Cu2O–reduced graphene oxide composite as a high-performance electrocatalyst for oxygen evolution reaction in alkaline media

2021 ◽  
Author(s):  
Xiaomei Xu ◽  
Qingqing An ◽  
Hao Sun ◽  
Yongchun Wang ◽  
Wenhui Shang ◽  
...  

Ethylene glycol was used as an inexpensive and nontoxic reducing agent to synthesize a Cu2O–reduced graphene oxide (Cu2O–rGO) composite. This material exhibited good electrocatalytic oxygen generation performance.

NANO ◽  
2019 ◽  
Vol 14 (01) ◽  
pp. 1950003 ◽  
Author(s):  
Guoxing Zhu ◽  
Xulan Xie ◽  
Lisong Xiao ◽  
Xiaoyun Li ◽  
Xiaoping Shen ◽  
...  

Development of high-performance nonprecious metal-based catalysts for oxygen evolution reaction (OER) is crucial to improve the efficiency of water electrolysis and photoelectrochemical water splitting for harvesting and storage of solar energy. Herein, Co–Fe phosphates and their composites with reduced graphene oxide (rGO) were prepared by a simple hydrothermal method, which then acted as oxygen evolution reaction catalysts. In 1.0 M KOH aqueous solution, the as-obtained optimal composite, Co–Fe phosphate/rGO, can catalyze oxygen evolution reaction with a very sharp onset potential and a small over-potential of 338[Formula: see text]mV to achieve a current density of 10[Formula: see text]mA[Formula: see text]cm[Formula: see text]. It was found that in these Co–Fe phosphates, the optimal Co:Fe ratio is 0.75:0.25. The excellent electrocatalytic performance of the Co–Fe phosphate/rGO composite would benefit from the synergistic effects between Fe and Co species, as well as rGO substrate providing conductive channels. The formed Co–Fe phosphate/rGO electrocatalysts can be the promising replacement of precious metal-based catalysts for more practical and cost-efficient water splitting.


RSC Advances ◽  
2016 ◽  
Vol 6 (36) ◽  
pp. 30552-30563 ◽  
Author(s):  
Ahamed Irshad ◽  
Nookala Munichandraiah

The MnOx–Pi–rGO OER catalyst is prepared by the simultaneous electrochemical reduction of MnO4− ions and GO in a neutral phosphate electrolyte.


2020 ◽  
Vol 8 (5) ◽  
pp. 2701-2711 ◽  
Author(s):  
Sen Meng ◽  
Xing Zhao ◽  
Chun-Yan Tang ◽  
Peng Yu ◽  
Rui-Ying Bao ◽  
...  

A bridge-arched integrated evaporator that introduces air as the thermal insulation layer exhibits high-efficiency solar steam generation.


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