The effects of MoO3 impregnation order on the catalytic activity for propane combustion over Pt/ZrO2 catalysts: The crucial roles of Pt-MoO3 interfacial sites density

2021 ◽  
Author(s):  
Jian Chen ◽  
Mengfei Luo ◽  
Jiqing Lu ◽  
Chufeng Liu ◽  
Weiyue Wang ◽  
...  

MoO3 promoted Pt/ZrO2 catalysts were prepared by co-impregnation (Pt-Mo/ZrO2) or stepwise impregnation (Pt/Mo/ZrO2 and Mo/Pt/ZrO2) for propane combustion. Impregnation order affects the density of active Pt-MoO3 interfacial sites, which is...

2020 ◽  
Vol 391 ◽  
pp. 80-90
Author(s):  
Pei-Pei Zhao ◽  
Jian Chen ◽  
Hong-Bo Yu ◽  
Bing-Heng Cen ◽  
Wei-Yue Wang ◽  
...  

2018 ◽  
Vol 34 (1) ◽  
pp. 31
Author(s):  
Paulo Roberto Nagipe Da Silva ◽  
Ana Brígida Soares

The perovskite-type oxides using transition metals present a promising potential as catalysts in total oxidation reaction. The present work investigates the effect of synthesis by oxidant co-precipitation on the catalytic activity of perovskite-type oxides LaBO3 (B= Co, Ni, Mn) in total oxidation of propane and CO. The perovskite-type oxides were characterized by means of X-ray diffraction, nitrogen adsorption (BET method), thermo gravimetric and differential thermal analysis (ATG-DTA) and X-ray photoelectron spectroscopy (XPS). Through a method involving the oxidant co-precipitation it’s possible to obtain catalysts with different BET surface areas, of 33-44 m2/g, according the salts of metal used. The characterization results proved that catalysts have a perovskite phase as well as lanthanum oxide, except LaMnO3, that presents a cationic vacancies and generation for known oxygen excess. The results of catalytic test showed that all oxides have a specific catalytic activity for total oxidation of CO and propane even though the temperatures for total conversion change for each transition metal and substance to be oxidized.


2008 ◽  
Vol 139 (1-2) ◽  
pp. 37-42 ◽  
Author(s):  
Teruaki Asada ◽  
Teppei Kayama ◽  
Hajime Kusaba ◽  
Hisahiro Einaga ◽  
Yasutake Teraoka

CrystEngComm ◽  
2019 ◽  
Vol 21 (17) ◽  
pp. 2727-2735 ◽  
Author(s):  
Juxia Xiong ◽  
Zhu Luo ◽  
Ji Yang ◽  
Yanbing Guo ◽  
Adimali Piyadasa ◽  
...  

Well-tuned TiO2–Al2O3 binary nanoarrays had been fabricated onto ceramic honeycombs and exhibited excellent robustness and catalytic activity for propane oxidation.


1998 ◽  
Vol 19 (3-4) ◽  
pp. 261-266 ◽  
Author(s):  
Yoshiteru Yazawa ◽  
Hisao Yoshida ◽  
Nobuyuki Takagi ◽  
Shin-ichi Komai ◽  
Atsushi Satsuma ◽  
...  

Author(s):  
J. C. Wheatley ◽  
J. M. Cowley

Rare-earth phosphates are of particular interest because of their catalytic properties associated with the hydrolysis of many aromatic chlorides in the petroleum industry. Lanthanum phosphates (LaPO4) which have been doped with small amounts of copper have shown increased catalytic activity (1). However the physical and chemical characteristics of the samples leading to good catalytic activity are not known.Many catalysts are amorphous and thus do not easily lend themselves to methods of investigation which would include electron microscopy. However, the LaPO4, crystals are quite suitable samples for high resolution techniques.The samples used were obtained from William L. Kehl of Gulf Research and Development Company. The electron microscopy was carried out on a JEOL JEM-100B which had been modified for high resolution microscopy (2). Standard high resolution techniques were employed. Three different sample types were observed: 669A-1-5-7 (poor catalyst), H-L-2 (good catalyst) and 27-011 (good catalyst).


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