A benevolent direction to environmental suitability: Ionic liquid immobilized MoO3 nanoparticles as efficient visible-light-driven photocatalytic degradation of antibiotics

2021 ◽  
Author(s):  
Debarati Chakraborty ◽  
Meghali Devi ◽  
Bishal Das ◽  
Monjur Hassan Barbhuiya ◽  
Siddhartha Sankar Dhar ◽  
...  

In this study we report, synthesis of a novel MoO3-bonded imidazolium-sulfonic acid chloride (MoO3-IL) and its application in photocatalytic degradation of two very highly polluting antibiotics viz. ciprofloxacin and metronidazole....

Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 788
Author(s):  
Beibei Zhang ◽  
Lu Zhang ◽  
Yulong Zhang ◽  
Chao Liu ◽  
Jiexiang Xia ◽  
...  

In this work, a simple chemical precipitation method was employed to prepare spherical-like Ag3PO4 material (IL-Ag3PO4) with exposed {111} facet in the presence of reactive ionic liquid 1-butyl-3-methylimidazole dihydrogen phosphate ([Omim]H2PO4). The crystal structure, microstructure, optical properties, and visible-light photocatalytic performance of as-prepared materials were studied in detail. The addition of ionic liquids played a crucial role in forming spherical-like morphology of IL-Ag3PO4 sample. Compared with traditional Ag3PO4 material, the intensity ratio of {222}/{200} facets in XRD pattern of IL-Ag3PO4 was significantly enhanced, indicating the main {111} facets exposed on the surface of IL-Ag3PO4 sample. The presence of exposed {111} facet was advantageous for facilitating the charge carrier transfer and separation. The light-harvesting capacity of IL-Ag3PO4 was larger than that of Ag3PO4. The photocatalytic activity of samples was evaluated by degrading rhodamine B (RhB) and p-chlorophenol (4-CP) under visible light. The photodegradation efficiencies of IL-Ag3PO4 were 1.94 and 2.45 times higher than that of Ag3PO4 for RhB and 4-CP removal, respectively, attributing to a synergy from the exposed {111} facet and enhanced photoabsorption. Based on active species capturing experiments, holes (h+), and superoxide radical (•O2−) were the main active species for visible-light-driven RhB photodegradation. This study will provide a promising prospect for designing and synthesizing ionic liquid-assisted photocatalysts with a high efficiency.


RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47615-47624 ◽  
Author(s):  
Ping Li ◽  
Chunbo Liu ◽  
Guoling Wu ◽  
Yang Heng ◽  
Shuang Lin ◽  
...  

In this paper, Fe-doped SrTiO3 (FSTO) photocatalysts were successfully prepared via a facile solvothermal method, and their photocatalytic activities for degrading tetracycline (TC) under visible light irradiation were examined.


2021 ◽  
Author(s):  
Lijie Wang ◽  
Qiang Li ◽  
Xiaoxiao Lu ◽  
Zhenfei Tian ◽  
Shiwu He ◽  
...  

A series of novel three-dimensional (3D) CoTiO3/BiOBr (CTBB) hierarchical heterostructures were prepared via a simple hydrothermal method. In comparison with pure CoTiO3 and BiOBr, all the CTBB nanocomposites display enhanced...


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