicines. Development of nano-phytomedicines (or by reducing the size of phytomedicine), attaching polymers with phytomedicines and modifying the surface properties of herbal drugs, have increased the solubility, permeability and eventually the bioavailability of herbal formulations. Novel formulations such as niosomes, liposomes, nanospheres, phytosomes etc., can be exploited in this area. This article reviews herbal medicines, which have prominent activity in the Central Nervous System (CNS) disorders and reported nano-phytomedicines based delivery systems.


RSC Advances ◽  
2021 ◽  
Vol 11 (13) ◽  
pp. 7732-7737
Author(s):  
Fenying Wang ◽  
Dan Wang ◽  
Tingting Wang ◽  
Yu Jin ◽  
Baoping Ling ◽  
...  

Fluorescent molecularly imprinted polymer (FMIP) gains great attention in many fields due to their low cost, good biocompatibility and low toxicity. Here, a high-performance FMIP was prepared based on the autocatalytic silica sol–gel reaction.


2012 ◽  
Vol 509 ◽  
pp. 51-55
Author(s):  
Hong Quan Liu ◽  
Fei Xiang Hao ◽  
Yi Jie Gu ◽  
Yun Bo Chen

LiFePO4 has been considered as the most promising positive electrode due to its low cost, high theoretical capacity, stability and low toxicity, all highly required in vehicle applications. In this work, LiFePO4 compound was synthesized by the solid carbothermic reduction reactions with different Li resource. The pure LiFePO4 phase was confirmed for all samples by analysis of the XRD results. The different morphologies were obtained due to different Li resources. The potential plateau of all samples is in the range from 3V to 4V. The sample (LiCO3 as the Li resource) has a higher discharge capacity of 118mAhg−1 at 0.2C 20% greater than that of the sample (LiOH as the Li resource). The reason comes maybe from nano pore characteristics, which reduce Li ion diffusion distance, and increase the utilization efficiency of material.


Author(s):  
Chang'an Li ◽  
Xin Guan ◽  
Shizhong Yue ◽  
Xi Zu Wang ◽  
Jianmin Li ◽  
...  

Thermoelectric polymers have attracted great attention because of their unique merits including low thermal conductivity, low cost, non- or low toxicity and high mechanical flexibility. However, their thermoelectric properties particularly...


2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Zhidong Wang ◽  
Jun Li ◽  
Yuanyuan Ji ◽  
Peng An ◽  
Shu Zhang ◽  
...  

Although significantly develops in hepatocellular carcinoma (HCC), features of HCC remain an aggressive cancer with a dismal outcome. Traditional Chinese medicine (TCM), specifically Chinese herbal medicine (CHM), is one of the most popular complementary and alternative medicine modalities worldwide. The use of heat-clearing and detoxicating (Chinese namedqingre jiedu) CHM has attracted great attention as an alternative antitumor including HCC considering its low toxicity and high activity. Together these reports indicate that CHM is a promising anti-HCC herbal remedy in basic research. For patients with advanced HCC, CHM including formula and single combined with transcatheter arterial chemoembolization or chemotherapy is able to decrease tumor growth and the side effect of toxicity and improve overall survival, quality of life, and immune function. Due to its abundance, low cost, and safety in consumption, CHM remains a species with tremendous potential for further investigation in HCC.


Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7271
Author(s):  
Tomasz Baran ◽  
Alberto Visibile ◽  
Michael Busch ◽  
Xiufang He ◽  
Szymon Wojtyla ◽  
...  

This work aims at reviewing the most impactful results obtained on the development of Cu-based photocathodes. The need of a sustainable exploitation of renewable energy sources and the parallel request of reducing pollutant emissions in airborne streams and in waters call for new technologies based on the use of efficient, abundant, low-toxicity and low-cost materials. Photoelectrochemical devices that adopts abundant element-based photoelectrodes might respond to these requests being an enabling technology for the direct use of sunlight to the production of energy fuels form water electrolysis (H2) and CO2 reduction (to alcohols, light hydrocarbons), as well as for the degradation of pollutants. This review analyses the physical chemical properties of Cu2O (and CuO) and the possible strategies to tune them (doping, lattice strain). Combining Cu with other elements in multinary oxides or in composite photoelectrodes is also discussed in detail. Finally, a short overview on the possible applications of these materials is presented.


