Fabrication of Co3O4 nanoparticles decorated porous activated carbon electrode for the electrochemical detection of 4-nitrophenol

2021 ◽  
Author(s):  
Benadict Joseph Xavier ◽  
Christy Ezhilarasi J ◽  
Sea-Fue Wang ◽  
Elanthamilan Elaiyappillai ◽  
Sriram Balasubramanian ◽  
...  

State-of-the-art, electrochemical applications recently employ various activated carbons combined with transition metal oxides as electrode materials; exhibit superior conductivity and tailored porosity to offer both rapid electron transfer. In this...

2014 ◽  
Vol 7 (4) ◽  
pp. 1250-1280 ◽  
Author(s):  
Marta Sevilla ◽  
Robert Mokaya

This review presents the state-of-the-art with respect to synthesis of activated carbons, and their use as electrode materials in supercapacitors and as hydrogen storage materials.


2013 ◽  
Vol 1505 ◽  
Author(s):  
Krzysztof Fic ◽  
Mikolaj Meller ◽  
Grzegorz Lota ◽  
Elzbieta Frackowiak

ABSTRACTThe main subject of this paper is to examine and to evaluate the capacitive behaviour of activated carbon electrodes electrochemically decorated by quinone-type functional groups. For this purpose, different electrolytes, i.e. hydroquinone, catechol and resorcinol at the concentration of 0.38 mol L-1, dissolved in 1 mol L-1 H2SO4, 1 mol L-1 Li2SO4 and 6 mol L-1 KOH were used. These electrolytes could generate electroactive groups (able to undergo reversible redox reactions) on the surface of electrode material. Apart from typical adsorption of the mentioned dihydroxybenzenes, so called grafting could occur and might cause generation of quinone|hydroquinone functionals on carbon surface. As an effect of functional reversible redox reaction, additional capacitance value, called pseudocapacitance, could be achieved. Hence, besides typical charge originating from charging/discharging of the electrical double layer on the electrode/electrolyte interface, additional capacitance comes also from faradaic reactions. Activated carbons are the most promising electrode materials for this purpose; apart from great physicochemical properties, they are characterized by well-developed specific surface area over 2000 m2 g-1 which results in high capacitance values.In the manuscript the influence of the hydroxyl group location as well as electrolyte solution pH on the electrochemical performance of the electrode is discussed.


2016 ◽  
Vol 8 (2) ◽  
pp. 1319-1326 ◽  
Author(s):  
Pitchaimani Veerakumar ◽  
Vediyappan Veeramani ◽  
Shen-Ming Chen ◽  
Rajesh Madhu ◽  
Shang-Bin Liu

1996 ◽  
Vol 8 (4) ◽  
pp. 331-334 ◽  
Author(s):  
Marina Mastragostino ◽  
Catia Arbizzani ◽  
Luca Meneghello ◽  
Ruggero Paraventi

2018 ◽  
Vol 930 ◽  
pp. 597-602 ◽  
Author(s):  
Tayara Correia Gonsalves ◽  
Franks Martins Silva ◽  
Ligia Silverio Vieira ◽  
Julio Cesar Serafim Casini ◽  
Rubens Nunes de Faria

In recent years, extensive investigations have focused on the study and improvement of supercapacitor electrode materials. The electric devices produced with these materials are used to store energy over time periods ranging from seconds to several days. The main factor that determines the energy storage period of a supercapacitor is its self-discharge rate, i.e., the gradual decrease in electric potential that occurs when the supercapacitor terminals are not connected to either a charging circuit or electric load. Self-discharge is attenuated at lower temperatures, resulting in an increased energy storage period. This paper addresses the temperature-dependence of self-discharge via a systematic study of supercapacitors with nominal capacitances of 1.0 and 10.0 F at DC potentials of 5.5 and 2.7 V, respectively. The specific capacitances, internal resistances, and self-discharge characteristics of commercial activated carbon electrode supercapacitors were investigated. Using cyclic voltammetry, the specific capacitances were determined to be 44.4 and 66.7 Fg−1 for distinct carbon electrode supercapacitors. The self-discharge characteristics were investigated at both room temperature and close to the freezing point. The internal resistances of the supercapacitors were calculated using the discharge curves at room temperature. The microstructures of the electrode materials were determined using scanning electron microscopy.


Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3453 ◽  
Author(s):  
Alain Mauger ◽  
Christian M. Julien

Sodium-ion batteries (SIBs) were investigated as recently as in the seventies. However, they have been overshadowed for decades, due to the success of lithium-ion batteries that demonstrated higher energy densities and longer cycle lives. Since then, the witness a re-emergence of the SIBs and renewed interest evidenced by an exponential increase of the publications devoted to them (about 9000 publications in 2019, more than 6000 in the first six months this year). This huge effort in research has led and is leading to an important and constant progress in the performance of the SIBs, which have conquered an industrial market and are now commercialized. This progress concerns all the elements of the batteries. We have already recently reviewed the salts and electrolytes, including solid electrolytes to build all-solid-state SIBs. The present review is then devoted to the electrode materials. For anodes, they include carbons, metal chalcogenide-based materials, intercalation-based and conversion reaction compounds (transition metal oxides and sulfides), intermetallic compounds serving as functional alloying elements. For cathodes, layered oxide materials, polyionic compounds, sulfates, pyrophosphates and Prussian blue analogs are reviewed. The electrode structuring is also discussed, as it impacts, importantly, the electrochemical performance. Attention is focused on the progress made in the last five years to report the state-of-the-art in the performance of the SIBs and justify the efforts of research.


Sign in / Sign up

Export Citation Format

Share Document