Bifunctional Pt-Mo catalyst for in-situ hydrogenation of methyl stearate into alkanes using formic acid as a hydrogen donor

2021 ◽  
Author(s):  
Wei Yang ◽  
Kejing Wu ◽  
Yingming Zhu ◽  
Yingying Liu ◽  
Houfang Lu ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Formic Acid ◽  
Greenhouse Effect ◽  
Methyl Stearate ◽  
Fossil Fuels ◽  
Hydrogen Donor ◽  
Energy Crisis ◽  
Mo Catalyst

Biofuels have aroused considerable interest as a direct substituent of fossil fuels due to energy crisis and greenhouse effect. In this article, bifunctional Pt-Mo catalyst supported on activated carbon (AC)...

Ethanol-Enhanced Liquefaction of Lignin with Formic Acid as an in Situ Hydrogen Donor

2015 ◽  
Vol 29 (9) ◽  
pp. 5835-5840 ◽  
Author(s):  
Xinping Ouyang ◽  
Xiangzhen Huang ◽  
Yuan Zhu ◽  
Xueqing Qiu
Keyword(s):  
Formic Acid ◽  
Hydrogen Donor

scholarly journals Selective Oxidation of Methane over Fe-Zeolites by In Situ Generated H2O2

Catalysts ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 299 ◽  
Author(s):  
Jongkyu Kang ◽  
Eun Duck Park
Keyword(s):  
Activated Carbon ◽  
Liquid Phase ◽  
Ion Exchange ◽  
Formic Acid ◽  
Selective Oxidation ◽  
Molecular Hydrogen ◽  
Reaction Conditions ◽  
Oxidation Of Methane ◽  
The Given

Liquid-phase selective oxidation of methane into methane oxygenates, including methanol and formic acid, with molecular oxygen was investigated using Fe-zeolites and Pd/activated carbon in the presence of molecular hydrogen as a reducing agent. Various Fe-zeolites such as Fe-ZSM-5, Fe-mordenite, Fe-β, Fe-Y, and Fe-ferrierite were prepared by ion-exchange and compared for this reaction. Among them, Fe-ZSM-5 was selected for further study because this catalyst showed high activity in the selective oxidation of methane with relatively less leaching. Further, the effect of reaction temperature, pH, and the amount of catalyst was examined, and detailed investigations revealed that the leached Fe species, which were facilitated in the presence of acid, were mainly responsible for methane oxidation under the given reaction conditions.

Global Warming and Its Multiple Causes

2020 ◽  
Vol 3 (2) ◽  
Author(s):  
Romdhane Ben Slama
Keyword(s):  
Global Warming ◽  
Greenhouse Gases ◽  
Greenhouse Effect ◽  
Infrared Radiation ◽  
Fossil Fuels ◽  
Ambient Air ◽  
The Earth ◽  
The One ◽  
Heat Released ◽  
Emission Of Greenhouse Gases

The global warming which preoccupies humanity, is still considered to be linked to a single cause which is the emission of greenhouse gases, CO2 in particular. In this article, we try to show that, on the one hand, the greenhouse effect (the radiative imprisonment to use the scientific term) took place in conjunction with the infrared radiation emitted by the earth. The surplus of CO2 due to the combustion of fossil fuels, but also the surplus of infrared emissions from artificialized soils contribute together or each separately,  to the imbalance of the natural greenhouse effect and the trend of global warming. In addition, another actor acting directly and instantaneously on the warming of the ambient air is the heat released by fossil fuels estimated at 17415.1010 kWh / year inducing a rise in temperature of 0.122 ° C, or 12.2 ° C / century.

Sulfur-anchored palm shell waste-based activated carbon for ultrahigh sorption of Hg(II) for in-situ groundwater treatment

2021 ◽  
pp. 125995
Author(s):  
So Yeon Yoon ◽  
Seok Byum Jang ◽  
Kien Tiek Wong ◽  
Hyeseong Kim ◽  
Min Ji Kim ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Groundwater Treatment ◽  
Palm Shell ◽  
Shell Waste

scholarly journals TiO2 Nanowires with Doped g-C3N4 Nanoparticles for Enhanced H2 Production and Photodegradation of Pollutants

Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 254
Author(s):  
Liushan Jiang ◽  
Fanshan Zeng ◽  
Rong Zhong ◽  
Yu Xie ◽  
Jianli Wang ◽  
...  
Keyword(s):  
Environmental Governance ◽  
Fossil Fuels ◽  
H2 Production ◽  
Tio2 Nanowires ◽  
Photocatalytic Ability ◽  
Production Of Hydrogen ◽  
Growth Method ◽  
Renewable Hydrogen ◽  
Degradation Of Pollutants

With the rapid consumption of fossil fuels, along with the ever-increasing environmental pollution, it is becoming a top priority to explore efficient photocatalysts for the production of renewable hydrogen and degradation of pollutants. Here, we fabricated a composite of g-C3N4/TiO2 via an in situ growth method under the conditions of high-temperature calcination. In this method, TiO2 nanowires with a large specific surface area could provide enough space for loading more g-C3N4 nanoparticles to obtain C3N4/TiO2 composites. Of note, the g-C3N4/TiO2 composite could effectively photocatalyze both the degradation of several pollutants and production of hydrogen, both of which are essential for environmental governance. Combining multiple characterizations and experiments, we found that the heterojunction constructed by the TiO2 and g-C3N4 could increase the photocatalytic ability of materials by prompting the separation of photogenerated carriers. Furthermore, the photocatalytic mechanism of the g-C3N4/TiO2 composite was also clarified in detail.

scholarly journals In Situ Fabrication of Activated Carbon from a Bio-Waste Desmostachya bipinnata for the Improved Supercapacitor Performance

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Gopal Krishna Gupta ◽  
Pinky Sagar ◽  
Sumit Kumar Pandey ◽  
Monika Srivastava ◽  
A. K. Singh ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Energy Density ◽  
Power Density ◽  
Supercapacitor Electrode ◽  
In Situ Fabrication ◽  
Transmission Electron ◽  
Good Energy ◽  
Supercapacitor Performance ◽  
Operating Potential

AbstractHerein, we demonstrate the fabrication of highly capacitive activated carbon (AC) using a bio-waste Kusha grass (Desmostachya bipinnata), by employing a chemical process followed by activation through KOH. The as-synthesized few-layered activated carbon has been confirmed through X-ray powder diffraction, transmission electron microscopy, and Raman spectroscopy techniques. The chemical environment of the as-prepared sample has been accessed through FTIR and UV–visible spectroscopy. The surface area and porosity of the as-synthesized material have been accessed through the Brunauer–Emmett–Teller method. All the electrochemical measurements have been performed through cyclic voltammetry and galvanometric charging/discharging (GCD) method, but primarily, we focus on GCD due to the accuracy of the technique. Moreover, the as-synthesized AC material shows a maximum specific capacitance as 218 F g−1 in the potential window ranging from − 0.35 to + 0.45 V. Also, the AC exhibits an excellent energy density of ~ 19.3 Wh kg−1 and power density of ~ 277.92 W kg−1, respectively, in the same operating potential window. It has also shown very good capacitance retention capability even after 5000th cycles. The fabricated supercapacitor shows a good energy density and power density, respectively, and good retention in capacitance at remarkably higher charging/discharging rates with excellent cycling stability. Henceforth, bio-waste Kusha grass-derived activated carbon (DP-AC) shows good promise and can be applied in supercapacitor applications due to its outstanding electrochemical properties. Herein, we envision that our results illustrate a simple and innovative approach to synthesize a bio-waste Kusha grass-derived activated carbon (DP-AC) as an emerging supercapacitor electrode material and widen its practical application in electrochemical energy storage fields.

Insights into the Development of Cu-based Photocathodes for Carbon Dioxide (CO2) Conversion

2021 ◽  
Author(s):  
Wenzhang Li ◽  
Keke Wang ◽  
yanfang Ma ◽  
Yang Liu ◽  
Weixin Qiu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Fossil Fuels ◽  
Environmental Issues ◽  
Energy Crisis ◽  
Co2 Conversion ◽  
Carbon Dioxide Co2 ◽  
Reduction Of Co2

The ever-growing factitious over-consumption of fossil fuels and the accompanying massive emissions of CO2 have caused severe energy crisis and environmental issues. Photoelectrochemical (PEC) reduction of CO2 that can combine...

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