2021 ◽  
Vol 25 ◽  
Author(s):  
Rashid Ali ◽  
Ajay Kumar Chinnam ◽  
Vikas R. Aswar

: The deep eutectic mixtures (DESs), introduced as novel alternative to usual volatile organic solvents for organic transformations has attracted a tremendous attention of the research community because of their low cost, negligible vapour pressure, low toxicity, biodegradability, recyclability, insensitive towards moisture, and readily availability from bulk renewable resources. Although, the low melting mixture of dimethyl urea (DMU)/L-(+)-tartaric acid (TA) is still infancy yet much effective as it play double and triple roles such as solvent, catalyst and/or reagent in a same pot for many crucial organic transformations. These unique properties of DMU/TA mixture prompted us to provide a quick overview of where the field stands presently, and where it might be going in near future. To our best knowledge, no review dealing with the applications of a low melting mixture of DMU/TA appeared in the literature except the one published in 2017 describing only the chemistry of indole systems. Therefore, we intended to reveal the developments of this versatile low melting mixture in the modern organic synthesis since its first report in 2011 by Köenig’s team to till date. Hopefully, the present review article will be useful to the researcher working not only in the arena of synthetic organic chemistry but also to the scientists working in other branches of science and technology.


2020 ◽  
Vol 10 (3) ◽  
pp. 1019 ◽  
Author(s):  
Jiali Cui ◽  
Feng Zhang ◽  
Hongyan Li ◽  
Jianguo Cui ◽  
Yatao Ren ◽  
...  

Biochar (BC) is a carbon-rich material produced from pyrolysis of biomass. In addition to its low toxicity, environmental compatibility, and low cost, BC has the desired advantages of well-developed mesoporous structure and abundant surface functional groups. In recent years, BC-based photocatalysts (BCPs) have played a significant role in many environmental fields. In this paper, we highlight the current progress and several exciting results of BCPs by focusing on their synthesis, characterization, mechanisms, and applications in wastewater treatment. Details on various preparation methods include sol–gel, hydrothermal/solvothermal, ultrasound, calcination, and in situ methods are summarized and discussed. The underlying mechanisms and the applications of BCPs for different semiconductors are reviewed. Furthermore, some future trends and potentials are outlined.


2017 ◽  
Vol 61 (6) ◽  
Author(s):  
Álvaro Martín-Montes ◽  
Daniel Plano ◽  
Rubén Martín-Escolano ◽  
Verónica Alcolea ◽  
Marta Díaz ◽  
...  

ABSTRACT The in vitro leishmanicidal activities of a series of 48 recently synthesized selenium derivatives against Leishmania infantum and Leishmania braziliensis parasites were tested using promastigotes and intracellular amastigote forms. The cytotoxicity of the tested compounds for J774.2 macrophage cells was also measured in order to establish their selectivity. Six of the tested compounds (compounds 8, 10, 11, 15, 45, and 48) showed selectivity indexes higher than those of the reference drug, meglumine antimonate (Glucantime), for both Leishmania species; in the case of L. braziliensis, compound 20 was also remarkably selective. Moreover, data on infection rates and amastigote numbers per macrophage showed that compounds 8, 10, 11, 15, 45, and 48 were the most active against both Leishmania species studied. The observed changes in the excretion product profile of parasites treated with these six compounds were also consistent with substantial cytoplasmic alterations. On the other hand, the most active compounds were potent inhibitors of Fe superoxide dismutase (Fe-SOD) in the two parasite species considered, whereas their impact on human CuZn-SOD was low. The high activity, low toxicity, stability, low cost of the starting materials, and straightforward synthesis make these compounds appropriate molecules for the development of affordable antileishmanicidal agents.


2012 ◽  
Vol 512-515 ◽  
pp. 431-434 ◽  
Author(s):  
Wei Liu ◽  
Zhi Peng Xie ◽  
Li Li Zhang ◽  
Xian Feng Yang

In this study, low-cost kerosene with low toxicity was used as organic solvent to research the solvent debinding behavior of ceramic compact produced by injection molding. The Influences of time, temperature and solid loading on the debinding rate were investigated, the mechanism of which was also discussed. The results show that: The debinding rate increased with increasing temperature and decreased with extended time; Diffusion is the controlling factor at the initial stage and temperature was the main factor influencing the reaction rate; Dissolution is the controlling factor and concentration difference was the main factor at the later stage; The higher the solid loading of green body, the slower the debinding rate and the lower the final proportion of binder removal.


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